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Particle tracking velocimetry of the flow field around a collapsing cavitation bubble

Dennis Kröninger、Karsten Köhler、Thomas Kurz 等 4 位作者2009-09-15Experiments in Fluids

The velocity field in the vicinity of a laser-generated cavitation bubble in water is investigated by means of particle tracking velocimetry (PTV). Two situations are explored: a bubble collapsing spherically and a bubble collapsing aspherically near a rigid wall. In the first case, the accuracy of the PTV method is a…

Fluid Dynamics and MixingCavitation Phenomena in PumpsUltrasound and Cavitation Phenomena

Nanocomposites made from cellulose nanocrystals and tailored segmented polyurethanes

Marı́a L. Auad、Mirna A. Mosiewicki、Tara Richardson 等 5 位作者2009-09-15Journal of Applied Polymer Science

Abstract The effect of the addition of microcrystalline cellulose nanofibers into linear segmented polyurethanes (SPU) was investigated. The polymers were synthesized with 4,4‐methylene‐bisphenyldiisocyanate (MDI) and poly(tetramethyleneglycol) (PTMG) with 1,4‐butanediol (BD) as chain extender. The nanocrystals were i…

Advanced Cellulose Research StudiesPolymer composites and self-healingLignin and Wood Chemistry

Extracting phonon thermal conductance across atomic junctions: Nonequilibrium Green’s function approach compared to semiclassical methods

Patrick E. Hopkins、Pamela M. Norris、Mikiyas S. Tsegaye 等 4 位作者2009-09-15Journal of Applied Physics

The thermal conductance of nanoscale phonon modes is typically calculated using the Boltzmann transport equation. A particular implementation of this method is the acoustic mismatch model (AMM) that compares impedance ratios at a mathematically abrupt transition between two equilibrium regions. The shortcomings of thi…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Radiation and Cooling Technologies

Joule heating in single-walled carbon nanotubes

Tarek Ragab、Cemal Basaran2009-09-15Journal of Applied Physics

Joule heating in single-walled carbon nanotubes (CNTs) using a quantum mechanical approach is presented in this paper. The modeling is based on the energy transfer between the electrons and both acoustic and optical phonons. In this formulation, only the knowledge of the full energy dispersion relation, phonon dispers…

Carbon Nanotubes in CompositesMechanical and Optical ResonatorsNanopore and Nanochannel Transport Studies

Something Old, Something New, Something Borrowed; How the Thermoacidophilic Archaeon Sulfolobus solfataricus Responds to Oxidative Stress

Walid S. Maaty、Blake Wiedenheft、Pavel Tarlykov 等 13 位作者2009-09-15PLoS ONE

To avoid molecular damage of biomolecules due to oxidation, all cells have evolved constitutive and responsive systems to mitigate and repair chemical modifications. Archaea have adapted to some of the most extreme environments known to support life, including highly oxidizing conditions. However, in comparison to bac…

Photosynthetic Processes and MechanismsEnzyme Structure and FunctionPorphyrin Metabolism and Disorders

Structure and properties of cellulose fibers from ionic liquids

Tao Cai、Huihui Zhang、Qinghua Guo 等 5 位作者2009-09-15Journal of Applied Polymer Science

Abstract 1‐Butyl‐3‐methylimidazolium chloride ([BMIM]Cl) was used as a solvent for cellulose, the rheological behavior of the cellulose/[BMIM]Cl solution was studied, and the fibers were spun with a dry‐jet–wet‐spinning process. In addition, the structure and properties of the prepared cellulose fibers were investigat…

Nanocomposite Films for Food PackagingAdvanced Cellulose Research StudiesLignin and Wood Chemistry

Concentration-dependent near-infrared quantum cutting in NaYF4:Pr3+, Yb3+ phosphor

Xinhuang Chen、Xiaoyong Huang、Qinyuan Zhang2009-09-15Journal of Applied Physics

Near-infrared quantum cutting phenomenon has been demonstrated in Pr3+–Yb3+-codoped NaYF4 microcrystals synthesized by a facile hydrothermal route, which involves the emission of two near-infrared photons from an absorbed blue photon via a cooperative downconversion process. The Pr3+–Yb3+ energy transfer mechanisms ha…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsSolid State Laser Technologies

Self-Assembled Polymeric Micellar Nanoparticles as Nanocarriers for Poorly Soluble Anticancer Drug Ethaselen

Xinru Li、Zhuoli Yang、Kewei Yang 等 9 位作者2009-09-15Nanoscale Research Letters

A series of monomethoxy poly(ethylene glycol)-poly(lactide) (mPEG-PLA) diblock copolymers were synthesized, and mPEG-PLA micelle was fabricated and used as a nanocarrier for solubilization and delivery of a promising anticancer drug ethaselen. Ethaselen was efficiently encapsulated into the micelles by the dialysis me…

Nanoparticle-Based Drug DeliveryPolymer Surface Interaction StudiesDendrimers and Hyperbranched Polymers

Raman Spectroelectrochemistry of Molecules within Individual Electromagnetic Hot Spots

Timur Shegai、Alexander Vaskevich、Israel Rubinstein 等 4 位作者2009-09-15Journal of the American Chemical Society

The role of chemical enhancement in surface-enhanced Raman scattering (SERS) remains a contested subject. We study SERS spectra of 4-mercaptopyridine molecules excited far from the molecular resonance, which are collected from individual electromagnetic hot spots at concentrations close to the single-molecule limit. T…

Gold and Silver Nanoparticles Synthesis and ApplicationsElectrochemical Analysis and ApplicationsNanocluster Synthesis and Applications

High Figure of Merit in Nanostructured n-Type KPbmSbTem+2 Thermoelectric Materials

Pierre F. P. Poudeu、Aurelie Gueguen、Chun‐I Wu 等 5 位作者2009-09-15Chemistry of Materials

We demonstrate that the KPb m SbTe 2+ m system (PLAT- m for tellurium, antimony, lead potassium, m = 19−21) of materials exhibits high thermoelectric performance. Samples with compositions K 1− x Pb m +δ Sb 1+γ Te m+2 were prepared using several combinations of x, δ, γ and m and their thermoelectric properties were in…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Radiation and Cooling Technologies

Thermodynamic Studies and Hydride Transfer Reactions from a Rhodium Complex to BX3 Compounds

Michael T. Mock、Robert G. Potter、Donald M. Camaioni 等 8 位作者2009-09-15Journal of the American Chemical Society

This study examines the use of transition-metal hydride complexes that can be generated by the heterolytic cleavage of H(2) gas to form B-H bonds. Specifically, these studies are focused on providing a reliable and quantitative method for determining when hydride transfer from transition-metal hydrides to three-coordi…

Hydrogen Storage and MaterialsAsymmetric Hydrogenation and CatalysisCarbon dioxide utilization in catalysis

A Metal–Collagen Peptide Framework for Three‐Dimensional Cell Culture

Marcos M. Pires、David E. Przybyla、Jean Chmielewski2009-09-15Angewandte Chemie International Edition

It won′t overstay its welcome: Metal ions trigger the rapid assembly of a triple-helical collagen-based peptide with ligands at the ends and center into a fibrous three-dimensional mesh under physiological conditions (see picture). Importantly for applications in regenerative medicine, a mild chelating agent causes ra…

Silk-based biomaterials and applicationsMarine Biology and Environmental ChemistryCollagen: Extraction and Characterization

Structural and Magnetic Properties of Various Ferromagnetic Nanotubes

Xiufeng Han、S. Shamaila、Rehana Sharif 等 6 位作者2009-09-15Advanced Materials

Abstract The structural and magnetic properties of ferromagnetic nanotubes fabricated by a low cost electrodeposition method are investigated. The fabrication of various elemental ferromagnetic materials are described, such as Fe, Co, and Ni, and ferromagnetic alloys, such as NiFe, CoPt, CoFeB, and CoCrPt nanotube arr…

Magnetic properties of thin filmsCarbon Nanotubes in CompositesAnodic Oxide Films and Nanostructures

Engineering the Salmonella type III secretion system to export spider silk monomers

Daniel M Widmaier、Danielle Tullman‐Ercek、Ethan A. Mirsky 等 7 位作者2009-09-15Molecular Systems Biology

The type III secretion system (T3SS) exports proteins from the cytoplasm, through both the inner and outer membranes, to the external environment. Here, a system is constructed to harness the T3SS encoded within Salmonella Pathogeneity Island 1 to export proteins of biotechnological interest. The system is composed of…

Insect Resistance and GeneticsInvertebrate Immune Response MechanismsSilk-based biomaterials and applications

Magnetoelectric effect in BaTiO3/Ni particulate nanocomposites at microwave frequencies

Vincent Castel、Christian Brosseau、J. Ben Youssef2009-09-15Journal of Applied Physics

We present a comprehensive study of the magnetic and microwave properties of piezoelectric BaTiO3/magnetostrictive Ni nanocomposites (NCs), fabricated under uniaxial compression, at room temperature. In the current work, we investigated samples in the compositional range between 0≤fNi≤33.5 vol % and from 0.1 to 6 GHz…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMagnetic Properties and Applications

Magnetocrystalline interactions inMnCr2O4spinel

E. Winkler、S. Blanco Canosa、Francisco Rivadulla 等 8 位作者2009-09-15Physical Review B

In this work we present a magnetic, structural, and electron spin resonance (ESR) study of the geometrically frustrated ${\text{MnCr}}_{2}{\text{O}}_{4}$ spinel in an extended range of $T$ (2--1000 K). At the lowest temperature $(T<18\text{ }\text{K})$ the ESR lineshape is compatible with the coexistence of spiral…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Functionalized Au22 Clusters: Synthesis, Characterization, and Patterning

Edakkattuparambil Sidharth Shibu、Boya Radha、Pramod Kumar Verma 等 7 位作者2009-09-15ACS Applied Materials & Interfaces

We synthesized fluorescent, porphyrin-anchored, Au(22) clusters in a single step, starting from well-characterized Au(25) clusters protected with glutathione (-SG) by a combined core reduction/ligand exchange protocol, at a liquid-liquid interface. The prepared cluster was characterized by UV/vis, photoluminescence, X…

Nanocluster Synthesis and ApplicationsPharmacological Effects and Toxicity StudiesAdvanced Nanomaterials in Catalysis

Effect of Mn doping on electric and magnetic properties of BiFeO3 thin films by chemical solution deposition

Ji-Zhou Huang、Yao Wang、Yuanhua Lin 等 5 位作者2009-09-15Journal of Applied Physics

The effect of Mn doping on crystal structure, electric and magnetic properties of BiFeO3 thin films prepared via a chemical deposition method on (111) Pt/Ti/SiO2/Si substrates was studied. The substitution of Fe ions by a small amount (5%) of Mn ions could facilitate the stabilization of Fe3+ in BiFeO3 thin films, whi…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMagneto-Optical Properties and Applications

Third-order nonlinear optical properties of a one- and two-electron spherical quantum dot with and without a hydrogenic impurity

Mehmet Şahin2009-09-15Journal of Applied Physics

In this study, a detailed investigation of the nonlinear optical properties of a spherical quantum dot (QD) containing one and two electrons has been carried out. First, intersublevel linear, third-order, and total absorptions of both single- and double-electron QDs have been investigated for cases with (i.e., D0 and…

Semiconductor Quantum Structures and DevicesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Dielectric properties of Li2O–3B2O3 glasses

Rahul Vaish、K. B. R. Varma2009-09-15Journal of Applied Physics

The frequency and temperature dependences of the dielectric constant and the electrical conductivity of the transparent glasses in the composition Li2O–3B2O3 were investigated in the 100 Hz–10 MHz frequency range. The dielectric constant and the loss in the low frequency regime were electrode material dependent. Diele…

Material Dynamics and PropertiesGlass properties and applicationsPhotorefractive and Nonlinear Optics