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The Synthesis and Photoluminescence of M[sup II]M[sub 2][sup III](S,Se)[sub 4]

P.C. Donohue、J. E. Hanlon1974-01-01Journal of The Electrochemical Society

The compositions M II M 2 III ( S , Se ) 4 where M II = Eu , , Ca , Sr , Ba and M III = Al , Ga , In were prepared by reaction of the elements in evacuated silica tubes with iodine as a mineralizer. All members except Ba ( Ga , Al ) 2 S 4 , which is cubic, exhibit the pseudo‐orthorhombic PbGa 2 Se 4 type structure. Th…

Luminescence Properties of Advanced MaterialsCrystal Structures and PropertiesLanthanide and Transition Metal Complexes

The Kinetics of Hydrogen Absorption in Palladium (α‐ and β‐phase) and Palladium‐Silver‐Alloys

W. Auer、H. J. Grabke1974-01-01Berichte der Bunsengesellschaft für physikalische Chemie

Abstract The reaction H 2 → 2 H (dissolved) on thin Pd and Pd‐Ag foils (2.5–5 μm) was studied, with the aid of resistance measurements, in a flow apparatus at temperatures in the range 20–150°C. The rate determining step is the dissociation of the H 2 ‐molecule on the metal surface. It is assumed that in the formation…

Advanced Chemical Physics StudiesCatalysts for Methane ReformingHydrogen Storage and Materials

Mapping of the Structural Genes of the Three Aspartokinases and of the Two Homoserine Dehydrogenases of Escherichia coli K-12

Jacques Thèze、Danielle Margarita、G. N. Cohen 等 5 位作者1974-01-01Journal of Bacteriology

Mutants requiring threonine plus methionine (or homoserine), or threonine plus methionine plus diaminopimelate (or homoserine plus diaminopimelate) have been isolated from strains possessing only one of the three isofunctional aspartokinases. They have been classified in several groups according to their enzymatic def…

Enzyme Structure and FunctionAmino Acid Enzymes and MetabolismBiochemical and Molecular Research

A Survey of a Group of Phosphors, Based on Hexagonal Aluminate and Gallate Host Lattices

J.M.P.J. Verstegen1974-01-01Journal of The Electrochemical Society

A group of photoluminescent materials, which may have great influence on future fluorescent lamp development, is surveyed. The materials are based on hexagonal aluminates and gallates which are structurally related to the magnetoplumbites and (β‐alumina. When activated with Mn 2+ , Eu 2+ , Tl 2+ , Ce 3+ , and Tb 3+ ,…

Luminescence Properties of Advanced MaterialsPhotonic Crystals and ApplicationsRadiation Detection and Scintillator Technologies

Thermal Decomposition of Polyvinyl Chloride) and of Its Low-Molecular-Weight Model Compounds

Z. Mayer1974-01-01Journal of macromolecular science. Part C, Reviews in macromolecular chemistry and physics/Journal of macromolecular science. Reviews in macromolecular chemistry and physics

Polyvinyl chloride) (PVC) is undoubtedly among the most frequently used plastics; it is widely applied in many branches of the national economy, including industry and building [1]. Its advantages are comparatively high chemical resistance, low production costs, and an almost universal possibility of application as pa…

Thermal and Kinetic AnalysisPolymer Science and PVCChemistry and Chemical Engineering

Zirconium in Nuclear Applications

JH Schemel、HS Rosenbaum1974-01-01OpenAlex

Description The Symposium on Zirconium in Nuclear Applications was held 21–24 August 1973 in Portland, Ore., and was co-sponsored by the American Society for Testing and Materials (ASTM) Committee B-10 on Refractory Metals and Alloys and by the Institute of Metals Division, The Metallurgical Society of the American In…

Nuclear reactor physics and engineeringNuclear Materials and Properties

Surface and Defect Properties of Solids

作者信息未提供1974-01-01Royal Society of Chemistry eBooks

Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular ar…

Electron and X-Ray Spectroscopy Techniques

Equilibria in the Fe2(SO4)3/Fe2O3/SO3 system

W. D. Halstead、James W. Laxton1974-01-01Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases

The pressures of SO3 which exist in equilibrium with ferric sulphate have been measured in the temperature range 740 to 975 K by static and dynamic techniques. The overall equilibrium may be described by the two equations Fe2(SO4)3⇌Fe2O3+ 3SO3, 2SO3⇌2SO2+ O2 The equilibrium SO3 pressures above partially sulphated samp…

Metal Extraction and BioleachingChemical and Physical Properties in Aqueous SolutionsThermal and Kinetic Analysis

Optical properties of the Magnetotropic Nematic Phase of Poly-γ-Benzyl-ζ-Glutamate

Donald B. DuPré、James R. Hammersmith1974-01-01Molecular crystals and liquid crystals

Above a critical concentration in certain solvents poly-γ-benzyl-L-glutamate (PBLG) forms a lyotropic liquid crystal of the cholesteric structure. In the presence of sufficiently strong electric or magnetic fields this liquid crystal undergoes a mesomorphic phase transition to nematic order. Reported are the results o…

Liquid Crystal Research AdvancementsMolecular spectroscopy and chiralityZiziphus Jujuba Studies and Applications

Erosion-Corrosion of Finned Heat Exchanger Tubes

J. Horst、CR Sloan1974-01-01OpenAlex

Converted reformer gas on the shell side of a heat exchanger was cooled by water on the tube side. In addition to hydrogen and nitrogen, the gas contained substantial quantities of CO2 and water vapor. The tubes were integral finned of C-steel. Condensate from the gas stream filled the space between fins, while CO2 fr…

Metallurgy and Material FormingNuclear Materials and PropertiesMetal Alloys Wear and Properties

Conditions de formation de divers hydrocarbonates voisins de l'hydrotalcite

Henri Besson、Simonne Caillère、Stéphane Hénin1974-01-01Bulletin du Groupe français des Argiles

En traitant à l'ébullition des mélanges renfermant de l'Hydroxyde d'alumine et des carbonates de magnésium, de nickel ou de lithium, on obtient des composés voisins de l'hydrotalcite. A 60°C, en plaçant les produits initiaux dans des sacs à dialyse, il se forme les mêmes composés associés parfois à des impuretés. Dans…

Layered Double Hydroxides Synthesis and Applications

Grain boundaries in recrystallization

Robert W. Cahn1974-01-01Canadian Metallurgical Quarterly

In this brief survey, the theoretical models for nucleation of new grains in annealed cold-worked metals are reviewed in the light of recent researches in the author's laboratory. The importance of strain-induced boundary migration is gradually emerging. The role of vacancies in enhancing the mobility of grain boundar…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsMetallurgy and Material Forming

Optical absorption spectra of iron (III) and chromium (III) doped in synthetic yttrium-aluminium-garnets (YAG)

YOSHINORI RUGITANI、K. Tagawa、Kazúo Kato1974-01-01Mineralogical Journal

Eleven weak absorption peaks of Fe3+ and two broad absorptions of Cr3+ doped in synthetic yttrium-aluminium-garnets, Y3Al2A13O12, have been assigned to d-d transitions of the metal ions in octahedral and tetrahedral sites. All of these absorption peaks have 1:1 correspondence to transitions which are predicted to occu…

Luminescence Properties of Advanced MaterialsSolid State Laser TechnologiesLanthanide and Transition Metal Complexes

Anisotropic Thermal Expansion and Compressibility of Black Phosphorus

Robert J. Riedner、S. R. Srinivasa、L. Cartz 等 6 位作者1974-01-01OpenAlex

The anisotropic thermal expansion and compressibility coefficients of black phosphorus have been determined by high temperature single‐crystal x‐ray diffraction, by high pressure x‐ray diffraction and by neutron (time‐of‐flight) diffraction and are Ka = 1.5(2), Kb = 15.1(4), Kc = 12.1(4), Kv = 30.2(1.0) × 10−4 kbar−1.…

Nuclear Materials and PropertiesThermal and Kinetic AnalysisInorganic Chemistry and Materials

Effect of Vanadium on the 475° C Embrittlement of a Chromium Steel

P. Koutaniemi、V. Heikkinen、A. Saarinen1974-01-01Metal Science

Ferritic stainless steels containing more than 13% chromium are subject to severe embrittlement, known as the 475° C embrittlement, when heated in the temperature range of 400–550° C. Several experimental and review papers have been published about this phenomenon concerning binary iron–chromium alloys. On the other h…

Metal and Thin Film MechanicsMicrostructure and Mechanical Properties of SteelsMetal Alloys Wear and Properties

Amines as Corrosion Inhibitors for Aluminium-Manganese Alloy in Phosphoric Acid

J. D. Talati、G. A. Patel1974-01-01British Corrosion Journal

The corrosion of 3S aluminium (Al-Mn alloy) and its inhibition in solutions of phosphoric acid has been studied. The extent of corrosion increases with increase in acid concentration and with the length of the period of immersion. At 0·5% inhibitor concentration the efficiency of the inhibitors increases in the order:…

Corrosion Behavior and InhibitionMaterial Properties and Applications

Specimen Holder to Critical-Point Dry Microorganisms for Scanning Electron Microscopy

Cletus P. Kurtzman、F. L. Baker、M. J. Smiley1974-01-01Applied Microbiology

Critical-point drying of microorganisms for scanning electron microscopy can be rapidly and effectively accomplished by use of a newly described specimen holder. Up to eight different samples of spores or vegetative cells are placed between polycarbonate membrane filters in the holder and processed through solvent deh…

Electron and X-Ray Spectroscopy Techniques

Williams Domains and Dielectric Alignment in a Nematic Liquid Crystal

Hans Gruler1974-01-01Molecular crystals and liquid crystals

We investigate here the threshold behaviour of Williams domains and of the dielectric alignment in homeotropic and parallel oriented nematic films for different signs and magnitudes of the dielectric anisotropy. The theoretical predictions of the Helfrich theory are in agreement with the experiment.

Liquid Crystal Research AdvancementsNonlinear Dynamics and Pattern FormationPlant Reproductive Biology

Correlation and Prediction of Excess Thermodynamic Functions of Strongly Nonideal Liquid Mixtures

Isamu Nagata、Toshiro Yamada1974-01-01Industrial & Engineering Chemistry Process Design and Development

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCorrelation and Prediction of Excess Thermodynamic Functions of Strongly Nonideal Liquid MixturesIsamu Nagata and Toshiro YamadaCite this: Ind. Eng. Chem. Process Des. Dev. 1974, 13, 1, 47–53Publication Date (Print):January 1, 1974Publication History Published online1 May 20…

Process Optimization and IntegrationCrystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutions