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Rhodium and Rhodium Oxide Thin Films Characterized by XPS

Yoshio Abe、Kiyohiko Kato、Midori Kawamura 等 4 位作者2001-04-01Surface Science Spectra

RhO2 belongs to the family of conducting platinum group metal oxides, which have attracted attention as new capacitor electrode materials for dynamic random access memories (DRAMs) and nonvolatile ferroelectric random access memories (FeRAMs). Rh, Rh2O3, and RhO2 thin films were prepared by sputtering and their XPS sp…

Magnetic properties of thin filmsElectron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysis

Pressureless Sintering and Properties of Titanium Diboride Ceramics Containing Chromium and Iron

Shin Hyuk Kang、Deug J. Kim、Eul Son Kang 等 4 位作者2001-04-01Journal of the American Ceramic Society

The simultaneous addition of 0.5 wt% Cr and Fe was found to enhance the densification of TiB 2 . The densities of specimens that were sintered for 2 h at 1800° and 1900°C were 97.6% and 98.8% of the theoretical value, respectively. The mechanical properties of the specimen sintered at 1800°C, which had a strength of 5…

Advanced ceramic materials synthesisBoron and Carbon Nanomaterials ResearchAdvanced materials and composites

One-Step Synthesis of a Highly Active, Mesoporous, Titanium-Containing Silica by Using Bifunctional Templating

Z. Shan、Enrica Gianotti、J.C. Jansen 等 6 位作者2001-04-01Chemistry - A European Journal

A highly active, three-dimensional, mesoporous titanosilica, TiTUD-1, with comparable properties to Ti-grafted mesoporous silica MCM-41, has been prepared in a one-step synthesis. A non-surfactant chemical, triethanolamine, was used as a template molecule. Triethanolamine easily forms complexes with titanium alkoxides…

Catalytic Processes in Materials ScienceZeolite Catalysis and SynthesisMesoporous Materials and Catalysis

Self-Organized Networks Based on Conjugated Polymers

L. V. Govor、I. Bashmakov、R. Kiebooms 等 5 位作者2001-04-01Advanced Materials

A successful method to fabricate large-area, microstructured sieve materials (see Figure) from a poly(p-phenylene–vinylene) (PPV) precursor and from poly(3-octylthiophene) (P3OT) is reported. Strong periodicity and a large, defect-free area make this structure extremely interesting for polymer optoelectronics. The und…

Conducting polymers and applicationsPolydiacetylene-based materials and applications

New piezoelectric polymer for air-borne and water-borne sound transducers

R. Kressmann2001-04-01The Journal of the Acoustical Society of America

Acoustic transducers made of a charged cellular polymer called EMFi have been designed and investigated with respect to air-borne and water-borne sound. The longitudinal transducer constant is around 90 pC/N, strongly exceeding the values of other piezoelectric polymers. This is mainly attributed to the very low Young…

Advanced Sensor and Energy Harvesting MaterialsHigh voltage insulation and dielectric phenomenaDielectric materials and actuators

Characterization of Montmorillonite Surfaces After Modification by Organosilane

Kang Song、G. Sandı́2001-04-01Clays and Clay Minerals

Abstract X-ray powder diffraction (XRD), thermal gravimetric analysis (TGA), surface area measurements, and near-edge X-ray absorption fine structure (NEXAFS) spectroscopy were used to examine the surface properties of organosilane-modified smectite-type aluminosilicate clays. Organic modified clays derived from the r…

Polymer Nanocomposites and PropertiesMesoporous Materials and CatalysisClay minerals and soil interactions

Metal-ligand interactions: Gas-phase transition metal cluster carbonyls

Kent M. Ervin2001-04-01International Reviews in Physical Chemistry

Experimental studies of the interactions of small transition-metal cluster anions with carbonyl ligands are reviewed and compared with neutral and cationic clusters. Under thermal conditions, the reaction rates of transition-metal clusters with carbon monoxide are measured as a function of cluster size. Saturation lim…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Method of Producing a Polyester/Viscose Core-Spun Yarn Containing Spandex Using a Modified Ring Spinning Frame

Osman Babaarslan2001-04-01Textile Research Journal

Core yarns are known as multi-component yarns in which one component, the core material, stays nearly at the center of the yarn while the others cover it. Stretch knitted or woven fabrics can be made from core yarns in which the core is an elastomeric filament such as Dorlastan®, Lycra®, Glospan®, etc., and the coveri…

Textile materials and evaluations

Influence of long-term storage in cold hibernation on strain recovery and recovery stress of polyurethane shape memory polymer foam

S J Tey、Weimin Huang、Witold M. Sokolowski2001-04-01Smart Materials and Structures

In this paper, the effects of long-term storage in compressed cold hibernated elastic memory (CHEM) polyurethane foam, a kind of shape memory polymer, are investigated experimentally. The foams were pre-strained at a high temperature, which was above the glass transition temperature, to 80% and 93.4%, respectively, an…

Polymer composites and self-healing

A study of partial discharges from water droplets on a silicone rubber insulating surface

Ivan J. S. Lopes、Shesha Jayaram、E.A. Cherney2001-04-01IEEE Transactions on Dielectrics and Electrical Insulation

This paper presents measurements of partial discharge (PD) from water droplets on a silicone rubber insulating surface in an ac field. Tests are done by placing droplets on the surface using a micro-pipette, and by condensing water in a controlled humidity chamber. The field enhancement factor due to droplets placed o…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationElectrohydrodynamics and Fluid Dynamics

Effect of Steel Microstructure on Corrosion Rate and Protective Iron Carbonate Film Formation

Arne Dugstad、H. Hemmer、M. Seiersten2001-04-01CORROSION

Three low-alloy carbon steels were given different heat treatments before testing in a corrosion flow loop at 80°C. Both the general corrosion rate and the susceptibility to form localized attack were significantly affected by the tempering temperature and the size and distribution of the carbides. Two of the steels c…

Corrosion Behavior and InhibitionMicrostructure and Mechanical Properties of SteelsHydrogen embrittlement and corrosion behaviors in metals

Insect silk contains both a Kunitz‐type and a unique Kazal‐type proteinase inhibitor

Xavier Nirmala、Dalibor Kodrı́k、Michal Žurovec 等 4 位作者2001-04-01European Journal of Biochemistry

Insect silk is made up of structural fibrous (fibroins) and sticky (sericins) proteins, and contains a few small peptides of hitherto unknown functions. We demonstrate that two of these peptides inhibit bacterial and fungal proteinases (subtilisin, proteinase K and pronase). These 'silk proteinase inhibitors' 1 and 2…

Insect Resistance and GeneticsInvertebrate Immune Response MechanismsSilk-based biomaterials and applications

Magnetic and electric “dead” layers in (La0.7Sr0.3)MnO3 thin films

R. P. Borges、Wiebke Guichard、J. G. Lunney 等 5 位作者2001-04-01Journal of Applied Physics

The magnetic, transport, and structural properties of (La0.1Sr0.3)MnO3 films deposited on MgO (001) are reported as a function of thickness and substrate temperature. The substrate temperature is fundamental in determining the structural properties and a deviation from the optimum temperature (680 °C) leads to grain b…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Morphological Stability of Poly(propylene) Nanocomposites

Peter Reichert、Botho Hoffmann、Thorsten Bock 等 6 位作者2001-04-01Macromolecular Rapid Communications

Poly(propylene) compounds containing organophilic layered nanosilicates were prepared by means of melt extrusion at 210°C in order to investigate the influence of maleic anhydride-grafted poly(propylene) (PP-g-MA) as a compatibilizer on morphology development and rheological properties. It was found that the addition…

Polymer Nanocomposites and Propertiesbiodegradable polymer synthesis and propertiesPolymer composites and self-healing

Uninformative Characters and Apparent Conflict Between Molecules and Morphology

Michael S. Y. Lee2001-04-01Molecular Biology and Evolution

Incongruence between different data sets remains one of the central issues in systematics. Numerous tree- based and character-based tests to identify incongruence have been developed, and each has strengths and weaknesses (e.g., for reviews, see Cunningham 1997a;Johnson and Soltis 1998 ). Currently, one of the most wi…

Algal biology and biofuel productionDiatoms and Algae Research

Local structure analysis of an optically active center in Er-doped ZnO thin film

Masashi Ishii、Shuji Komuro、Takitaro Morikawa 等 4 位作者2001-04-01Journal of Applied Physics

The local structure of an optically active center in erbium-doped zinc oxide (ZnO:Er) thin film produced by a laser ablation technique and its optical activation process are investigated by Er LIII-edge x-ray absorption fine structure analysis using a synchrotron radiation as an x-ray source. In as-ablated ZnO:Er thin…

Semiconductor materials and devicesThin-Film Transistor TechnologiesSilicon Nanostructures and Photoluminescence

Adhesion of ultrathin ZrO2(111) films on Ni(111) from first principles

A. Nørlund Christensen、Emily A. Carter2001-04-01The Journal of Chemical Physics

We have studied the ZrO2(111)/Ni(111) interface using the ultrasoft pseudopotential formalism within density functional theory. We find that ZrO2(111) adheres relatively strongly at the monolayer level but thicker ceramic films interact weakly with the Ni-substrate. We argue that the cohesion changes character from do…

Catalytic Processes in Materials ScienceSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Spherical MSU-1 Mesoporous Silica Particles Tuned for HPLC

Cédric Boissière、Mario L. Kummel、M. Persin 等 5 位作者2001-04-01Advanced Functional Materials

Among the mesoporous silica micellar templated structures (MTSs), MSU-X silica, obtained through an N0I0 assembly between non-ionic polyethyleneoxide-based surfactants (N0) and silica neutral inorganic precursors (I0), exhibits a regular ordered structure with a 3D wormhole porous framework and an easily controlled po…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisAnalytical Chemistry and Chromatography

New Insight into the Role of the PhaP Phasin of Ralstonia eutropha in Promoting Synthesis of Polyhydroxybutyrate

Gregory M. York、JoAnne Stubbe、Anthony J. Sinskey2001-04-01Journal of Bacteriology

Phasins are proteins that are proposed to play important roles in polyhydroxyalkanoate synthesis and granule formation. Here the phasin PhaP of Ralstonia eutropha has been analyzed with regard to its role in the synthesis of polyhydroxybutyrate (PHB). Purified recombinant PhaP, antibodies against PhaP, and an R. eutro…

Enzyme Catalysis and Immobilizationbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

Fire retardant fillers for polymers

Peter Hornsby2001-04-01International Materials Reviews

The application of many polymers is limited by their inherent flammability. Various routes are available to overcome this drawback through the inclusion of additives to inhibit ignition. These function by different mechanisms, tend to be polymer specific and may contribute to or suppress the smoke produced during burn…

Fire dynamics and safety researchFlame retardant materials and propertiesEnvironmental and Industrial Safety