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On the Formation and Desolvation Mechanism of Organic Molecule Solvates: A Structural Study of Methyl Cholate Solvates

Agris Be̅rziņš、Aija Trimdale-Deksne、Artis Kons 等 4 位作者2017-09-25Crystal Growth & Design

Solvate formation and the desolvation mechanism of 25 obtained methyl cholate solvates were rationalized using crystal structure analysis and study of the phase transformations. The facile solvate formation was determined to be associated with the possibility for more efficient packing in structures containing solvent…

Crystallography and molecular interactionsNonlinear Optical Materials ResearchCrystallization and Solubility Studies

Overview of Intergranular Fracture of Neutron Irradiated Austenitic Stainless Steels

Anna Hojná2017-09-25Metals

Austenitic stainless steels are normally ductile and exhibit deep dimples on fracture surfaces. These steels can, however, exhibit brittle intergranular fracture under some circumstances. The occurrence of intergranular fracture in the irradiated steels is briefly reviewed based on limited literature data. The data ar…

Microstructure and Mechanical Properties of SteelsFusion materials and technologiesHydrogen embrittlement and corrosion behaviors in metals

Toughening of Epoxy Adhesives by Combined Interaction of Carbon Nanotubes and Silsesquioxanes

Giuseppina Barra、Luigi Vertuccio、Umberto Vietri 等 6 位作者2017-09-25Materials

The extensive use of adhesives in many structural applications in the transport industry and particularly in the aeronautic field is due to numerous advantages of bonded joints. However, still many researchers are working to enhance the mechanical properties and rheological performance of adhesives by using nanoadditi…

Mechanical Behavior of CompositesFiber-reinforced polymer compositesSilicone and Siloxane Chemistry

Advances and challenges in the field of plasma polymer nanoparticles

Andrei Choukourov、Pavel Pleskunov、Daniil Nikitin 等 13 位作者2017-09-25Beilstein Journal of Nanotechnology

This contribution reviews plasma polymer nanoparticles produced by gas aggregation cluster sources either via plasma polymerization of volatile monomers or via radio frequency (RF) magnetron sputtering of conventional polymers. The formation of hydrocarbon, fluorocarbon, silicon- and nitrogen-containing plasma polymer…

Surface Modification and SuperhydrophobicityDust and Plasma Wave PhenomenaElectrohydrodynamics and Fluid Dynamics

A Triblock Copolymer Design Leads to Robust Hybrid Hydrogels for High-Performance Flexible Supercapacitors

Guangzhao Zhang、Yunhua Chen、Yonghong Deng 等 4 位作者2017-09-25ACS Applied Materials & Interfaces

We report here an intriguing hybrid conductive hydrogel as electrode for high-performance flexible supercapacitor. The key is using a rationally designed water-soluble ABA triblock copolymer (termed as IAOAI) containing a central poly(ethylene oxide) block (A) and terminal poly(acrylamide) (PAAm) block with aniline mo…

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

Doping of two-dimensional MoS 2 by high energy ion implantation

Kang Xu、Yuda Zhao、Ziyuan Lin 等 7 位作者2017-09-25Semiconductor Science and Technology

Abstract Two-dimensional (2D) materials have been demonstrated to be promising candidates for next generation electronic circuits. Analogues to conventional Si-based semiconductors, p - and n -doping of 2D materials are essential for building complementary circuits. Controllable and effective doping strategies require…

Graphene research and applications2D Materials and ApplicationsMXene and MAX Phase Materials

Nanotechnologies in Pancreatic Cancer Therapy

Ayesha Manzur、Adeolu Oluwasanmi、Darren Moss 等 5 位作者2017-09-25Pharmaceutics

Pancreatic cancer has been classified as a cancer of unmet need. After diagnosis the patient prognosis is dismal with few surviving over 5 years. Treatment regimes are highly patient variable and often the patients are too sick to undergo surgical resection or chemotherapy. These chemotherapies are not effective often…

Nanoparticle-Based Drug DeliveryPancreatic and Hepatic Oncology ResearchGraphene and Nanomaterials Applications

A Reloadable Self‐Healing Hydrogel Enabling Diffusive Transport of C‐Dots Across Gel–Gel Interface for Scavenging Reactive Oxygen Species

Jing Chen、Shuya Li、Ye Zhang 等 8 位作者2017-09-25Advanced Healthcare Materials

While reloadable drug delivery platforms are highly prized for the treatment of a broad spectrum of diseases, the gel-gel interface between hydrogels hinders the intergel diffusive transport of drugs and thus limits the application of hydrogels as reloadable depots. Here, this study reports the circumvention of this b…

Carbon and Quantum Dots ApplicationsGraphene and Nanomaterials Applications

Novel Strategy toward AIE-Active Fluorescent Polymeric Nanoparticles from Polysaccharides: Preparation and Cell Imaging

Qing Wan、Ruming Jiang、Lili Guo 等 10 位作者2017-09-25ACS Sustainable Chemistry & Engineering

Fluorescent polymeric nanoparticles (FPNs) as novel theranostic agents for cancer diagnosis and treatment have been widely investigated in recent years. However, most FPNs were constructed with typical inorganic quantum dots, fluorescent proteins, and conventional organic dyes, which have still suffered from many obst…

Nanoplatforms for cancer theranosticsLuminescence and Fluorescent MaterialsCarbon and Quantum Dots Applications

Ab initio study of mode-resolved phonon transmission at Si/Ge interfaces using atomistic Green's functions

Benoit Latour、Nina Shulumba、Austin J. Minnich2017-09-25Physical review. B./Physical review. B

Solid interfaces with exceptionally low or high thermal conductance are of intense scientific and practical interest. However, realizing such interfaces is challenging due to a lack of knowledge of the phonon transmission coefficients between specific modes on each side of the interface and how the coefficients are af…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Radiation and Cooling Technologies

Tunable long persistent luminescence in the second near-infrared window via crystal field control

Jianmin Nie、Yang Li、Shanshan Liu 等 6 位作者2017-09-25Scientific Reports

Abstract Construction of an active composite as a biomarker with deeper tissue penetration and higher signal-to-noise ratio (SNR) is of great importance for the application in bioimaging. Here, we report a strategy for tuning the emission bandwidth and intensity via crystal field control in long persistent phosphors (…

Luminescence Properties of Advanced MaterialsNanoplatforms for cancer theranosticsLuminescence and Fluorescent Materials

Spin transport properties based on spin gapless semiconductor CoFeMnSi

Jiangchao Han、Yulin Feng、K.L. Yao 等 4 位作者2017-09-25Applied Physics Letters

Spin gapless semiconductors have been regarded as the most promising candidates for spin injection materials due to the complete (100%) spin polarization and the conductivity between half-metals and semiconductors. To explore the potential spintronic applications of the quaternary Heusler alloy CoFeMnSi (CFMS), a rece…

2D Materials and ApplicationsMXene and MAX Phase MaterialsHeusler alloys: electronic and magnetic properties

Flower-Like Molybdenum Disulfide for Polarity-Triggered Accumulation/Release of Small Molecules

Qizhang Huang、Yueyun Fang、Jifu Shi 等 6 位作者2017-09-25ACS Applied Materials & Interfaces

Flower-like molybdenum disulfide (MoS 2 ) with rich edge sites has been prepared by the hydrothermal method. The edge sites possess polarity due to the noncentrosymmetric Mo–S on exposed (100) facets and thus show a strong electrostatic attraction toward polar species. The flower-like MoS 2 can be used as small-molecu…

Advanced Photocatalysis Techniques2D Materials and ApplicationsMolecular Junctions and Nanostructures

Enhanced EGFR Targeting Activity of Plasmonic Nanostructures with Engineered GE11 Peptide

Francesca Biscaglia、Senthilkumar Rajendran、Paolo Conflitti 等 13 位作者2017-09-25Advanced Healthcare Materials

Plasmonic nanostructures show important properties for biotechnological applications, but they have to be guided on the target for exploiting their potentialities. Antibodies are the natural molecules for targeting. However, their possible adverse immunogenic activity and their cost have suggested finding other valid…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesMonoclonal and Polyclonal Antibodies Research

Effect of Chemical Surface Treatment on Flax-Reinforced Epoxy Composite

Ümit Hüner2017-09-25Journal of Natural Fibers

The aim of this study is to examine the impact of surface modification on properties of flax fiber and flax-reinforced composites. For this purpose, acetic anhydride, sodium hydroxide, and silane were used to treat surface of the flax fiber. The effects of treatments on fiber were investigated by using contact angle,…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research StudiesFiber-reinforced polymer composites

Polaron-Driven Surface Reconstructions

Michele Reticcioli、Martin Setvín、Xianfeng Hao 等 8 位作者2017-09-25Physical Review X

Surface reconstructions in cleaved crystals are generally thought to be driven by charge transfer between surface atoms. New calculations and experiments with rutile titanium dioxide exhibit a radically different mechanism based on charge trapping, which could open up novel ways of designing crystal surfaces for a ran…

ZnO doping and propertiesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Biodegradable zein–polydopamine polymeric scaffold impregnated with TiO 2 nanoparticles for skin tissue engineering

S. Babitha、Purna Sai Korrapati2017-09-25Biomedical Materials

Abstract Polymers from renewable resources are attractive for various industrial and biomedical applications owing to their compatibility, degradability, ease of use and availability. Rapid progress in the development of nanotechnology has improved the characteristic features of polymers in composite materials by rein…

Electrospun Nanofibers in Biomedical ApplicationsWound Healing and TreatmentsSilk-based biomaterials and applications

Pulling with the Pentafluorosulfanyl Acceptor in Push–Pull Dyes

Prabhat Gautam、Craig P. Yu、Guoxian Zhang 等 5 位作者2017-09-25The Journal of Organic Chemistry

functionality is also strongly electron-withdrawing but at the same time highly lipophilic. We report six new fluorescent dyes, which were characterized by UV-vis/fluorescence spectroscopy, single-crystal X-ray diffraction, and cyclic voltammetry. Notable dye properties include large Stokes shifts (>100 nm), pronounce…

Porphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent MaterialsPhotochromic and Fluorescence Chemistry

6-inch uniform vertically-oriented graphene on soda-lime glass for photothermal applications

Haina Ci、Huaying Ren、Yue Qi 等 8 位作者2017-09-25Nano Research

Vertically-oriented graphene (VG) has many advantages over flat lying graphene, including a large surface area, exposed sharp edges, and non-stacking three-dimensional geometry. Recently, VG nanosheets assembled on specific substrates have been used for applications in supersensitive gas sensors and high-performance e…

Graphene research and applicationsGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Plasmonics–Nanofluidics Hydrid Metamaterial: An Ultrasensitive Platform for Infrared Absorption Spectroscopy and Quantitative Measurement of Molecules

Thu Hac Huong Le、Takuo Tanaka2017-09-25ACS Nano

One of the most attractive potentials of plasmonic metamaterials is the amplification of intrinsically weak signals such as molecular infrared absorption or Raman scattering for detection applications. This effect, however, is only effective when target molecules are located at the enhanced electromagnetic field of th…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesPlasmonic and Surface Plasmon Research