Materials Literature
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The morphology and rheology of polyethylene-octene elastomer (POE)/crosslinked starch (CS) immiscible blends with various amounts of compatibilizer were experimentally examined. A graft copolymer, POE-g-MAH, acting as the compatibilizer, was used to modify the interface of the blend. The particle radius in the POE/CS…
Here we extend the research of the $(R,\mathrm{Ca}){\mathrm{MnO}}_{3}$ perovskites to the smallest-$R$ end member $(\mathrm{Lu},\mathrm{Ca}){\mathrm{MnO}}_{3}$. Magnetic and magnetotransport properties of the $({\mathrm{Lu}}_{1\ensuremath{-}x}{\mathrm{Ca}}_{x}){\mathrm{MnO}}_{3}$ system are systematically investigated…
Abstract Poly(methyl methacrylate) doped with CuCl 2 was prepared and its electron spin resonance (ESR) spectra and optical properties were studied. The ESR spectra can be accounted for by the presence of two radicals: R a and R b . FTIR spectroscopy reveals that there is no main difference of the spectra due to the a…
We briefly review systematic and comprehensive studies on several chlorine-substituted bent-core liquid crystal materials in their nematic phases. The results, in comparison to rod-shaped molecules, are both extraordinary and technologically significant. Specifically: a) Electrohydrodynamic instabilities provide uniqu…
Abstract This article is focused on the phase structure development in immiscible polymer blends during melt mixing. Nonuniformity of the phase structure, i.e., the coexistence of areas containing particles with markedly different size distribution, was detected in quenched and compression molded samples of a number o…
We demonstrated transmissive- and reflective-type Fresnel lenses based on dye-doped liquid crystal using photoalignment technique. The former is a polarization-independent and electrically tunable. The maximum diffraction efficiency reaches 37%, which approaches the theoretical limit ~ 41 %. Such a lens functions as a…
A series of polycrystalline full-Heusler Co2MnAl thin films were deposited on Si (100) coated with thermo SiO2 by using different types of seed layers such as Cr, Mg, MgO∕Cr, and MgO. The properties of the Co2MnAl thin films such as the coercivity, atomic composition, and crystalline structure strongly depend on the d…
In this study many composites based on low density polyethylene (LDPE) with calcium carbonate (CaCO3) and maleic anhydride-grafted polyethylene (MAH-g-LDPE) as a compatibilizer have been investigated in order to study their behavior and the reinforcing mechanisms involved. Different types of chemical modifications of…
Abstract Thermodynamic phase behavior was studied for polymer dispersed liquid crystal (PDLC) films consisting of blends of different thermoplastics such as poly (bisphenol A carbonate) (PC), poly(methylphenylsiloxane) (PMPLSi), poly(styrene‐ b ‐ethylene oxide) (PSEO) block copolymer, and low‐molecular weight 4′‐(hexy…
Abstract Even at low content, polypropylene significantly worsens mechanical properties of the recycled PVC composite, i.e. tensile strength at break and elongation at break. But, if small quantities of surface modified nanofiller calcium carbonate is added, an applicable composite that contains 10–30% of waste materi…
This work is concerned with the influence of mica in natural rubber compounds on properties such as Mooney viscosity, processability and rheological behavior. The amount of this filler was varied from 0 to 40 phr and the stabilized and totalized torques, specific and mechanical energies were determined in a HAAKE torq…
Abstract Heterogeneous metallocene catalysts were prepared by incipient wetness impregnation of AlSBA‐15 (Si/Al = 4.8, 15, 30, 60, and ∞) mesostructured materials with ( n BuCp) 2 ZrCl 2 /MAO. For comparative purposes commercial silica and silica–alumina (Si/Al = 4.8) supports were also impregnated with the MAO/metall…
X-ray and neutron scattering and analytical ultracentrifugation provide multiparameter structural and compositional information on proteins that complements high-resolution protein crystallography and NMR studies. They are ideal methods to use when either a large protein cannot be crystallized, when scattering provide…
Abstract The thermal, dynamic mechanical analysis, morphology and mechanical properties of semi‐interpenetrating polymer networks based on crosslinked polyurethane (PU) and poly(2‐hydroxyethyl methacrylate) (PHEMA) synthesized by photopolymerization and by thermopolymerization have been investigated. The thermal analy…
Abstract The present paper deals with the photo‐Fries rearrangement of fully aromatic esters in polymeric media. Low molecular weight aryl esters bearing the 1‐naphthyl chromophore were investigated with respect to their photochemical reactivity and the yield of hydroxyketones as the photo‐Fries rearrangement product.…
The addition of nonmagnetic Ga into body-centered cubic Fe enhances the magnetostriction constant λ100 over tenfold. Literature reports for substitution of Ge at low concentrations suggest that the addition of Ge also enhances the magnetostriction. In this work, the magnetostriction and microstructure of Fe–Ge were in…
Remarkable nonlinear conductivity is observed in the organic conductor (MDT-TS)(I2Br)_{0.420} (MDT-TS: 5H-2-(1,3-diselenol-2-ylidene)-1,3,4,6-tetrathiapentalene) below the metal-insulator transition at 30 K. This compound is characterized by the incommensurate donor and anion columns, and the non-Ohmic behavior is ass…
An amphiphilic tris(dibenzoylmethanato)europium(III) (Eu(DBM)(3)) coordinated P(MMA-co-EIPPMMA)-co-P(NIPAAm-co-NDAPM) copolymer was synthesized, which exhibited good biocompatibility and emitted strong red luminescence (MMA, methyl methacrylate; EIPPMMA, 4-(1-ethyl-1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenyl meth…
Abstract A two‐level factorial experimental design was used to examine the combined effects of o‐MMT gallery polarity, surface modification of MDH, MA‐ g ‐PP and antioxidant addition, together with processing variables, on the burning behaviour and thermal stability of ternary composites based on PP, MDH and o‐MMT. Re…
Magnetic properties and microstructure of directly quenched Nd9.5Fe75.5−xMxB15 (M=Mo, Nb, Ta, Ti, V, and Zr; x=0–4) bulk magnets in rod form with a diameter of 0.7mm have been studied. The substitution of the selected refractory elements for Fe in the Nd9.5Fe75.5MxB15 alloy can suppress the formation of the soft phase…