Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
Abstract Spherulite size graded polyurethane elastomers (PUEs) were prepared using a mold with a temperature gradient from different polymer glycols, 4,4′‐diphenylmethane diisocyanate (MDI) and a mixture of 1,4‐butanediol (BD), and 1,1,1‐trimethylol propane (TMP) as a curing agent by a prepolymer method. The used poly…
Abstract The free‐radical graft copolymerization of maleic anhydride (MAH) onto highly reactive low molecular weight polyisobutylene was conducted by the use of benzoyl peroxide as an initiator through the solvothermal method. Fourier transform infrared spectra and 1 H‐NMR spectra confirmed that maleic anhydride was s…
Abstract Epoxy composites incorporating natural components have been mainly limited to the use of natural fibers. However, there have been a few instances where polysaccharides have been used as particulate fillers in thermoset compositions. The present study investigated the effect of guar gum/hydroxypropyl guar gum…
Abstract A series of novel aromatic poly(ether imides) with inherent viscosities of 0.48–0.70 dL/g and weight‐average molecular weights of 18,800–40,500 g/mol were successfully prepared from two dianhydride and two diamine monomers containing pyridine moiety via both two‐step method and one‐step method. Comparison of…
Abstract Heat treatment is one method to improve mechanical properties of metal, but each heat treatment method has its advantages and disadvantages, therefore, different requirements regarding size, shape, and properties with respect to different heat treatment processes should be considered. Gas quenching is a heat…
Abstract A novel fluorinated biphenyl‐type epoxy resin (FBE) was synthesized by epoxidation of a fluorinated biphenyl‐type phenolic resin, which was prepared by the condensation of 3‐trifluoromethylphenol and 4,4′‐bismethoxymethylbiphenyl catalyzed in the presence of strong Lewis acid. Resin blends mixed by FBE with p…
Abstract The effect of processing history in a single‐screw extruder on molecular characteristics was studied by employing commercially available low‐density polyethylene with no additives. Generation of long‐chain branch, which is responsible for the neck‐in phenomenon and draw resonance, is indicated by nonlinear vi…
A simple and powerful anodization method is described for the formation of highly ordered coaxial bimodal nanotubes (see image) on titanium alloys. Coaxial nanotube arrays may possess considerable advantages over existing coaxial nanocables.
Transmission electron microscopy images showed that the ZnO quantum dots (QDs) were conjugated with multi-walled carbon nanotubes (MWCNTs). Bistable memories utilizing an ensemble of the ZnO QD-MWCNT heterostructures were developed and the storage capability of the devices was significantly enhanced due to the conjuga…
Abstract A melt pump was assembled into the compounding line to ensure both sufficient time for diffusion process of polymer chains into the silicate gallery and sufficient mechanical shear energy for exfoliation of clay layers. The melt pump in front of the open co‐rotating twin‐screw extruder controls the throughput…
Abstract A stable porous superhydrophobic high‐density polyethylene (HDPE) surface with water contact angle of 160.0 ± 1.9° and sliding angle of 2.0 ± 1.6° was obtained by adding ethanol in humid atmosphere at 5°C. Soaked in water with temperatures ranging from 5 to 50°C for 15 days, even suffering compressive forces,…
Emission from charge recombination between radical cations and anions of a series of regioisomeric 1,4-, 1,3-, and 1,2-bis(phenylethynyl)benzenes (bPEBs) substituted by various electron donor and/or acceptor groups was measured during pulse radiolysis in benzene (Bz). The formation of bPEB in the excited singlet state…
Abstract In this article, epoxy/graphite nanoplatelet (GNP) conductive composites with the low percolation threshold of ∼ 0.5 vol % were prepared. The effect of microstructure, particularly the spatial distribution of fillers in the matrix on the resistivity and its dependence on temperature, also was investigated. It…
Abstract To investigate the effect of interfacial interaction on the crystallization and mechanical properties of polypropylene (PP)/nano‐CaCO 3 composites, three kinds of compatibilizers [PP grafted with maleic anhydride (PP‐ g ‐MA), ethylene–octene copolymer grafted with MA (POE‐ g ‐MA), and ethylene–vinyl acetate c…
The effect of varying bismuth concentration on the optical constants of amorphous Ge20Se80− x Bi x (where x = 0, 3, 6, 9 and 12 at%) thin films prepared by thermal evaporation has been investigated. The transmission spectra T(λ) of the films at normal incidence were obtained in the spectral region from 400 to 2500 nm.…
We report dynamic Monte Carlo simulations of crystallization under hard confinement of spherical diblock copolymers. We compared the parallel results of blocks with short chains made by breaking block junctions. We observed that blocks crystallize faster but harvest lower crystallinity than short chains, which is in a…
Relaxometric studies are still of scientific interest due to their use in medicine and biology. In this study, proton T(1) and T(2) relaxivities of Mn(II), Cu(II) and Cr(III) in water were determined in the presence and absence of various proteins (albumin, alpha-globulin, gamma-globulin, lysozyme, fibrinogen). The 1/…
Li adsorption on isoreticular MOFs with metal Fe, Cu, Co, Ni and Zn was studied using density function theory. Li functionalization shows a considerable structural change associated with a volume change in isoreticular MOF-5 except for the Zn metal center. Hydrogen binding energies on Li functionalized MOFs are seen t…
A thermo-responsive polymer/quantum dot platform based on poly(N-isopropyl acrylamide) (PNIPAM) brushes 'grafted from' a gold substrate and quantum dots (QDs) covalently attached to the PNIPAM layer is presented. The PNIPAM brushes are grafted from the gold surface using an iniferter-initiated controlled radical polym…
Effective delivery is a critical issue in the use of conventional free drugs. Studies on the structure-function relationship of a therapeutic antibody-derived candidacidal decapeptide (killer peptide, KP) revealed its ability to spontaneously and reversibly self-assemble in an organized network of fibril-like structur…