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Metabolic pathway for poly(3-hydroxybutyrate-co-3-hydroxyvalerate) formation in Nocardia corallina: inactivation of mutB by chromosomal integration of a kanamycin resistance gene

H F Valentin、Douglas Dennis1996-02-01Applied and Environmental Microbiology

The gene encoding the large subunit of the methylmalonyl-coenzyme A (CoA) mutase in Nocardia corallina (mutBNc) was cloned. A 4.3-kbp BamHI fragment containing almost the entire mutBNc was identified by Southern hybridization experiments employing a digoxigenin-labeled probe deduced from mutB of Streptomyces cinnamone…

Biofuel production and bioconversionEnzyme Catalysis and Immobilizationbiodegradable polymer synthesis and properties

The “Peroxo Perrhenic Acid” H4Re2O13: An Oxygen‐Rich Metal Peroxide and Oxidation Catalyst

Wolfgang A. Herrmann、João D. G. Correia、Fritz E. Kühn 等 5 位作者1996-02-01Chemistry - A European Journal

Abstract The rhenium oxides Re 2 O 7 and ReO 3 react with hydrogen peroxide solutions yielding peroxo complexes that efficiently catalyze the oxidation of olefins, aromatics, and certain organometallic compounds. In contrast, related oxides of molybdenum (MoO 3 ) and vanadium (V 2 O 5 ) do not activate H 2 O 2 under c…

Polyoxometalates: Synthesis and ApplicationsCatalysis and Oxidation ReactionsGa2O3 and related materials

Full-potential linear-muffin-tin-orbital calculations of the magnetic properties of rare-earth–transition-metal intermetallics. I. Description of the formalism and application to the seriesRCo5(R=rare-earth atom)

K. Hummler、M. Fähnle1996-02-01Physical review. B, Condensed matter

For the series R${\mathrm{Co}}_{5}$ (R=rare-earth atom) various parameters occurring in the two-sublattice model of rare-earth--transition-metal intermetallics (local magnetic moments, intersublattice exchange fields, crystal field parameters, as well as magnetic hyperfine fields and electric field gradients) are calc…

Magnetic properties of thin filmsRare-earth and actinide compoundsMagnetic Properties of Alloys

Granitic melt viscosities; empirical and configurational entropy models for their calculation

Don R. Baker1996-02-01American Mineralogist

Other| February 01, 1996 Granitic melt viscosities; empirical and configurational entropy models for their calculation Don R. Baker Don R. Baker McGill University, Department of Earth and Planetary Sciences, Montreal, PQ, Canada Search for other works by this author on: GSW Google Scholar Author and Article Informatio…

Geological and Geochemical AnalysisMaterial Dynamics and PropertiesGlass properties and applications

Reliability of the Simplified Integral-Breadth Methods in Diffraction Line-Broadening Analysis

Davor Balzar、S. Popović1996-02-01Journal of Applied Crystallography

A comparison between different simplified integral-breadth methods, often used in the Rietveld-refinement programs to calculate coherent domain size and lattice strain, is carried out. It is shown that systematic differences exist for both domain size and strain, when they simultaneously broaden diffraction lines. Amo…

Electron and X-Ray Spectroscopy TechniquesNon-Destructive Testing TechniquesX-ray Diffraction in Crystallography

Growth-Associated Production of Poly(3-Hydroxyvalerate) from n-Pentanol by a Methylotrophic Bacterium, Paracoccus denitrificans

Tsuneo Yamané、Xiaoqi Chen、Satoko Ueda1996-02-01Applied and Environmental Microbiology

Paracoccus denitrificans accumulated a polyester in its cells during growth on n-pentanol. The composition of the polyester varied during the cultivation: the level of the 3-hydroxyvalerate unit in the polyester increased, and eventually a homopolymeric poly(3-hydroxyvalerate) [P(3HV)] accumulated to an amount 22 to 2…

Biofuel production and bioconversionEnzyme Catalysis and Immobilizationbiodegradable polymer synthesis and properties

Optical properties of tin-doped indium oxide determined by spectroscopic ellipsometry

Tobias Gerfin、Michaël Grätzel1996-02-01Journal of Applied Physics

Sputtered tin-doped indium oxide (ITO) coatings were investigated by UV-visible spectroscopic ellipsometry at different angles of incidence. The results were fitted using a classical dispersion formula for the optical constants of ITO in a model structure with a compact homogeneous film and a top layer representing su…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

Optical spectroscopy ofCr4+-dopedCa2GeO4andMg2SiO4

M.F. Hazenkamp、Hans U. Güdel、Mihail Atanasov 等 5 位作者1996-02-01Physical review. B, Condensed matter

Polarized single crystal absorption spectra and luminescence spectra of ${\mathrm{Cr}}^{4+}$-doped ${\mathrm{Ca}}_{2}$${\mathrm{GeO}}_{4}$ and ${\mathrm{Mg}}_{2}$${\mathrm{SiO}}_{4}$ are presented and discussed. The absorption spectra are analyzed using the angular overlap model (AOM). The agreement between the experi…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsLanthanide and Transition Metal Complexes

Relative coherency strain and phase transformation history in epitaxial ferroelectric thin films

C. M. Foster、W. Pompe、A.C. Daykin 等 4 位作者1996-02-01Journal of Applied Physics

Experimental evidence is presented to verify the quantitative predictions of interfacial defect theory as applied to strain relief in epitaxial PbTiO3 thin films through the formation of 90° domains. Epitaxial PbTiO3 thin films grown by metal-organic chemical vapor deposition on MgO(001), SrTiO3(001), LaAlO3(001), and…

Ferroelectric and Piezoelectric MaterialsNuclear materials and radiation effectsElectronic and Structural Properties of Oxides

The Effect of Fuel and Engine Design on Diesel Exhaust Particle Size Distributions

Kirby J. Baumgard、John H. Johnson1996-02-01SAE technical papers on CD-ROM/SAE technical paper series

<div class="htmlview paragraph">The objective of this research was to obtain diesel particle size distributions from a 1988 and a 1991 diesel engine using three different fuels and two exhaust control technologies (a ceramic particle trap and an oxidation catalytic converter). The particle size distributions fro…

Advanced Combustion Engine TechnologiesCatalytic Processes in Materials ScienceVehicle emissions and performance

Canted antiferromagnetism in an insulating lightly dopedLa1−xSrxMnO3withx⩽0.17

H. Kawano、Ryoichi Kajimoto、Masato Kubota 等 4 位作者1996-02-01Physical review. B, Condensed matter

We have investigated the magnetic structure of an insulating lightly doped ${\mathrm{La}}_{1\mathrm{\ensuremath{-}}\mathit{x}}$${\mathrm{Sr}}_{\mathit{x}}$${\mathrm{MnO}}_{3}$ with x=0.04,0.125, and 0.17 with neutron scattering technique and bulk magnetization measurements. The magnetic structure of the x=0.04 sample…

Physics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Filler Debonding in Particulate-Filled Composites

V. F. Babich、Yu.S. Lipatov、Tamara Todosijchuk1996-02-01The Journal of Adhesion

The decrease in Young's modulus after mechanically loading particulate-filled composites serves as a measure of the fraction of debonded filler particles. For composites based on plasticized rubber and fine ammonium perchlorate these effects have been studied for various stresses and for both varying amounts and parti…

Mechanical Behavior of CompositesPolymer crystallization and propertiesPolymer Nanocomposites and Properties

AN EXPERIMENTAL INVESTIGATION INTO THE FOAMING TENDENCY OF DIETHANOLAMINE GAS SWEETENING SOLUTIONS

J. Michael McCarthy、Mark A. Trebble1996-02-01Chemical Engineering Communications

The foaming tendency of a 30 weight % solution of diethanolamine (DEA) in distilled water was measured over a temperature range of 20-85°C and a pressure range of 1-3 MPa in the presense of a number of contaminants including carboxylic acids, oils, 1-4 bis (2-hydroxyethyl) piperazine (HEP), methanol, iron sulphide, si…

Pickering emulsions and particle stabilization

Effect of intramolecular interactions on the miscibility windows of PVC blends with modified SAN copolymers

Chul‐Hwan Kim、Jung-Ki Park、Taek‐Sung Hwang1996-02-01Polymer Engineering and Science

Abstract We investigated the miscibility windows in the blends of poly(vinyl chloride) (PVC) with chemically modified styrene/acrylonitrile (SAN) copolymers such as α‐methyl styrene/acrylonitrile (α SAN), α‐methyl styrene/methacrylonitrile (MSMAN). The blends of PVC with α SAN were found to have the broader miscibilit…

Polymer crystallization and propertiesRecycling and Waste Management TechniquesPolymer Science and PVC

Analysis of Tempering Stresses in Metal-Ceramic Disks

P.H. Dehoff、Kenneth J. Anusavice、Suresh B. Vontivillu1996-02-01Journal of Dental Research

Previous studies showed that residual compressive stresses induced by thermal tempering retarded the growth of surface cracks in bilayered porcelain disks. The objectives of the present study were: (1) to determine whether thermal tempering by air blasting reduces the length of cracks induced by microhardness indentat…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsAdvanced materials and composites

Discontinuous and continuous annealing phenomena in aluminium–nickel alloy

F.J. Humphreys、Helen M. Chan1996-02-01Materials Science and Technology

The annealing behaviour of an Al–6 wt-%Ni alloy containing a dispersion of second phase particles has been studied. It is shown that for a particle diameter of 0·3μm, annealing takes place by extended recovery. However, for a particle diameter of 1·7 μm, discontinuous recrystallisation occurs. The relationship between…

Microstructure and mechanical propertiesAluminum Alloy Microstructure PropertiesAluminum Alloys Composites Properties

Alkalimanganselenide und ‐telluride A 2 Mn 3 X 4 – Synthese, Kristall‐ und Spinstruktur

W. Bronger、H. Hardtdegen、M. Kanert 等 5 位作者1996-02-01Zeitschrift für anorganische und allgemeine Chemie

Abstract Die Verbindungen Rb 2 Mn 3 Se 4 , Cs 2 Mn 3 Se 4 , Rb 2 Mn 3 Te 4 und Cs 2 Mn 3 Te 4 wurden durch Umsetzungen von Alkalimetallcarbonaten mit Mangan oder Mangancarbonat und Chalkogen in einem mit Chalkogen beladenen Wasserstoffstrom erhalten. Kristallstrukturuntersuchungen ergaben, daß alle Verbindungen isotyp…

Crystal Structures and PropertiesIron-based superconductors researchInorganic Chemistry and Materials

Long-Term Prediction of Localized Corrosion of Alloy 825 in High-Level Nuclear Waste Repository Environments

D. S. Dunn、Narasi Sridhar、G. Cragnolino1996-02-01CORROSION

Long-term prediction of localized corrosion of high-level nuclear waste container materials is a necessary step in the performance assessment of the engineered barrier system. Localized corrosion of corrosion-resistant materials may occur if the containers are exposed to chloride (Cl–)-containing ground water at eleva…

Hydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and DurabilityNon-Destructive Testing Techniques

Monte Carlo Simulation of the Director Field of a Nematic Liquid Crystal with Three Elastic Coefficients

Thomas Gruhn、S. Heß1996-02-01Zeitschrift für Naturforschung A

Abstract In this article, a Monte Carlo simulation is presented, which generates the equilibrium director field of a nematic liquid crystal under the influence of an external field and fixed boundary conditions. The liquid crystal is characterized by a set of directors on a spatially fixed lattice. The simulation is b…

Liquid Crystal Research AdvancementsTheoretical and Computational PhysicsNonlinear Dynamics and Pattern Formation

Particle Size Determination by Laser Reflection: Methodology and problems

Olivier Monnier、Jean‐Paul Klein、Berthe Ratsimba 等 4 位作者1996-02-01Particle & Particle Systems Characterization

Abstract The particle size distribution of crystalline solids has progressively become a key parameter in manufacturing processes, as important as chemical purity. Among the particle size determination and counting systems available on the market, very few offer the possibility of continuous in situ monitoring of the…

Fluid Dynamics and MixingMinerals Flotation and Separation TechniquesCrystallization and Solubility Studies