Materials Literature
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A liquid-crystal optical phased-array technology that uses stressed liquid crystals provides a new type of tip-tilt wavefront corrector. It demonstrates a very fast time response (10 kHz) and high beam-steering efficiency (approximately 91%). The new technology presented here will allow for a nonmechanical, high-speed…
The dielectric properties, dopant distributions, and microstructures of BaTiO 3 ‐based multilayer ceramic capacitors (MLCCs) sintered in H 2 –N 2 –H 2 O atmospheres with =10 −7.5 Pa (BMX‐7.5) and =10 −9.5 Pa (BMX‐9.5) were studied, and the effects of oxygen partial pressures were analyzed. Dielectric measurements show…
A mathematical analysis of the cubic crystal structure of fast oxide-ion conductor beta-La(2)Mo(2)O(9) (and derived members of the LAMOX family) shows that its cationic sublattice can behave as a semirigid framework. Tilt/rotation of rigid [O1La(3)Mo] anti-tetrahedral units about their 3-fold axis can open up tunnels…
The use of metal−ligand binding as the driving force for the self-assembly polymerizations of a ditopic monomer offers a facile route to the preparation of metallo-supramolecular polymers. We report, herein, the utilization of this approach for the polymerization of a conjugated macromonomer that was derived by functi…
The optimisation of the radiation protection for the workers in nuclear industry is an important part of the safety culture. The application of the ALARA concept (to keep exposures as low as reasonably achievable) is not always straightforward as it is influenced by the site geometry, source distribution and work orga…
Photoionization cross sections of the phenyl radical to form the phenyl cation were measured using tunable vacuum ultraviolet synchrotron radiation coupled with photofragment translational spectroscopy. The phenyl radical was produced via 193- or 248-nm dissociation of chlorobenzene. At 10.0 eV, the photoionization cr…
A novel biomimetic route for the synthesis of electrically conducting homopolymers/copolymers of pyrrole and 3,4-ethylenedioxythiophene (EDOT) in the presence of a polyelectrolyte, such as polystyrene sulfonate (SPS), is presented. A poly(ethylene glycol)-modified hematin (PEG-hematin) was used to catalyze the homopol…
Abstract Poly(ethylene oxide) (PEO), soluble in both aqueous and organic solvents, is one of the most intriguing polymers. PEO solution properties have been extensively studied for decades; however, many of the studies have focused on specific properties, such as clustering, of PEO in aqueous solutions, and the behavi…
Point kernel codes that simulate gamma-ray transport often use build-up factors to take scattered photons into account. This study introduces a new method, for computing multi-layer shield build-up factors. This method, based on an empirical formula for calculating double-layer shield build-up factors, is iterative. F…
Abstract Novel luminescent polyoxometalate anion‐pillared layered double hydroxides (LDHs) were prepared by aqueous ion exchange of a Zn–Al LDH precursor in nitrate form with the europium‐containing polyoxotungstate anions [EuW 10 O 36 ] 9– , [Eu(BW 11 O 39 )(H 2 O) 3 ] 6– and [Eu(PW 11 O 39 ) 2 ] 11– . The host–guest…
A metmyoglobin (Fe3+), an oxidized form of myoglobin (Fe2+), was confined in nanospaces of about 4 nm in diameter in mesoporous silica (FSM; folded-sheet mesoporous material), forming a metmyoglobin (Fe3+)-FSM nanoconjugate. The spectral characteristics of metmyoglobin (Fe3+)- and myoglobin (Fe2+)-FSM show an absorpti…
Aluminum nitride (AlN) powders manufactured via three major commercial processes, namely, chemical vapor deposition from triethyl aluminum, carbothermal reduction and nitridation of alumina, and direct nitridation of aluminum, were exposed to moist air at room temperature to investigate the degradation mechanism and k…
Abstract Two dinuclear Eu III complexes have been synthesized by employing β‐diketones and 2,2′‐bipyrimidine (bpm) as sensitizing ligands for the Eu ion and a bridging ligand, respectively, and characterized by various means including single‐crystal X‐ray crystallography. The use of dibenzoylmethane (dbm) and trifluor…
This review is devoted to the recent advances in the preparation of immobilised metalloporphyrins and their use as heterogeneous catalysts for alkene epoxidation. The wide range of supports, nature of attachments, and metalloporphyrins that have been reported is detailed and a comparison is made between the activities…
We examine the vitrification and melting of asymmetric star polymer mixtures by combining rheological measurements with mode coupling theory. We identify two types of glassy states, a single glass, in which the small component is fluid in the glassy matrix of the big one, and a double glass, in which both components a…
The buckling of multiwalled carbon nanotubes under torsional load coupling with temperature change is researched. The effects of torsional load, temperature change, surrounding elastic medium, and van der Waals forces between the inner and outer nanotubes are taken into account at the same time. Using continuum mechan…
We develop a mesoscale polystyrene model based on atomistic simulations of oligomers using the iterative Boltzmann inversion method. The potential is optimized against the atomistic simulation until the radial distribution function generated from the mesoscale model is consistent with the atomistic simulation. The mes…
We demonstrate for the first time that the superlacunary polyanion [H(2)P(4)W(24)O(94)](22)(-) reacts with electrophiles. One-pot reaction of this precursor polyanion with dimethyltin dichloride in aqueous acidic medium results in the hybrid organic-inorganic [{Sn(CH(3))(2)}(4)(H(2)P(4)W(24)O(92))(2)](28)(-) (1). Sing…
Fully dense polymer‐derived SiAlCN ceramics were exposed to pure water vapor flowing at the rate of 4.4 cm/s at 1100°C. Weight changes as a function of annealing time were recorded to illustrate the oxidation/corrosion behavior of the materials. The paralinear kinetic model was used to determine the parabolic and line…
We review the use of phase field methods in solidification modeling, describing their fundamental connection to the physics of phase transformations. The inherent challenges associated with simulating phase field models across multiple length and time scales are discussed, as well as how these challenges have been add…