Materials Literature
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A novel continuous heterogeneous crystallization process is developed in which the active pharmaceutical ingredient (API) is crystallized directly on the surface of an excipient within the crystallizer. The product is subsequently dried and formed into tablets without the need for complex downstream processing steps,…
Silver-coated gold nanorods (GNRs) with large longitudinal surface plasmon resonance (SPR) wavelength tunability were fabricated by depositing silver (Ag) on the surface of GNRs. Linear and third-order optical nonlinear properties together with the ultrafast response time of these nanorods were investigated. The resul…
Medium manganese austenitic steel (MMAS) fabricated through the hot rolling process has been used in the mining, military, and mechanical industries. In this paper, the abrasion performance and hardening mechanism were measured under a series of impact energies. The impact wear was tested at different impact energies…
In this paper, the temperature dependencies of iron loss under different flux densities, frequencies, and dc bias flux densities are systematically investigated. The temperature dependence of the hysteresis loss varies significantly with the dc bias flux density while that of the eddy current loss is independent of th…
To utilize the lignin generated by the paper industry and reduce the cost of poly(lactic acid) (PLA), PLA/lignin composites were prepared from PLA and different ratios of lignosulfonate (LS) or desulfonated lignosulfonate (DLS) particles using a casting method. The physicochemical properties of the lignins were charac…
The optical interaction of circularly polarized light with structurally chiral optical antennas results in chiral nanophotonics and antenna-enhanced chiral molecular sensing. Here we develop a simple analytical framework, connecting the far-field chiroptical transmission (circular dichroism) of feasible 2D and 3D nano…
The special electronic, optical, thermal, and mechanical properties of graphene resulting from its 2D nature, as well as the ease of functionalizing it through a simple acid treatment, make graphene an ideal building block for the development of new hybrid nanostructures with well-defined dimensions and behavior. Such…
For their use in supercapacitors, aqueous electrolytes of acidic (H 2 SO 4 ), neutral (Na 2 SO 4, K 2 SO 4 ), and basic (NaOH, KOH) nature are studied, using two microporous binder-free and self-standing carbon cloths as electrodes. The carbon cloths show similar porosities and specific surface areas but different con…
Nanocrystal superlattices are typically fabricated by either solvent evaporation or destabilization methods that require long time periods to generate highly ordered structures. In this paper, we report for the first time the use of electric fields to reversibly drive nanocrystal assembly into superlattices without ch…
Flexible transparent barrier films are required in various fields of application ranging from flexible, transparent food packaging to display encapsulation. Environmentally friendly, waterborne polymer–clay nanocomposites would be preferred but fail to meet in particular requirements for ultra high water vapor barrier…
Summary Microemulsion nanofilms based on fish skin gelatine ( FSG ) and 3% (w/w, gelatine) ZnO nanoparticles (Zn ONP ) incorporated with ginger essential oil ( GEO ) at different concentration (10%, 20%, 40%, 80%, w/w, gelatine) were developed and characterised. Film thickness and elongation increased, while film tens…
The electrostatic gating of graphene field-effect transistors is demonstrated using a monolayer electrolyte. The electrolyte, cobalt crown ether phthalocyanine (CoCrPc) and LiClO 4, is deposited as a monolayer on the graphene channel, essentially creating an additional two-dimensional layer on top of graphene. The cro…
Natural melanins are biocompatible conductors with versatile functionalities. Here, we report fabrication of multifunctional poly(vinyl alcohol)/melanin nanocomposites by layer-by-layer (LBL) assembly using melanin nanoparticles (MNPs) directly extracted from sepia officinalis inks. The LBL assembly offers facile mani…
BACKGROUND: The object of this study was to develop a thermally and reactive oxygen species-responsive nanocarrier system for cancer therapy. RESULTS: PPS-PNIPAm block copolymer was designed and synthesised using a combination of living anionic ring-opening polymerization and atom transfer radical polymerization. The…
Quantitative surface-enhanced Raman spectroscopy (SERS) with ultrahigh sensitivity will significantly promote its practical application in many fields, such as environment monitoring, food safety, and drug detection. However, the challenges that remain unresolved, particularly in the low concentration levels, arise fr…
Photoexcitation of spin crossover (SCO) complexes can trigger extensive electronic spin transitions and transformation of molecular structure. However, the precise nature of the associated ultrafast structural dynamics remains elusive, especially in the solid state. Here, we studied a single-crystal SCO material with…
The structure solution from powder diffraction has undergone an intense evolution during the last 20 years, but is far from being routine. Current challenges of powder crystallography include ab initio crystal structure determination on real samples of new materials with specific microstructures, characterization of i…
This study demonstrates how simple structural modification of a prototypical organic ferroelectric molecule can be used to tune its key ferroelectric properties. In particular, it is found that shortening the alkyl chain length of trialkylbenzene‐1,3,5‐tricarboxamide (BTA) from C 18 H 37 to C 6 H 13 causes an increase…
We introduce a label-free biosensing cellulose strip sensor with surface-enhanced Raman spectroscopy (SERS)-encoded bimetallic core@shell nanoparticles. Bimetallic nanoparticles consisting of a synthesis of core Ag nanoparticles (AgNP) and a synthesis of shell gold nanoparticles (AuNPs) were fabricated on a cellulose…
Abstract In this research, multiple-shape memory polymers were prepared from benzoxazine (BA-a) resin and a urethane prepolymer (PU). The effects of BA-a resin content on the thermal, mechanical and multiple-shape memory properties were investigated by differential scanning calorimetry (DSC), thermogravimetric analysi…