Materials Literature
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Many ordered adlayer structures have been reported for CO on the (100) surfaces of Pt, Rh, Pd, Ni and Cu. Also, some ordered structures are known for NO on the same surfaces. The current review includes all those articles that give a graphical representation of the position of the adsorbates inside the unit cell. The…
1. Tutorial Reviews 1.1 Coupling Chemistries for the Modification and Functionalization of Surfaces to Create Advanced Bio-interfaces, H. Schonherr 1.2 Surface Plasmon Resonance-Based Biosensors, J. Dostalek, Chun Jen Huang and W. Knoll 1.3 Surface Modification and Adhesion, R. Forch 1.4 Modern Biological Sensors, A.T…
Metal clusters have been investigated rather intensely for both fundamental and technological reasons. In this work we report the results of plane-wave density functional theory calculations of Fe, Co, and Ni adatoms and dimers adsorbed on graphene. We study both homonuclear and heteronuclear dimers, and the latter in…
Abstract The development of a novel nucleophilic thio‐bromo “Click” reaction, specifically base‐mediated thioetherification of thioglycerol with α‐bromoesters, is reported. Combination of this thio‐bromo click reaction with subsequent acylation with 2‐bromopropionyl bromide provides an iterative two‐step divergent gro…
Abstract The development of a novel nucleophilic thio‐bromo “Click” reaction, specifically base‐mediated thioetherification of thioglycerol with α‐bromoesters was reported in an earlier article. The combination of this thio‐bromo click reaction with subsequent acylation with 2‐bromopropionyl bromide provides an iterat…
High coercivity (9.47 kOe) has been obtained for oleic acid capped chemically synthesized CoFe(2)O(4) nanoparticles of crystallite size approximately 20 nm. X-ray diffraction analysis confirms the formation of spinel phase in these nanoparticles. Thermal annealing at various temperatures increases the particle size an…
In this work, the synthesis of gallic acid-chitosan and catechin-chitosan conjugates was carried out by adopting a free radical-induced grafting procedure. For this purpose, an ascorbic acid/hydrogen peroxide redox pair was employed as radical initiator. The formation of covalent bonds between antioxidant and biopolym…
Water drops on hydrophobic microtextured materials sit on a mixture of solid and air. In standard superhydrophobic situations, the drop contacts more air than solid, so that we can think of exploiting the insulating properties of this sublayer. We show here that its presence induces a significant delay in freezing, wh…
Irradiation of graphene on SiO2 by 500 eV Ne and He ions creates defects that cause intervalley scattering as is evident from a significant Raman D band intensity. The defect scattering gives a conductivity proportional to charge carrier density, with mobility decreasing as the inverse of the ion dose. The mobility de…
First-principles calculations of structure optimization, phonon modes, and finite temperature molecular dynamics predict that silicon and germanium can have stable, two-dimensional, low-buckled, honeycomb structures. Similar to graphene, these puckered structures are ambipolar and their charge carriers can behave like…
Fe-Cr base high damping alloys(HDA).as the typical ferromagnetic type HDA,have been well investigated in a long history due to their merits in low cost and superior workability like steels,and are widely applied for suppression of noise or vibration in many industrial fields.The magnetoelastic coupling in ferromagneti…
The aim of our research reported in this paper is to mimic and understand gallstone formation. The precipitation of calcium carbonate by reacting CaCl 2 with NaHCO 3 in model bile containing 68.6 mol % of taurocholate, 22.9 mol % of lecithin, and 8.5 mol % of cholesterol with a total lipid (taurocholate + lecithin + c…
The thermal stability of highly ordered two-dimensional superlattices consisting of dodecanethiol-ligated Au nanoparticles has been investigated using in situ grazing incidence small-angle x-ray scattering in air and in vacuum. In the lower temperature region (<70 °C), annealing in air results in a minimal change of s…
We present results of mechanical stress relaxation measurements on polymers confined at the air-water interface in the form of a monolayer. Systematic measurements allow, to our knowledge, for the first time, observation of the scaling of the stress relaxation time of the highly confined polymers as a function of both…
The electron and hole spectrum in single and bilayer graphene is derived from known one-dimensional models, and the relation between the spectrum and symmetry of the lattice is shown.
Nearly monodisperse MnO nanocrystals were synthesized by the thermal decomposition of manganese oleate using the hot-injection method. The growth dynamics of the nanocrystals was studied by the time-sampling method, which revealed an interesting growing-to-shrinking behavior accompanied by a broadening−narrowing−broad…
'Forbidden' Bragg reflections of iron orthoborate Fe(3)BO(6) were studied theoretically and experimentally in the vicinity of the iron K edge. Their energy spectra are explained as resulting from the interference of x-rays scattered from two inequivalent crystallographic sites occupied by iron ions. This particular st…
In our work we have focused on the incorporation of magnetite nanoparticles (NPs) into poly(allylamine hydrochloride)/poly(sodium 4-styrenesulfonate) polyelectrolyte multilayers (PEMs). The main goal of presented studies was to control the two-dimentional ordering of NPs within polyelectrolyte films. The ordering of N…
Porous alumina film on aluminum with gel-like pore wall was prepared by a two-step anodization of aluminum, and the corresponding gel-like porous film was etched in diluted NaOH solution to produce alumina nanowires in the form of densely packed alignment. The resultant alumina nanowires were reacted with NH(3) and ev…
We derive a posteriori estimates for a discretization in space of the standard Cahn–Hilliard equation with a double obstacle free energy. The derived estimates are robust and efficient, and in practice are combined with a heuristic time step adaptation. We present numerical experiments in two and three space dimension…