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Na2B2Se7, K2B2S7 und K2B2Se7: Drei Perchalkogenoborate mit neuem polymeren Anionengerüst

A. Hammerschmidt、J. Küper、Ludwig Stork 等 4 位作者1994-11-01Zeitschrift für anorganische und allgemeine Chemie

Abstract Na 2 B 2 Se 7 (I 2/a; a = 11,863(4) Å, b = 6,703(2) Å, c = 13,811(6) Å, β = 109,41(2)°; Z = 4); K 2 B 2 S 7 (I 2/a; a = 11,660(2) Å, β = 6,827(1) Å, c = 12,992(3) Å, β = 106,78(3)°; Z = 4) und K 2 B 2 Se 7 (I 2/a; a = 12,092(4) Å, b = 7,054(2) Å, c = 13,991(5) Å, β = 107,79(3)°; Z = 4) wurden durch Reaktion s…

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyInorganic Chemistry and Materials

Modeling of the Factors Contributing to the Initiation and Propagation of the Crevice Corrosion of Alloy 625

R. S. Lillard、John R. Scully1994-11-01Journal of The Electrochemical Society

Crevice corrosion of alloy 625 in both chlorinated and nonchlorinated American Society for Testing and Materials (ASTM) artificial ocean water was modeled. Secondary current and potential distributions as a function of crevice depth were obtained from the model using the following crevice initiation criteria ( i ) E <…

Corrosion Behavior and InhibitionHigh-Temperature Coating BehaviorsHydrogen embrittlement and corrosion behaviors in metals

Molecular Dynamics Simulation of the Collapse of Poly(1,4-trans-butadiene) to Globule and to a Thin Film

Yongjian Zhan、Wayne L. Mattice1994-11-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMolecular Dynamics Simulation of the Collapse of Poly(1,4-trans-butadiene) to Globule and to a Thin FilmYongjian Zhan and Wayne L. MatticeCite this: Macromolecules 1994, 27, 24, 7056–7062Publication Date (Print):November 1, 1994Publication History Published online1 May 2002P…

Polymer crystallization and properties

Rapid chemography of porous silicon undergoing hydrolysis

Leigh Canham、S Saunders、Paul B. Heeley 等 5 位作者1994-11-01Advanced Materials

Highly porous silicon reacts with water vapor in the air to create images on photographic plates within seconds. It is demonstrated that this process, known as chemography, can be used diagnostically to reveal inhomogeneity in porous silicon layers that is not always detectable by optical or electron microscopy. It is…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Mononuclear Barium Diketonate Polyamine Adducts. Synthesis, Structures, and Use in MOCVD of Barium Titanate

R. A. Gardiner、Douglas C. Gordon、Gregory T. Stauf 等 6 位作者1994-11-01Chemistry of Materials

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMononuclear Barium Diketonate Polyamine Adducts. Synthesis, Structures, and Use in MOCVD of Barium TitanateRobin A. Gardiner, Douglas C. Gordon, Gregory T. Stauf, Brian A. Vaartstra, Robert L. Ostrander, and Arnold L. RheingoldCite this: Chem. Mater. 1994, 6, 11, 1967–1970Pu…

Corrosion Behavior and InhibitionPolymer Nanocomposites and PropertiesSilicone and Siloxane Chemistry

Synthesis and Characterization of Zincosilicates with the SOD Topology

Miguel Á. Camblor、Raúl F. Lobo、Hubert Koller 等 4 位作者1994-11-01Chemistry of Materials

The incorporation of Zn^(2+) into tetrahedral framework positions of zeolites with the sodalite topology (SOD) is obtained by direct synthesis. The zincosilicates are characterized by thermal analyses, a Rietveld refinement of powder X-ray diffraction (XRD) data, and infrared&#13;\n(IR) and ^1H, ^(23)Na, ^(13)C, and ^…

Catalytic Processes in Materials ScienceZeolite Catalysis and SynthesisMesoporous Materials and Catalysis

Heteroepitaxy of Syndiotactic Polypropylene with Polyethylene and Homoepitaxy

Martina Schumacher、Andrew J. Lovinger、Pawan Agarwal 等 5 位作者1994-11-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHeteroepitaxy of Syndiotactic Polypropylene with Polyethylene and HomoepitaxyM. Schumacher, A. J. Lovinger, P. Agarwal, J. C. Wittmann, and B. LotzCite this: Macromolecules 1994, 27, 23, 6956–6962Publication Date (Print):November 1, 1994Publication History Published online1…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesFiber-reinforced polymer composites

Rheological and Mechanical Properties of Filled Rubber: Silica-Silicone

Mirta I. Aranguren、Elsi Mora、Christopher W. Macosko 等 4 位作者1994-11-01Rubber Chemistry and Technology

Abstract This work focuses on the relationship between the morphology of filled rubbers and their behavior at small and large deformations. Composites were made from vinyl terminated polydimethylsiloxane (PDMS) and different fumed silicas. Filler concentration range was kept between 0 to 40 phr (parts of silica per hu…

Advanced Fiber Optic SensorsPolymer Nanocomposites and PropertiesSilicone and Siloxane Chemistry

Studies on Aliphatic Portion of Coal Organic Materials Based on Ruthenium Ion Catalyzed Oxidation

Satoru Murata、Kohji Uesaka、Hirohiko Ino-ue 等 4 位作者1994-11-01Energy & Fuels

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStudies on Aliphatic Portion of Coal Organic Materials Based on Ruthenium Ion Catalyzed OxidationSatoru Murata, K. U-esaka, Hirohiko Ino-ue, and Masakatsu NomuraCite this: Energy Fuels 1994, 8, 6, 1379–1383Publication Date (Print):November 1, 1994Publication History Publishe…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization Studies

Pt2+ vs. Pt4+ in AsS33- Solutions and Isolation of the Clusters [Pt(As3S5)2]2- and [Pt3(AsS4)3]3-. Observation of Unique Thioarsenate ligands and Pt-As Bonds

Jun-Hong Chou、Mercouri G. Kanatzidis1994-11-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPt2+ vs. Pt4+ in AsS33- Solutions and Isolation of the Clusters [Pt(As3S5)2]2- and [Pt3(AsS4)3]3-. Observation of Unique Thioarsenate ligands and Pt-As BondsJun-Hong Chou and Mercouri G. KanatzidisCite this: Inorg. Chem. 1994, 33, 24, 5372–5373Publication Date (Print):Novemb…

Crystal Structures and PropertiesOrganometallic Compounds Synthesis and CharacterizationInorganic Chemistry and Materials

GRP2 proteins contain both CCHC zinc fingers and a cold shock domain.

Paul D. Kingsley、James Palis1994-11-01The Plant Cell

P D Kingsley, J Palis; GRP2 proteins contain both CCHC zinc fingers and a cold shock domain., The Plant Cell, Volume 6, Issue 11, 1 November 1994, Pages 1522–15

Protein Structure and DynamicsHeat shock proteins researchEnzyme Structure and Function

Viability of Adipose Tissue Injected and Treated by Different Methods: An Experimental Study in the Rat

Rony Moscona、Oren Shoshani、H Lichtig 等 4 位作者1994-11-01Annals of Plastic Surgery

Fat injection is being used for the correction of various soft-tissue defects. In this study, the manner of fat injection yielding the greatest transplant viability was examined. Autologous fat was obtained from the inguinal area of rats and subsequently reinjected to the nuchal region, an area naturally poor in subcu…

Mesenchymal stem cell researchReconstructive Surgery and Microvascular TechniquesElectrospun Nanofibers in Biomedical Applications

Enhanced Blue-Light Emission from an Indium-Treated Porous Silicon Device

Peter Steiner、F. Kozlowski、M. Wieluński 等 4 位作者1994-11-01Japanese Journal of Applied Physics

We present the technology and the performance of blue-light-emitting porous silicon devices. The devices are fabricated using porous silicon formation with UV-light applied. Furthermore, indium is electroplated into the pores, causing an increase of the quantum efficiency. The blue electroluminescence exhibits a peak…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Polar‐Oriented Crystallization of Fresnoite (Ba 2 TiSi 2 O 8 ) on Glass Surface Due to Ultrasonic Treatment with Suspensions

Yong Ding、Yoshinari Miura、Akiyoshi Osaka1994-11-01Journal of the American Ceramic Society

Improved polar ( c ‐axis) oriented growth of fresnoite (Ba 2 TiSi 2 O 8 ) was observed for surface crystallization of a glass 33.3BaO· 16.7TiO 2 · 50SiO 2 (in mol%) due to ultrasonic surface treatment with an aqueous suspension of Ba 2 TiSi 2 O 8 , and an oriented film more than 50 μm in thickness was prepared. The ef…

Ferroelectric and Piezoelectric MaterialsGlass properties and applicationsBuilding materials and conservation

Dynamics of lyotropic ferronematic liquid crystals submitted to magnetic fields

J.-C. Bacri、A. M. Figueiredo Neto1994-11-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

The dynamical behavior of lyotropic ferronematic liquid crystals of potassium laurate, decanol (or decilamonium chloride), water, and ferrofluid is studied by means of optical techniques, under the influence of magnetic fields. Making use of interferometric measurements, three different processes, with typical charact…

Liquid Crystal Research AdvancementsNonlinear Dynamics and Pattern Formation

Structural and Magnetic studies on a Bromine-Bridged Copper(II) Dimer with 5,7-Dimethyl[1,2,4]triazolo[1,5-a]pyrimidine

M.A. Romero、Juan M. Salas、M. Quirós 等 6 位作者1994-11-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStructural and Magnetic studies on a Bromine-Bridged Copper(II) Dimer with 5,7-Dimethyl[1,2,4]triazolo[1,5-a]pyrimidineM. Angustias Romero, Juan M. Salas, Miguel Quiros, M. Purificacion Sanchez, Jose Romero, and Daniel MartinCite this: Inorg. Chem. 1994, 33, 24, 5477–5481Pub…

Metal complexes synthesis and propertiesMagnetism in coordination complexesSynthesis and Reactivity of Heterocycles

Reducing NOx in diesel exhausts by SCR technique: Experiments and simulations

Stig Andersson、Pär Gabrielsson、C.U. Ingemar Odenbrand1994-11-01AIChE Journal

Abstract Results of experiments are compared to simulations of the performance of V 2 O 5 /γ‐alumina SCR catalyst used to remove nitrogen oxides from diesel exhausts. The kinetic model is based on Eley‐Rideal kinetics. Temperature programmed desorption (TPD) of the ammonia is used to evaluate adsorption/desorption par…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsIndustrial Gas Emission Control

Symmetry adapted cluster-configuration interaction study on the excited and ionized states of TiBr4 and TiI4

Hiroshi Nakatsuji、Masahiro Ehara1994-11-01The Journal of Chemical Physics

The symmetry adapted cluster-configuration interaction (SAC-CI) method is briefly reviewed and applied to the excitation and ionization spectra of TiX4 (X=Br, I). The valence excited states of these molecules are investigated systematically and compared with the previous study on TiCl4. The experimental spectra are we…

Luminescence Properties of Advanced MaterialsAmmonia Synthesis and Nitrogen ReductionInorganic Fluorides and Related Compounds

Ab Initio Study of Structures and Energetics of Small Copper-Selenium Clusters

Ansgar Schaefer、Reinhart Ahlrichs1994-11-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAb Initio Study of Structures and Energetics of Small Copper-Selenium ClustersAnsgar Schaefer and Reinhart AhlrichsCite this: J. Am. Chem. Soc. 1994, 116, 23, 10686–10692Publication Date (Print):November 1, 1994Publication History Published online1 May 2002Published inissue…

Advanced Chemical Physics StudiesNanocluster Synthesis and Applicationsnanoparticles nucleation surface interactions

Elastic properties ofB2-NiTi andB2-PdTi

Gustav Bihlmayer、R. Eibler、A. Neckel1994-11-01Physical review. B, Condensed matter

Elastic constants of the high-temperature phases of the shape-memory alloys NiTi and PdTi are determined by means of full-potential linearized augmented-plane-wave total-energy calculations. Thereby, insight into the driving mechanism of the martensitic transformation of these alloys can be obtained. In the case of Ni…

High-pressure geophysics and materialsShape Memory Alloy TransformationsIntermetallics and Advanced Alloy Properties