Materials Literature
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The immobilization of dodecylbenzenesulfonate (DBS <sup>−</sup> ) in polypyrrole (PPy) during electropolymerization is typically expected to lead to cation-driven activity. Here we demonstrate that the actuation direction changed by using same electrolyte but different solvent.
A one-pot strategy from ring-opening metathesis polymerization was employed to prepare AIE-active star polymers, which were designed to have multi-responsive fluorescence to varied stimuli including pH, CO <sub>2</sub> , and metal ions.
The sub-diffraction demagnification imaging of hyperlens with plasmonic reflector was demonstrated experimentally in lithography performance at 365 nm light wavelength.
Efficiently thermal conductive networks were fabricated in the iPP/h-BN composites by the “bridge effect” of MWCNTs or GNPs.
Temperature-sensitive and Mn <sup>2+</sup> -location-dependent red emission from (Mn/Zn)–Ga–Sn–S supertetrahedral nanoclusters.
The first report on polymer precursor synthesis for TaC–SiC nanocomposties with Ta-polymer characterized by XAFS.
The electronic structures and magnetism of defect- and transition metal (TM)-embedded stanene monolayers are investigated by using first-principles methods. Single vacancy (SV) and double vacancy (DV) cannot induce magnetism, while embedding a TM can effectively tune the magnetic moments of the stanene monolayer. More…
Guest editors Anne-Marie Caminade, Evamarie Hey-Hawkins and Ian Manners introduce the Smart Inorganic Polymers issue of <italic>Chemical Society Reviews</italic>
A Ni supermolecular-networks-coated exfoliated graphene composite is prepared via a facile “two-in-one” electrosynthesis and exhibits excellent supercapacitive performance.
As compared with sulfur, the low reactivity of selenium makes it more challenging to synthesize high quality continuous single layer selenides required for practical applications. Here, we present the synthesis of monolayer MoSe2 by selenization of a pulsed laser deposited MoO3 film on SiO2/Si and sapphire substrates.…
desorbing the anthracene layer at temperatures in the 100 °C to 150 °C range, followed by two sequential annealing steps for the final cleaning, using Pt catalyst and activated carbon. The cleanliness of the suspended graphene membranes was analyzed employing the high surface sensitivity of low energy scanning electro…
Three aspects in the synthesis of oxides under solvothermal conditions are reviewed: materials discovery, substitutional chemistry and crystal habit control.
UCST-type thermoresponsive polypeptides with Y-shaped and ionic liquid pendants were synthesized by a multi-step post-polymerization method.
This manuscript describes the inorganic cubic core as an advantageous scaffold for realizing solid-state emissive materials with high thermal stability.
Stress and strain in thin films of Pr0.1Ce0.9O2-δ, supported on yttria stabilized zirconia (YSZ) and sapphire substrates, induced by large deviations from oxygen stoichiometry (δ = 0) were investigated by in situ high temperature X-ray diffraction and wafer curvature studies. The measured stresses and strains were cor…
This investigation reports the preparation of a pH responsive self-healing nanocomposite hydrogel based on ionic polymer and organically modified montmorillonite (OMMT) clay.
Tunable electronic structures in MPX <sub>3</sub> (M = Zn, Cd; X = S, Se) monolayers by strain are investigated, and the substitution of MX monolayers by MPX <sub>3</sub> is proposed.
In this feature article, we summarize the general aspects and recent progress that have contributed to the development of eco-friendly green synthesis procedures for graphene, including mechanisms, properties, and applications.
Thermoplastic vulcanizates (TPVs), as a special class of high-performance thermoplastic elastomers, have been widely used in the automotive industry, building, and electronics due to their good processability and recyclability.
Aluminum halide, alkoxide and amide complexes 2-6 of the form (N,N)AlX2-nYn (n = 0, 1 and (N,N) = 1,9-dimesityl-5-phenyldipyrromethene (1)) were synthesized and characterized by NMR spectroscopy and X-ray crystallography. The in situ generated lithium salt of dipyrromethene 1 was reacted with AlX3 to afford aluminum h…