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A semi-empirical model for high-field conduction in polyethylene is developed on the basis of data in the literature for ac conductivity in the range of 30 to 60 kV/mm and 'charge injection' from a needle in the range of 160 kV/mm. The model is used to compute high-field conduction-related phenomena by solving Poisson…
The efficient synthesis, molecular and crystal structure, chemical, spectroscopical and electrochemical properties and charge-transfer salts of dimethyl[2,4-dioxo(1H,3H)pyrimido]tetrathiafulvalene, a novel π-electron donor able to form intermolecular hydrogen bonds of nucleic acid base-pair type, are described.
High-surface-area zinc–cobalt–aluminium oxides have been prepared from coprecipitated hydroxycarbonate precursors. The oxides were tested for their H2S uptake in a microreactor at 303 K. The precursors all adopted a hydrotalcite-type structure, whilst the oxides were also all single-phase materials. Their structures w…
Reaction of CuCl2·2H2O or CuBr2 with the tridentate ligand 4-methyl-2,6-bis(pyrrolidin-1-yl-methyl)phenol (Hmbpp) in methanol yielded two copper(II) complexes [Cu4OCl4(mbpp)2]·2MeOH 1 and [Cu4OBr4(mbpp)2]2. They were characterised by single-crystal X-ray diffraction analyses. Both structures were solved using direct m…
Molten decanoic acid, capric acid, reacted with the layered double hydroxide (LDH) of initial composition Mg6Al3.4(OH)18.82(CO3)1.51(NO3)0.36·4.5 H2O, at a temperature of 150 °C using a heating rate of 1 °C min–1. Powder X-ray diffraction (PXRD) showed that the reaction products were microcrystalline. The polyphasic n…
Copper hydride, CuH, has been prepared by the reduction of aqueous copper sulfate using hypophosphorous acid. The polycrystalline red–brown hydride has been analysed using transmission electron microscopy, powder X-ray diffraction (PXRD) and differential scanning calorimetry, and consists of agglomerates of needle-lik…
The stability of polystyrene latices has been studied in the presence of hydroxyethyl cellulose (HEC) sodium carboxymethyl cellulose (SCMC) and sodium polystyrene sulfonate (SPSS) at various ionic strengths. Only HEC was adsorbed onto the particles from water, whereas all three polymers were adsorbed at high ionic str…
Efficient syntheses of a cyclic porphyrin dimer, cyclic trimer, cyclic tetramer, linear dimer, linear tetramer, and linear octamer are described. Starting from a zinc porphyrin monomer, simple oligopyridine ligands are used as templates to control oligomerisation by binding to the linear intermediates formed under Gla…
Tetrathiafulvalene and its derivatives can be chemically or electrochemically oxidized to yield stable radical cation salts which display unusual electrical properties. In order to increase the dimensionality of the system by extending the π‐conjugation and thus stabilizing the metallic state, while at the same time k…
Metallic electromigration is the movement of metallic material across a nonmetallic medium, under the influence of an electric field. It is increasingly important in the performance and reliability of electronic systems as an underling cause of functional failures in electrical and electronic components. This tutorial…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPreparation and Characterization of Microporosity and Acidity of Silica-Alumina Pillared ClaysAndoni Gil, Garbine Guiu, Paul Grange, and Mario MontesCite this: J. Phys. Chem. 1995, 99, 1, 301–312Publication Date (Print):January 1, 1995Publication History Published online1 Ma…
The crystal structures of seven three-co-ordinated complexes of copper(I) halides with thione ligands, [CuXL2], where L = 1,3-thiazolidine-2-thione and X = Cl or Br, L =N-ethylimidazolidine-2-thione and X = Br, L =N-isopropylimidazolidine-2-thione and X = Cl or Br, and L =N-propylimidazolidine-2-thione and X = Cl or I…
Low molecular weight chitosan (LMWC) (a mixture of chitooligosaccharides with high degrees of polymerization; an average degree of polymerization is 6.8) stimulated mitogenic response to platelet-derived growth factor (PDGF) in a dose-dependent manner in cultured rat vascular smooth muscle cells, and a maximum effect…
In this paper the following questions are considered: What are the phenomena which limit the total fracture energy of a structure under the extension before it breaks? When is the limiting energy level more important that the stress limit? What are possible ways to increase the required fracture energy of a sample bef…
One of the important issues in the determination of induction motor efficiency is the prediction of iron losses in the magnetic circuit. This in essence requires a knowledge of the time variation of the flux density in the steel followed by the knowledge of the iron losses appropriate to that waveform and lamination m…
CsB/sub 3/O/sub 5/ has been found to be phase matchable for SFG down to 0.185 /spl mu/m by mixing the fifth harmonic of a Nd:YAG laser at 1.0642 /spl mu/m and the output of a KTP parametric oscillator pumped by the second harmonic of the same Nd:YAG laser at 20.0/spl deg/C. Improved Sellmeier's equations and nonlinear…
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Visible-range absorption spectra of poly(o-toluidine) and poly(m-toluidine) films on tin-doped indium(III) oxide-coated optically transparent electrodes as a function of applied potential are reported. Absorption maxima and redox potentials shift from values found for polyaniline due to the lower conjugation length in…
Recent developments in electronic components and systems have resulted in the improvement in the detection of partial discharges. However, the interpretation of all the information now available is complicated due to the large number of variables involved. The aim of this paper is to confirm the rapid transition from…
The synthesis, solution redox properties and electronic spectra of a new series of stable, neutral nickel–dithiolene complexes [Ni(R2timdt)2](where R2timdt is the monoreduced anion of the first example of 1,3-dialkylimidazolidine-2,4,5-trithione and alkyl = Et, Pri, Bu), showing an intense electronic absorption at λ≈…