Materials Literature
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Abstract Epoxidized natural rubber (ENR) with a level of epoxide groups of 20 mol % was prepared via the performic epoxidation method. It was then used to blend with high‐density polyethylene (HDPE) at various blend ratios. Three types of blend compatibilizers were prepared. These included a graft copolymer of HDPE an…
This work reports on the detection of the valence band of buried Heusler compounds by means of hard x-ray photoemission spectroscopy. The measurements have been performed on the so-called “half” tunnel junctions that are thin films of Co2MnSi underneath MgO. Starting from the substrate, the structure of the samples is…
The dynamics of stress-accelerated dislocations in copper is investigated using molecular dynamics simulations. The structure and motion of dissociated edge dislocations are analyzed using the common neighborhood parameter and local stresses. Dislocations are accelerated by high shear stresses and reach stable velocit…
The formability of metals depends on the crystallographic texture produced during thermo-mechanical processing. The crystallographic orientation of the deformed grains results from the applied deformation path. Asymmetric rolling is a new process that is expected to improve the formability of rolled aluminium sheets b…
Photoactivation of multiple carrier charge extraction in a tandem cell configuration is demonstrated. An all-solution-processed tandem photovoltaic structure, consisting of a hydrazine treated PbSe nanocrystal film and a P3HT/PCBM bulk-heterojunction solar cell, was fabricated. The PbSe nanocrystal film was used as th…
We report a detailed magnetic, magnetocaloric, and magnetotransport study on ${R}_{2}{\text{Ni}}_{2}\text{Sn}$ compounds with different rare earths. The magnetic state of these compounds is found to be complex because of the coexistence of ferromagnetic and antiferromagnetic components. These compounds show phenomena…
Alignment of pristine carbon nanotubes (P-CNTs) and fluorinated carbon nanotubes (F-CNTs) in nylon-6 polymer composite fibers (PCFs) has been achieved using a single-screw extrusion method. CNTs have been used as filler reinforcements to enhance the mechanical and thermal properties of nylon-6 composite fibers. The co…
Abstract Trimethylsilyl cellulose (TMSC) can be efficiently synthesized with 1,1,1,3,3,3‐hexamethyldisilazane (HMDS) by applying the ionic liquids (ILs) 1‐ethyl‐3‐methylimidazolium acetate, 1‐ethyl‐3‐methylimidazolium chloride, and 1‐butyl‐3‐methylimidazolium chloride as reaction medium, yielding pure biopolymer deriv…
The valence-band offset of ZnO∕MgO (111) heterojunction has been directly measured by x-ray photoelectron spectroscopy. Excluding the strain effect, the valence-band offset is determined to be 0.87±0.20eV, and the conduction-band offset ΔEC is deduced to be −3.59±0.20eV, indicating that ZnO∕MgO heterojunction has a ty…
An increase in the health and environment legislation awareness pushed the textile manufacturers to develop their strategies to produce eco-friendly flame-retardant textiles with competitive cost. Chitosan is added during the phosphorylation process as a nitrogen source that has synergistic effect with phosphorus. Inc…
We report on the tunability, by a magnetic field, of a negative permeability metamaterial consisting of stacked arrays of broadside-coupled split ring resonators infiltrated with liquid crystals (LCs). The resonant frequency shift was numerically assessed by a rigorous anisotropic analysis of the reorientation of LC m…
Predominantly this article deals with the question of how to design new solid catalysts for a variety of industrial and laboratory-orientated purposes. A generally applicable strategy, illustrated by numerous examples, is made possible based on the use of nanoporous materials on to the (high-area) inner surfaces of wh…
The dc magnetization, ac susceptibility, and isothermal remanent magnetization measurements are carried out for antiperovskite Mn3GaN. Strong indication for a frozen state with freeing temperature of Tf at ∼133K is found, determined from the difference between field-cooled and zero-field-cooled magnetizations. The ac…
The structural relaxation (SR) process in an amorphous chalcogenide material (Ge2Sb2Te5) is studied by electrical measurements on phase-change memory devices. SR induces a change in the conduction regime from Poole to Poole–Frenkel transport, evidencing a temperature accelerated defect-annihilation process. Based on a…
The deposition of plasma polymer coatings onto porous alumina (PA) membranes was investigated with the aim of adjusting the surface chemistry and the pore size of the membranes. PA membranes from commercial sources with a range of pore diameters (20, 100 and 200 nm) were used and modified by plasma polymerization usin…
Abstract Fire retardancy behavior of polypropylene–magnesium hydroxide–clay composites of different morphologies is presented. Layer‐ and needle‐like clay nanoparticles in natural and organically surface modified form have been compared. Fire retardant performance of the composites was evaluated by conical combustor a…
Our goal was to analyze the changes in morphology and physiological function (phagocytosis, migratory capabilities, humoral and cellular response, and nitric oxide secretion) of murine macrophages after labeling with a clinically used superparamagnetic iron oxide (SPIO), ferucarbotran. In SPIO-treated macrophages, nan…
The establishment of a molecular view of heterogeneous catalysis has been hampered for a number of reasons. There are, however, recent developments, which show that we are now on the way towards reaching a molecular-scale picture of the way solids work as catalysts. By a combination of new theoretical methods, detaile…
The electronic and magnetic properties of the mother material LaOFeAs of new superconductors have been carefully studied using first-principles electronic structure calculations based on the generalized gradient approximation in the density functional theory. The present calculation predicts that the ground state of L…
The magnetic phase transitions and the magnetocaloric effect in the Ising antiferromagnet DySb have been studied. A field-induced sign change of the magnetocaloric effect has been observed which is related to a first-order field-induced metamagnetic transition from the antiferromagnetic to the ferromagnetic states at/…