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Measurement of the hard-sphere equation of state using screened charged polystyrene colloids

M. A. Rutgers、J. H. Dunsmuir、Jiangeng Xue 等 5 位作者1996-03-01Physical review. B, Condensed matter

Using a high-resolution digital x-ray camera we have accurately measured the density profiles of several sediments of highly screened polystyrene colloidal spheres suspended in water. From the integral of the profile with height we directly measured the osmotic pressure as a function of volume fraction. The results ar…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesElectrostatics and Colloid Interactions

Devulcanization of Waste Tire Rubber by Powerful Ultrasound

A. S. Tukachinsky、D. Schworm、А. I. Isayev1996-03-01Rubber Chemistry and Technology

Abstract Ground rubber tire (GRT) is devulcanized in a continuous process where the rubber crumb is conveyed by a screw extruder to a thin gap between a stationary die and a vibrating horn. Ultrasound amplitude, gap thickness and the duration of the treatment are varied, and their effect on the rubber properties is st…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer composites and self-healing

Static and Dynamic Compressive Behavior of Aluminum Nitride under Moderate Confinement

Weinong Chen、G. Ravichandran1996-03-01Journal of the American Ceramic Society

An experimental technique for imposing lateral confinement on specimens subjected to dynamic or quasi‐static uniaxial compression has been developed. Lateral confinement is provided by a shrink‐fit metal sleeve installed on the lateral surface of a cylindrical ceramic specimen. Experiments using this technique were pe…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsHigh-Velocity Impact and Material Behavior

MR of carcinoma-specific monoclonal antibody conjugated to monocrystalline iron oxide nanoparticles: the potential for noninvasive diagnosis.

Laura G. Remsen、Christopher McCormick、Simon Roman-Goldstein 等 9 位作者1996-03-01PubMed

PURPOSE: To determine if tumor-specific monoclonal antibodies conjugated to superparamagnetic monocrystalline iron oxide nanoparticles can be used to yield specific diagnoses with the use of MR imaging. METHODS: Monoclonal antibodies conjugated to monocrystalline iron oxide nanoparticles were given to nude rats with i…

Nanoparticle-Based Drug DeliveryMonoclonal and Polyclonal Antibodies ResearchCharacterization and Applications of Magnetic Nanoparticles

Alkalinity, pH, and copper corrosion by‐product release

Marc Edwards、Michael R. Schock、Travis Meyer1996-03-01American Water Works Association

The conventional Langelier index or Larson's ratio approach to controlling copper corrosion by‐product release is demonstrably inaccurate. Contrary to expectations, higher bicarbonate concentrations exacerbate copper corrosion rates and by‐product release. In fact, as illustrated by monitoring experiences of large uti…

Corrosion Behavior and InhibitionWater Treatment and DisinfectionConcrete Corrosion and Durability

Chitosan Treatment: An Emerging Strategy for Enhancing Resistance of Greenhouse Tomato Plants to Infection by Fusarium oxysporum f.sp. radicis-lycopersici

Pierre Lafontaine、Nicole Benhamou1996-03-01Biocontrol Science and Technology

The potential of chitosan, a non-toxic and biodegradable polymer of beta -1,4-glucosamine, for controlling fusarium crown and root rot of greenhouse-grown tomato caused by Fusarium oxysporum f.sp. radicis-lycopersici (FORL) was investigated. The amendment of plant growth substratum with chitosan at concentrations of 1…

Plant tissue culture and regenerationNanocomposite Films for Food PackagingPineapple and bromelain studies

First-principles calculation of the pressure dependence of phase equilibria in the Al-Li system

Marcel H. F. Sluiter、Yutaka Watanabe、D. de Fontaine 等 4 位作者1996-03-01Physical review. B, Condensed matter

The solid-phase portion of the Al-Li phase diagram has been computed from first principles both at zero pressure and at a hydrostatic compression of 5.4 GPa. Computation of the pressure dependence of the Al-Li phase equilibria answers two questions: (1) how important is the effect of the atomic size difference, and (2…

X-ray Diffraction in CrystallographyThermodynamic and Structural Properties of Metals and AlloysMetallurgical and Alloy Processes

Preferred Orientations of NiO Films Prepared by Plasma-Enhanced Metalorganic Chemical Vapor Deposition

Eiji Fujii、Atsushi Tomozawa、Hideo Torii 等 4 位作者1996-03-01Japanese Journal of Applied Physics

Thin films of nickel oxide (NiO) with NaCl-type structure were prepared on glass substrates at 400°C by plasma-enhanced metalorganic chemical vapor deposition using nickel acetylacetonate as a source material. The relationship between O 2 flow rate, and preferred orientation and microstructure of the NiO films was inv…

ZnO doping and propertiesTransition Metal Oxide NanomaterialsGa2O3 and related materials

Grain Boundary Films in Rare‐Earth‐Glass‐Based Silicon Nitride

Chong‐Min Wang、Xiaoqing Pan、Michael J. Hoffmann 等 5 位作者1996-03-01Journal of the American Ceramic Society

The thickness of the intergranular films in Si 3 N 4 densified with lanthanide oxides has been systematically investigated using high‐resolution transmission electron microscopy. Four lanthanide oxides—La 2 O 3 , Nd 2 O 3 , Gd 2 O 3 , and Yb2O3—as well as Y 2 O 3 are chosen so that the results will reflect the overall…

Advanced ceramic materials synthesisSemiconductor materials and devicesGlass properties and applications

Sequential Functionalisation of Bis-Protected Tetrathiafulvalene-dithiolates

Klaus B. Simonsen、Niels Svenstrup、Jesper Lau 等 7 位作者1996-03-01Synthesis

All articles of this category The utilisation of the 2-cyanoethyl group as a versatile protecting group for 2-thioxo-1,3-dithiole-4,5-dithiolates and tetrathiafulvalene-thiolates is reported. Mono deprotection of bis-protected 2-thioxo-1,3-dithiole-4,5-dithiolate and of bis-protected tetrathiafulvalene-2,3-dithiolates…

Crystallography and molecular interactionsOrganic and Molecular Conductors ResearchOrganometallic Compounds Synthesis and Characterization

Application of polyaniline (emeraldine base, EB) in polymer light-emitting devices

H.L. Wang、A. G. MacDiarmid、Y.Z. Wang 等 5 位作者1996-03-01Synthetic Metals

We report the fabrication of several multilayer light-emitting-diode (LED) devices based on a novel conjugated polymer, poly(2,5-dihexadecanoxy phenylene vinylene pyridyl vinylene) (PPV-PPy V), involving the use of polyaniline (emeraldine base, EB) as an insulating layer between the emissive polymer layer and the elec…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Effect of host glass on the optical absorption properties ofNd3+,Sm3+, andDy3+in lead borate glasses

M. B. Saisudha、J. Ramakrishna1996-03-01Physical review. B, Condensed matter

The effect of host glass composition on the optical absorption spectra of ${\mathrm{Nd}}^{3+}$, ${\mathrm{Sm}}^{3+}$, and ${\mathrm{Dy}}^{3+}$ in lead borate glasses, with PbO contents varying from 30 to 70 mol %, has been analyzed using Judd-Ofelt theory and the compositional dependence has been determined for the hy…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsQuantum optics and atomic interactions

Hydrothermal Synthesis of Cerium(IV) Oxide

Masanori Hirano、Etsuro KATO1996-03-01Journal of the American Ceramic Society

CeO 2 powders have been prepared from cerium(III) nitrate, cerium(IV) sulfate, and cerium(IV) ammonium sulfate under hydrothermal conditions at 120° to 200°C for 5 to 40 h. The effects of the starting cerium compounds, hydrothermal treatment temperature, and the concentration of the solutions on the crystal growth of…

Catalytic Processes in Materials ScienceRadioactive element chemistry and processing

Evidence for collective spin dynamics above the ordering temperature inLa1−xCaxMnO3+δ

S. B. Oseroff、M. S. Torikachvili、Joseph M. Singley 等 6 位作者1996-03-01Physical review. B, Condensed matter

We have measured the temperature dependence of the electron paramagnetic resonance (EPR) of ${\mathrm{La}}_{1\mathrm{\ensuremath{-}}\mathit{x}}$${\mathrm{Ca}}_{\mathit{x}}$${\mathrm{MnO}}_{3+\mathrm{\ensuremath{\delta}}}$ for 0.0\ensuremath{\le}x\ensuremath{\le}1 at 9.2 and 35 GHz from 270 to 800 K. We vary \ensuremat…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsAdvanced Condensed Matter Physics

Oxide surfaces

Hans‐Joachim Freund、H. Kuhlenbeck、Volker Staemmler1996-03-01Reports on Progress in Physics

We review the current knowledge of the geometric and electronic structure of oxide surfaces. In particular, material published during the last five years and going beyond the latest book by Henrich and Cox, Surface Science of Oxide Surfaces, is documented. In addition to the discussion of effects on and in bulk oxide…

ZnO doping and propertiesCatalytic Processes in Materials ScienceElectronic and Structural Properties of Oxides

Synthesis of a Stable Hexagonally Packed Mesoporous Niobium Oxide Molecular Sieve Through a Novel Ligand‐Assisted Templating Mechanism

David M. Antonelli、Jackie Y. Ying1996-03-01Angewandte Chemie International Edition in English

Since the porous structure is completely retained upon surfactant removal , Nb‐TMS1, a hexagonally packed mesoporous transition metal oxide, is an interesting molecular sieve. The synthesis of this material was accomplished by a novel route in which the inorganic precursor 1 and the surfactant 2 were attached by a cov…

Mesoporous Materials and CatalysisPolyoxometalates: Synthesis and ApplicationsCatalysis and Hydrodesulfurization Studies

Another look at the deterioration of calcium aluminate cement concrete

Jaromir Jambor、Jan Skalny1996-03-01Materiales de Construccion

Potential degradation of concrete structures made of calcium aluminate cement (CAC) is well known and is caused by transformation (conversion) of the thermodynamically metastable into stable calcium aluminate hydrate phases. This recrystallization is influenced by temperature and humidity; the structural degradation o…