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Anisotropic Structure and Transformation Kinetics of Vapor-Deposited Indomethacin Glasses

Kevin J. Dawson、Lei Zhu、Lian Yu 等 4 位作者2010-12-17The Journal of Physical Chemistry B

One- and two-dimensional wide-angle X-ray scattering (1D and 2D WAXS) measurements were performed on vapor-deposited glasses of indomethacin. Physical vapor deposition can be used to prepare organic glasses with high kinetic stability and other properties that are expected for glasses that have been aged for thousands…

Material Dynamics and PropertiesGlass properties and applicationsPhase-change materials and chalcogenides

Hierarchical manganese oxide/carbon nanocomposites for supercapacitor electrodes

Yiting Peng、Zheng Chen、Jing Wen 等 8 位作者2010-12-17Nano Research

MnO 2 /carbon nanocomposites with hierarchical pore structure and controllable MnO 2 loading have been synthesized using a self-limiting growth method. This was achieved by the redox reactions of KMnO 4 with sacrificed carbon substrates that contain hierarchical pores. The unique pore structure allows the synthesis of…

Advancements in Battery MaterialsElectrocatalysts for Energy ConversionSupercapacitor Materials and Fabrication

Electro thermal simulation of superconducting nanowire avalanche photodetectors

Francesco Marsili、Faraz Najafi、Charles Herder 等 4 位作者2010-12-17arXiv

We developed an electro thermal model of NbN superconducting nanowire avalanche photodetectors (SNAPs) on sapphire substrates. SNAPs are single photon detectors consisting of the parallel connection of N superconducting nanowires. We extrapolated the physical constants of the model from experimental data and we simula…

Materials Sciencequant-ph

Optimal switching of a nanomagnet assisted by microwaves

N. Barros、M. Rassam、H. Jirari 等 4 位作者2010-12-17arXiv

We develop an efficient and general method for optimizing the microwave field that achieves magnetization switching with a smaller static field. This method is based on optimal control and renders an exact solution for the 3D microwave field that triggers the switching of a nanomagnet with a given anisotropy and in an…

Materials Science

Sound propagation and force chains in granular materials

Eli T. Owens、Karen E. Daniels2010-12-17arXiv

Granular materials are inherently heterogeneous, leading to challenges in formulating accurate models of sound propagation. In order to quantify acoustic responses in space and time, we perform experiments in a photoelastic granular material in which the internal stress pattern (in the form of force chains) is visible…

Materials ScienceSoft Condensed Matter

Transparent and Conductive Graphene Oxide/Poly(ethylene glycol) diacrylate Coatings Obtained by Photopolymerization

Marco Sangermano、Sophie Marchi、Luca Valentini 等 5 位作者2010-12-17Macromolecular Materials and Engineering

Abstract Water‐dispersed graphene oxide sheets were used to prepare graphene/poly(ethylene glycol) diacrylate resin composites by photopolymerization. It was found that graphene sheets undergo excellent morphological distribution within the resin system, giving rise to transparent composites with unaltered thermal pro…

Graphene research and applicationsAdvanced Sensor and Energy Harvesting MaterialsGraphene and Nanomaterials Applications

Cationic and charge-neutral calcium tetrahydroborate complexes and their use in the controlled ring-opening polymerisation of rac-lactide

M.G. Cushion、Philip Mountford2010-12-17Chemical Communications

The first cationic main group tetrahydroborate complexes are reported. [Ca(BH(4))(THF)(5)][BPh(4)] and the charge neutral (Tp((t)Bu,Me))Ca(BH(4))(THF) are initiators for the living ring opening polymerization of rac-lactide, the latter producing PLA with high levels of heterotactic enrichment. These represent a new cl…

Organometallic Complex Synthesis and Catalysisbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Antiproliferative activity of chelating N,O- and N,N-ruthenium(ii) arene functionalised poly(propyleneimine) dendrimer scaffolds

Preshendren Govender、Anna K. Renfrew、Catherine M. Clavel 等 6 位作者2010-12-17Dalton Transactions

Chelating neutral (N,O) and cationic (N,N) first- and second-generation ruthenium(II) arene metallodendrimers based on poly(propyleneimine) dendrimer scaffolds were obtained from dinuclear arene ruthenium precursors by reactions with salicylaldimine and iminopyridyl dendritic ligands, respectively. The N,N cationic co…

Metal complexes synthesis and propertiesDendrimers and Hyperbranched PolymersFerrocene Chemistry and Applications

First-principles study of phase stability of Gd-doped EuO and EuS

J. M. An、S. V. Barabash、V. Ozolins 等 5 位作者2010-12-17arXiv

Phase diagrams of isoelectronic Eu$_{1-x}$Gd$_x$O and Eu$_{1-x}$Gd$_{x}$S quasi-binary alloy systems are constructed using first-principles calculations combined with the standard cluster expansion approach and Monte-Carlo simulations. The oxide system has a wide miscibility gap on the Gd-rich side but forms ordered c…

Materials Science

Effect of SiO 2 on Densification and Microstructure Development in Nd:YAG Transparent Ceramics

Adam J. Stevenson、Xin Li、Miguel A. Martinez 等 9 位作者2010-12-17Journal of the American Ceramic Society

This paper examines the influence of SiO 2 doping on densification and microstructure evolution in Nd 3 x Y 3−3 x Al 5 O 12 (Nd:YAG) ceramics. Nd:YAG powders were doped with 0.035–0.28 wt% SiO 2 and vacuum sintered between 1484° and 1750°C. 29 Si magic‐angle spinning nuclear magnetic resonance showed that Si 4+ substi…

Luminescence Properties of Advanced MaterialsMicrowave Dielectric Ceramics SynthesisNuclear materials and radiation effects

Dispersion of linear and nonlinear optical susceptibilities and the hyperpolarizability of 3-methyl-4-phenyl-5-(2-pyridyl)-1,2,4-triazole

A.H. Reshak、Dalibor Štys、S. Auluck 等 4 位作者2010-12-17Physical Chemistry Chemical Physics

As a starting point for our calculation of 3-methyl-4-phenyl-5-(2-pyridyl)-1,2,4-triazole we used the XRD data obtained by C. Liu, Z. Wang, H. Xiao, Y. Lan, X. Li, S. Wang, Jie Tang, Z. Chen, J. Chem. Crystallogr., 2009 39 881. The structure was optimized by minimization of the forces acting on the atoms keeping the l…

Magnetism in coordination complexesNonlinear Optical Materials ResearchPhotochemistry and Electron Transfer Studies

Fluorescent nanoscale zinc( ii )-carboxylate coordination polymers for explosive sensing

Chengyi Zhang、Yanke Che、Zengxing Zhang 等 5 位作者2010-12-17Chemical Communications

Fluorescent nanoscale coordination polymers with cubic morphology and long range ordered structure were fabricated and exhibited efficient sensing for both nitroaromatic explosive and nitromethane due to large surface area to volume ratio and strong binding affinity to explosive molecules.

Metal-Organic Frameworks: Synthesis and ApplicationsMolecular Sensors and Ion DetectionLuminescence and Fluorescent Materials

Mesoporous vanadium pentoxide nanofibers with significantly enhanced Li-ion storage properties by electrospinning

Danmei Yu、Changguo Chen、Shuhong Xie 等 9 位作者2010-12-17Energy & Environmental Science

Mesoporous V2O5 nanofibers were fabricated by a method combining sol–gel processing with electrospinning followed by annealing in air. The resultant nanofibers were 350 nm in diameter and consisted of porous polycrystalline vanadium oxide with a specific surface area of ∼97 m2 g−1. The mesoporous V2O5 nanofibers demon…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationTransition Metal Oxide Nanomaterials

Structural, Magnetic, Electrical, and Magnetoelectric Properties of Sm- and Ho-Substituted Nickel Ferrites

K. Kamala Bharathi、G. Markandeyulu、C.V. Ramana2010-12-17The Journal of Physical Chemistry C

Sm- and Ho-substituted and pure nickel ferrite materials, namely, NiFe 1.925 Sm 0.075 O 4, NiFe 1.925 Ho 0.075 O 4, and NiFe 2 O 4, have been synthesized by the solid-state chemical reaction, and their structural, magnetic, dc electrical conductivity, ferromagnetic, ferroelectric, and dielectric properties have been e…

Multiferroics and related materialsMagnetic Properties and Synthesis of FerritesMagnetic Properties and Applications

A facile preparation route for boron-doped graphene, and its CdTe solar cell application

Tianquan Lin、Fuqiang Huang、Jun Liang 等 4 位作者2010-12-17Energy & Environmental Science

High quality freestanding pristine graphene (PG) and boron-doped graphene (BG) were prepared by a novel and versatile method. BG is more conductive than PG due to a larger density of state generated near the Fermi level. Using BG as a back electrode, we achieved improved hole-collecting ability and photovoltaic effici…

Graphene research and applications2D Materials and ApplicationsQuantum Dots Synthesis And Properties

Efficiently Harvesting Excitons from Electronic Type-Controlled Semiconducting Carbon Nanotube Films

Dominick J. Bindl、Meng‐Yin Wu、Frederick C. Prehn 等 4 位作者2010-12-17Nano Letters

We have employed thin films of highly purified semiconducting carbon nanotubes as near-infrared optical absorbers in heterojunction photovoltaic and photodetector devices with the electron acceptor C(60). In comparison with previous implementations of more electrically heterogeneous carbon nanotube/C(60) devices, we h…

Carbon Nanotubes in CompositesMolecular Junctions and NanostructuresFullerene Chemistry and Applications

Reversibly Thermochromic, Fluorescent Ultrathin Films with a Supramolecular Architecture

Dongpeng Yan、Jun Lu、Jing Ma 等 6 位作者2010-12-17Angewandte Chemie International Edition

Thermochromic luminescence is characteristic of the title system, which is fabricated by layer-by-layer assembly of anionic bis(2-sulfonatostyryl)biphenyl (BSB) and positively charged layered double hydroxide (LDH) nanosheets on quartz glass. The BSB/LDH films show fast luminescent response and switching properties, i…

Luminescence Properties of Advanced MaterialsPolyoxometalates: Synthesis and ApplicationsLayered Double Hydroxides Synthesis and Applications

Numerical Analysis of Dynamic Mechanical Properties for Rock Sample under Strong Impact Loading

Fuqiang Gao、Ai‐Jun Hou、Xiaolin Yang2010-12-16International Journal of Information Engineering and Electronic Business

Stress wave propagation effect and failure characteristic of limestone were studied by one-stage lightgas gun induced-plate impact experiment technology. The experiment results indicate that dispersion effect and attenuation characteristic exist in impacting rock. The failure of rock sample has division characteristic…

Rock Mechanics and ModelingHigh-Velocity Impact and Material BehaviorElectromagnetic Launch and Propulsion Technology

Viability and pluripotency studying of human embryo stem cells labeled with quantum dots

Jing Ruan、Jie Shen、Hua Song 等 7 位作者2010-12-16Nano Biomedicine and Engineering

Semiconductor quantum dots (QDs) hold increasing potential for cellular imaging both in vitro and in vivo. In this report, we aimed to study imaging of human embryonic stem (ES) cells labeled with quantum dots (QDs), and to evaluate the viability and pluripotency of human ES cells labeled with QDs. We used the Tat-QDs…

Quantum Dots Synthesis And PropertiesPluripotent Stem Cells ResearchTissue Engineering and Regenerative Medicine

Photoconductive Gain and Low-Frequency Noise Characteristics of ZnO Nanorods

Shie‐Ming Peng、Yan‐Kuin Su、Liang‐Wen Ji 等 9 位作者2010-12-16Electrochemical and Solid-State Letters

This investigation elucidates the characteristics of Schottky barrier UV sensors with ZnO nanorods. The nanorods are selectively distributed among the interdigitated silver electrodes, which can enable precise positioning and fabrication of the devices inexpensively. The freestanding nanorod provides an efficient ligh…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials