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Polyoxometalate-Diphosphate Complexes. 3. Possible Intermediates in the Molybdate-Catalyzed Hydrolysis of Pyrophosphate. The Structure of Hexamolybdomethylenediphosphonate, [(O3PCH2PO3)Mo6O18(H2O)4]4-

U. Kortz、Michael T. Pope1995-04-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPolyoxometalate-Diphosphate Complexes. 3. Possible Intermediates in the Molybdate-Catalyzed Hydrolysis of Pyrophosphate. The Structure of Hexamolybdomethylenediphosphonate, [(O3PCH2PO3)Mo6O18(H2O)4]4-Uli Kortz and Michael T. PopeCite this: Inorg. Chem. 1995, 34, 8, 2160–2163…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsChemical Synthesis and Characterization

Thermal Behavior and Decomposition of Intercalated Kaolinite

M. Gábor、Mária Tóth、János Kristóf 等 4 位作者1995-04-01Clays and Clay Minerals

Abstract Intercalation complexes of a Hungarian kaolinite were prepared with hydrazine and potassium acetate. The thermal behavior and decomposition of the kaolinite-potassium acetate complex was studied by simultaneous TA-EGA, XRD, and FTIR methods. The intercalation complex is stable up to 300°C, and decomposition t…

Concrete and Cement Materials ResearchSoil and Unsaturated FlowClay minerals and soil interactions

Oxidation Kinetics of Graphite Phase in Magnesia‐Carbon Refractories

Xiangmin Li、Michel Rigaud、Štefan Palčo1995-04-01Journal of the American Ceramic Society

Decarbonization of resin‐bonded magnesia‐graphite refractories, as one of the most important parameters for brick lining performance in service, has been studied kinetically in the temperature range from 1000° to 1400°C in air, where carbon burnout by oxygen is the dominant decarbonizing mechanism. The rate of carbon…

Advanced ceramic materials synthesisGlass properties and applications

Phase Behavior of Blends of Poly(ethylene glycol) and Partially Neutralized Poly(acrylic acid)

Xinya Lu、R. A. Weiss1995-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhase Behavior of Blends of Poly(ethylene glycol) and Partially Neutralized Poly(acrylic acid)Xinya Lu and R. A. WeissCite this: Macromolecules 1995, 28, 9, 3022–3029Publication Date (Print):April 1, 1995Publication History Published online1 May 2002Published inissue 1 April…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and properties

Phonon interference inBaTiO3: High-pressure Raman study

A. K. Sood、N. Chandrabhas、D. V. S. Muthu 等 4 位作者1995-04-01Physical review. B, Condensed matter

Raman experiments have been carried out on single crystals of ${\mathrm{BaTiO}}_{3}$ as a function of pressure up to 3.5 GPa across the ferroelectric (tetragonal) to paraelectric (cubic) phase transition. The unusual features in the Raman spectra associated with the interference effects due to coupling of the three ${…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesSolid-state spectroscopy and crystallography

Space-charge physics and the breakdown process

G. Blaise1995-04-01Journal of Applied Physics

The trapping of charges in hard dielectric materials has been recently described [G. Blaise, IEEE Trans. Electr. Insul. EI-28, 437 (1993)] on the basis of the polaron concept. A local increase of the internal energy of the medium Up∼5–10 eV results from the polarization around a trapped charge. The relaxation of the l…

Semiconductor materials and devicesHigh voltage insulation and dielectric phenomenaPower Transformer Diagnostics and Insulation

Reliable Measurements of the Nylon 6 Glass Transition Made Possible by the New Dynamic DSC

Y. P. Khanna、William P. Kuhn、W. Sichina1995-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTReliable Measurements of the Nylon 6 Glass Transition Made Possible by the New Dynamic DSCYash P. Khanna, William P. Kuhn, and William J. SichinaCite this: Macromolecules 1995, 28, 8, 2644–2646Publication Date (Print):April 1, 1995Publication History Published online1 May 20…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesForce Microscopy Techniques and Applications

Localization in fractal spaces: Exact results on the Sierpinski gasket

X. R. Wang1995-04-01Physical review. B, Condensed matter

Localization due to space structure, rather than due to randomness, is investigated by studying the usual tight-binding model on the Sierpinski gasket. Some exact results are obtained from the decimation--renormalization-group method. It is surprising that there exist an infinite number of extended states on the Sierp…

Mathematical Dynamics and FractalsTheoretical and Computational PhysicsQuasicrystal Structures and Properties

The dynamics of molecular bearings

Robert E. Tuzun、D. W. Noid、Bobby G. Sumpter1995-04-01Nanotechnology

Various types of molecular bearings have recently been proposed in the growing nanotechnology literature. Using novel molecular dynamics methods, we have simulated several model graphite bearings. The bearings varied in size from inner shafts of between 4 and 16 A in diameter, up to 120 A in length, and outer cylinder…

Carbon Nanotubes in CompositesDiamond and Carbon-based Materials ResearchForce Microscopy Techniques and Applications

Synthesis, Structure, and Spectroscopic Properties of Bismuth Citrate Compounds and the Bismuth-Containing Ulcer-Healing Agent Colloidal Bismuth Subcitrate (CBS). 4. Crystal Structure and Solution Behavior of a Unique Dodecanuclear Cluster (NH4)12[Bi12O8(cit)8](H2O)10

Eiji Asato、Kosho Katsura、Masahiro Mikuriya 等 6 位作者1995-04-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis, Structure, and Spectroscopic Properties of Bismuth Citrate Compounds and the Bismuth-Containing Ulcer-Healing Agent Colloidal Bismuth Subcitrate (CBS). 4. Crystal Structure and Solution Behavior of a Unique Dodecanuclear Cluster (NH4)12[Bi12O8(cit)8](H2O)10Eiji As…

Crystal Structures and PropertiesPolyoxometalates: Synthesis and ApplicationsOrganometallic Compounds Synthesis and Characterization

Reaction Mechanisms of Silicon Carbide Fiber Synthesis by Heat Treatment of Polycarbosilane Fibers Cured by Radiation: I, Evolved Gas Analysis.

Masaki Sugimoto、Toshio Shimoo、Kiyohito Okamura 等 4 位作者1995-04-01Journal of the American Ceramic Society

SiC fibers were synthesized from polycarbosilane (PCS) fibers by heat treatment after electron beam irradiation curing. The pyrolysis reaction mechanisms from the organic PCS to ceramic SiC were investigated by the analysis of gases evolved during heat treatment. There were two steps in the major reaction: the first s…

Advanced ceramic materials synthesisDiamond and Carbon-based Materials ResearchFiber-reinforced polymer composites

Optical and Electrochemical Properties of cis-1,2-Dicyano-1,2-bis(2,4,5-trimethyl-3-thienyl)ethene

Takashi Koshido、Tsuyoshi Kawai、Katsumi Yoshino1995-04-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOptical and Electrochemical Properties of cis-1,2-Dicyano-1,2-bis(2,4,5-trimethyl-3-thienyl)etheneTakashi Koshido, Tsuyoshi Kawai, and Katsumi YoshinoCite this: J. Phys. Chem. 1995, 99, 16, 6110–6114Publication Date (Print):April 1, 1995Publication History Published online1…

Conducting polymers and applicationsMolecular Junctions and NanostructuresPhotochemistry and Electron Transfer Studies

A compact electron-spin-polarization manipulator

Thomas Duden、E. Bauer1995-04-01Review of Scientific Instruments

A compact electron-spin-polarization manipulator is described which allows one to align the polarization in any desired direction in space. The system delivers a focused electron beam of typically 3–5 keV. Its application in spin-polarized low-energy electron microscopy for the study of magnetic domain structures is b…

Advanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy TechniquesPhotocathodes and Microchannel Plates

Electron trapping kinetics at dislocations in relaxed Ge0.3Si0.7/Si heterostructures

P. N. Grillot、Steven A. Ringel、Eugene A. Fitzgerald 等 5 位作者1995-04-01Journal of Applied Physics

The capture kinetics and trapping properties of a dislocation related electron trap detected in strain-relaxed, compositionally graded Ge0.3Si0.7/Si grown by rapid thermal chemical-vapor deposition are investigated by deep-level transient spectroscopy (DLTS). The volume DLTS trap concentration scales linearly with the…

Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceSemiconductor materials and interfaces

Polymer Waste Management–Biodegradation, Incineration, and Recycling

Samuel J. Huang1995-04-01Journal of Macromolecular Science Part A

Increasing volumes of synthetic polymers are manufactured for various applications. The disposal of the used materials is becoming a serious problem. Unlike natural polymers, most synthetic macromolecules cannot be assimilated by microorganisms. Although polymers represent slightly over 10% of total municipal waste, t…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionGraphene and Nanomaterials Applications

Chemical Etching of Si1 − x Ge x in HF : H 2 O 2 : CH 3 COOH

T. K.、M. O. Tanner、K. L Wang1995-04-01Journal of The Electrochemical Society

The properties of a highly selective chemical etchant composed of hydrofluoric acid, hydrogen peroxide, and acetic acid ( HF : H 2 O 2 : CH 3 COOH ) is investigated in etching SiGe / Si heterostructures. This solution has been found to etch Si 1 − x Ge x much faster than Si over the entire range of Ge contents. The et…

Semiconductor materials and devicesThin-Film Transistor TechnologiesSilicon Nanostructures and Photoluminescence

Measuring thermoelectric effects in thermal converters with a fast reversed DC

M. Klonz、Thomas Spiegel、R. Zirpel 等 8 位作者1995-04-01IEEE Transactions on Instrumentation and Measurement

The AC-DC transfer differences of thermal converters due to thermoelectric effects in the heater circuit are directly measured with a fast reversed DC to an uncertainty of a few parts in 10/sup 7/. This new and independent method allows former theoretical methods for evaluating thermoelectric effects in thermal conver…

Advanced MEMS and NEMS TechnologiesMagnetic Properties and ApplicationsSurface and Thin Film Phenomena

Anisotropy of the ZnO single crystal reflectivity in the region of residual rays

E. F. Venger、O. Melnichuk、L. Melnichuk 等 4 位作者1995-04-01physica status solidi (b)

Abstract The consistent parameters of hexagonal zinc oxide single crystals are obtained in the frame of the one‐oscillator model by analyzing the dispersion spectra of IR light reflection. The anisotropy coefficients of the electron effective masses and the plasmon damping Coefficients are measured. The calculated val…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

Illite/Smectite Diagenesis and Its Variable Correlation with Vitrinite Reflectance in the Pannonian Basin

Stephen Hillier、János Mátyás、Albert Matter 等 4 位作者1995-04-01Clays and Clay Minerals

Abstract The correlation between illite/smectite (I/S) diagenesis and mean vitrinite reflectance (R o ) data is examined in mudrocks from a hydrocarbon exploration well (geothermal gradient 35°C km −1 ) from the Great Hungarian Plain of the Pannonian Basin System. The expandability of I/S decreases with depth and ther…

Geological and Geochemical AnalysisPaleontology and Stratigraphy of FossilsClay minerals and soil interactions

Monoclinic .tautm. Hexagonal Phase Transition in Hydroxyapatite Studied by X-ray Powder Diffraction and Differential Scanning Calorimeter Techniques

Hiroyuki Suda、Masatomo Yashima、Masato Kakihana 等 4 位作者1995-04-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMonoclinic .tautm. Hexagonal Phase Transition in Hydroxyapatite Studied by X-ray Powder Diffraction and Differential Scanning Calorimeter TechniquesHiroyuki Suda, Masatomo Yashima, Masato Kakihana, and Masahiro YoshimuraCite this: J. Phys. Chem. 1995, 99, 17, 6752–6754Public…

Crystal Structures and PropertiesChemical Synthesis and CharacterizationX-ray Diffraction in Crystallography