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Single Ni Sites Supported on CeO2(111) Reveal Cooperative Effects in the Water–Gas Shift Reaction

Pablo G. Lustemberg、Leticia Feria、M. V. Ganduglia-Pirovano2018-09-03The Journal of Physical Chemistry C

Density functional theory (DFT) calculations have been performed to study the water–gas shift (WGS) reaction mechanism via the formation of a carboxyl (COOH) intermediate over a low-loaded Ni/CeO 2 (111) model catalyst for which adatoms and tiny clusters of nickel are in direct contact with the ceria support. Strong m…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsAmmonia Synthesis and Nitrogen Reduction

Strong absorption of solar energy by using wide band metamaterial absorber designed with plus-shaped resonators

Emın Ünal、Mehmet Bağmancı、Muharrem Karaaslan 等 5 位作者2018-09-03International Journal of Modern Physics B

A new metamaterial absorber (MA) having distinct properties than those given in the literature is investigated. Although several designs have been studied for achieving absorption characteristics in single-band, dual-band and multiple bands within the whole spectrum of solar light, there has been limited number of res…

Metamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface TechnologiesThermal Radiation and Cooling Technologies

Construction of Self-defensive Antibacterial and Osteogenic AgNPs/Gentamicin Coatings with Chitosan as Nanovalves for Controlled release

Wenhao Zhou、Yangyang Li、Jianglong Yan 等 7 位作者2018-09-03Scientific Reports

Abstract To solve the Ti implants-associated infection and poor osseointegration problems, we have constructed the AgNPs/gentamicin (Gen)-loaded silk fibroin (SF) coating with acceptable antibacterial and osteogenic aptitude. Nevertheless, due to uncontrollably sustained drug release, this bactericidal coating encount…

RNA Interference and Gene DeliveryPolymer Surface Interaction StudiesSilk-based biomaterials and applications

Enhancement of paperboard performance as packaging material by layering with plasticized polyhydroxybutyrate/nanocellulose coatings

Irene T. Seoane、Francesca Luzi、Débora Puglia 等 5 位作者2018-09-03Journal of Applied Polymer Science

ABSTRACT Paper presents low water vapor barrier capacity that is considered a limitation for its use in packaging applications. Therefore, the effect of using polyhydroxybutyrate (PHB)‐based coatings containing a plasticizer [Tributyrin (TB)] and cellulose nanocrystals (CNCs) in a bilayer configuration with paperboard…

Nanocomposite Films for Food PackagingAdvanced Cellulose Research Studiesbiodegradable polymer synthesis and properties

Cu1.5PMo12O40‐catalyzed condensation cyclization for the synthesis of substituted pyrazoles

Guo‐Ping Yang、Xing He、Bing Yu 等 4 位作者2018-09-03Applied Organometallic Chemistry

A convenient and direct approach has been developed for the preparation of pyrazole derivatives by the condensation cyclization of hydrazines/hydrazide and 1,3‐diketones in the presence of Cu 1.5 PMo 12 O 40 (0.33 mol%) under mild conditions (r.t.‐60 °C, 10–30 min). Notably, the reaction was found to be scalable as 99…

Polyoxometalates: Synthesis and ApplicationsChemical Synthesis and ReactionsSulfur-Based Synthesis Techniques

Functional gradient effects on the energy absorption of spider orb webs

Yang Guo、Zheng Chang、Bo Li 等 7 位作者2018-09-03Applied Physics Letters

Owing to their exquisite geometric structures and excellent mechanical properties, spider orb webs possess an outstanding ability to capture flying prey. In this work, we report a mechanism that enhances the energy absorption ability of spider webs. Through systematic measurements of the mechanical properties of both…

Surface Modification and SuperhydrophobicityAdhesion, Friction, and Surface InteractionsSilk-based biomaterials and applications

Development of a KNN Ceramic-Based Lead-Free Linear Array Ultrasonic Transducer

Zhiqiang Zhang、Ruimin Chen、Bo Wang 等 14 位作者2018-09-03IEEE Transactions on Ultrasonics Ferroelectrics and Frequency Control

High-frequency array transducers can provide higher imaging resolution than traditional transducers, thus resolving smaller features and producing finer images. Commercially available ultrasonic transducers are mostly made with lead-based piezoelectric materials, which are harmful to the environment and public health.…

Ferroelectric and Piezoelectric MaterialsUltrasound Imaging and ElastographyAcoustic Wave Resonator Technologies

Geomagnetic Disturbances and Impacts upon Power System Operation

John G. Kappenman2018-09-03OpenAlex

The onset of important power system problems can be assessed in part by experience from contemporary geomagnetic storms. Power networks are operated using what is termed an “N–1” operation criterion. That is, the system must always be operated to withstand the next credible disturbance contingency without causing a ca…

Geophysical and Geoelectrical MethodsLightning and Electromagnetic PhenomenaMagnetic Properties and Applications

Covalently Assembled Dipeptide Nanoparticles with Adjustable Fluorescence Emission for Multicolor Bioimaging

Shukun Li、Yamei Liu、Ruirui Xing 等 4 位作者2018-09-03ChemBioChem

Abstract Peptide self‐assembly, inspired by the naturally occurring fabrication principle, remains the most attractive in constructing fluorescent nanoagents towards bioimaging. However, the noncovalent interactions that drive peptide self‐assembly are usually susceptible to the complex physiological environment; thus…

Nanoplatforms for cancer theranosticsLuminescence and Fluorescent MaterialsSupramolecular Self-Assembly in Materials

Evaluation of Toxicity and Neural Uptake In Vitro and In Vivo of Superparamagnetic Iron Oxide Nanoparticles

Muhammad Kamran Khalid、Muhammad Asad、Petra Henrich‐Noack 等 10 位作者2018-09-03International Journal of Molecular Sciences

Superparamagnetic iron oxide nanoparticles (SPIO-NPs) have great potential to be used in different pharmaceutical applications, due to their unique and versatile physical and chemical properties. The aim of this study was to quantify in vitro cytotoxicity of dextran 70,000-coated SPIO-NPs labelled/unlabelled with rhod…

Nanoparticle-Based Drug DeliveryCharacterization and Applications of Magnetic NanoparticlesGraphene and Nanomaterials Applications

Orientation-controlled, low-temperature plasma growth and applications of h-BN nanosheets

I. S. Merenkov、Mikhail S. Myshenkov、Irina A. Zvereva 等 14 位作者2018-09-03Nano Research

Dimensionality and orientation of hexagonal boron nitride (h-BN) nanosheets are promising to create and control their unique properties for diverse applications. However, low-temperature deposition of vertically oriented h-BN nanosheets is a significant challenge. Here we report on the low-temperature plasma synthesis…

Graphene research and applicationsBoron and Carbon Nanomaterials ResearchGraphene and Nanomaterials Applications

A Flat Panel Photodetector Formed by a ZnS Photoconductor and ZnO Nanowire Field Emitters Achieving High Responsivity From Ultraviolet to Visible Light for Indirect-Conversion X-Ray Imaging

Zhipeng Zhang、Kai Wang、Keshuang Zheng 等 6 位作者2018-09-03Journal of Lightwave Technology

Flat panel photodetectors have been well studied for their applications in large area detection such as indirect-conversion X-ray imaging. Even though a few of photodetectors have become commercially available, there is still a room for advancement in responsive wavelength range and sensitivity. This paper reports a s…

Radiation Detection and Scintillator TechnologiesPhotoacoustic and Ultrasonic ImagingGa2O3 and related materials

Nano‐Graphene as Groundbreaking Miracle Material: Catalytic and Commercial Perspectives

Santosh Bahadur Singh、Chaudhery Mustansar Hussain2018-09-03ChemistrySelect

Abstract Over the past decade, nano‐graphene has emerged as one of the miraculous materials to mankind because of its outstanding electronic, optical, thermal, and mechanical properties. Unique characteristics of nano‐graphene make it more attractive for development of new metal‐free green heterogeneous catalysts espe…

Advanced Photocatalysis TechniquesGraphene research and applicationsNanomaterials for catalytic reactions

Effective surface tension of liquid marbles using controllable nanoparticle monolayers

Xiaoguang Li、Renxian Wang、Haixiao Shi 等 4 位作者2018-09-03Applied Physics Letters

The effective surface tension (γeff) of liquid marbles is a frequently used, but perplexing concept and clarifying this tension has been challenging, mainly due to difficulties in controlling affecting factors from marble surface particles, including particle agglomeration and areal particle density. In this study, we…

Surface Modification and SuperhydrophobicityProteins in Food SystemsPickering emulsions and particle stabilization

Multiwall MoS2 tubes as optical resonators

D. R. Kazanov、A. V. Poshakinskiy、V. Yu. Davydov 等 12 位作者2018-09-03Applied Physics Letters

We study the optical properties of MoS2 nanotubes (NTs) with walls comprising dozens of monolayers. We reveal strong peaks in micro-photoluminescence (μ-PL) spectra when detecting the light polarized along the NT axis. We develop a model describing the optical properties of the nanotubes acting as optical resonators w…

2D Materials and ApplicationsPhotonic and Optical DevicesMolecular Junctions and Nanostructures

VO 2 @SiO 2 /Poly( N -isopropylacrylamide) Hybrid Nanothermochromic Microgels for Smart Window

Yu Wang、Fang Zhao、Jie Wang 等 10 位作者2018-09-03Industrial & Engineering Chemistry Research

VO 2 /PNIPAm hybrid thermochromic material has been verified as promising to improve optical performance of smart windows. However, VO 2 can be easily oxidized especially when being dispersed in the hydrogel matrix, and also the nonuniform dispersion of VO 2 in a host will worsen the material’s optical performance. He…

TiO2 Photocatalysis and Solar CellsOptical Wireless Communication TechnologiesTransition Metal Oxide Nanomaterials

Energy transfer and color‐tunable emission in Ba 2 Y 2 Si 4 O 13 :Bi 3+ ,Eu 3+ phosphors

Weihui Song、Xueyan Chen、Liming Teng 等 9 位作者2018-09-03Journal of the American Ceramic Society

Abstract Single‐composition Ba 2 Y 2 Si 4 O 13 :Bi 3+ ,Eu 3+ (BYSO:Bi 3+ ,Eu 3+ ) phosphors with color‐tunable and white emission were prepared by conventional high temperature solid‐state reaction method. The structural and luminescent properties of these phosphors were thoroughly investigated through X‐ray diffracti…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsSolid-state spectroscopy and crystallography

Large tunnel magnetoresistance and temperature-driven spin filtering effect based on the compensated ferrimagnetic spin gapless semiconductor Ti2MnAl

Jiangchao Han、Guoying Gao2018-09-03Applied Physics Letters

Spin gapless semiconductors, also known a special class of half-metallic magnets, have received more and more attention in spintronic applications due to the complete spin polarization and the electrical conductivity between half-metals and semiconductors. Motivated by the recent synthesis of spin gapless semiconducto…

2D Materials and ApplicationsQuantum and electron transport phenomenaHeusler alloys: electronic and magnetic properties

Composite of polyaniline‐bismuth selenide with enhanced thermoelectric performance

M. Mitra、Chiranjit Kulsi、Kajari Kargupta 等 5 位作者2018-09-03Journal of Applied Polymer Science

ABSTRACT Conducting polymer‐chalcogenide composites have recently been used as propitious contenders for light‐weight, cost‐saving, and nonhazardous thermoelectric (TE) applications. In this work, polyaniline‐bismuth selenide (PANI‐Bi 2 Se 3 ) nanoplate composites are fabricated via combining in situ oxidative polymer…

Perovskite Materials and ApplicationsAdvanced Thermoelectric Materials and DevicesConducting polymers and applications

Effect of the functional group of silanes on the modification of silica surface and the physical properties of solution styrene-butadiene rubber/silica composites

Byungkyu Ahn、Donghyuk Kim、Kihyun Kim 等 8 位作者2018-09-03Composite Interfaces

Silica compounds were prepared using non-functionalized solution styrene-butadiene rubber (SSBR) to investigate effect of the functional group of silanes on the silica modification and properties of SSBR/silica compounds. Bis-[3-(triethoxysilyl)propyl]disulfide (TESPD), 3-mercaptopropyltriethoxysilane (MPTES), 3-amino…

Polymer Nanocomposites and PropertiesSynthesis and properties of polymersSilicone and Siloxane Chemistry