Materials Literature
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СавÑемени маÑеÑиÑали, меÑÑнаÑодна наÑÑна конÑеÑенÑиÑа - Contemporary materials, International scientific conference,СавÑемени маÑеÑиÑали 2010 - наÑÑна конÑеÑенÑиÑа Ñ ÐаÑÐ¾Ñ ÐÑÑи
A diarylethene substituted with 3,4-(propane-1,3-diyldioxy)thiophene (ProDOT) was synthesized to induce electrochemical deposition of diarylethenes. The ProDOT substituted diarylethene (BTFPP) showed reversible photochromism from colorless to purple upon exposure to a UV light and bleached to colorless by a visibly li…
Four kinds of cinnamate-type monomers were synthesized as healing agents. Photoirradiation of the monomers gave cyclobutane-containing crosslinked polymers via [2+2] cycloaddition. Cyclobutane cleavage upon cracking of the crosslinked polymers and re-cycloaddition of the cracked polymers were investigated by FT-IR spe…
This article quantifies the effect of the operating pressure of the H2 + C2H4 gas mixture on the current density and threshold voltage of the electron emission from dense forests of multiwalled carbon nanotubes synthesized using thermal catalytic Chemical Vapor Deposition under near atmospheric pressure process condit…
P3HT/graphene nanocomposite was prepared via in-situ reduction of exfoliated graphite oxide in the P3HT polymer matrix, where the exfoliated graphite oxide was formed beforehand via the oxidation of graphite via the Hummers method. The oxidation reaction not only imparts functional groups, such as C=O, C-OH, and C-O-C…
Purpose – The purpose of this paper is to describe how to synthesise polyurethane resins by using different polyester polyols and HDI isocyanurate. The polyester polyols were prepared by reacting single diol with different diacids. The effects of these polyester polyols on the performance properties of the coating fil…
Peptide nanostructures assembled from an aromatic diphenylalanine have attracted considerable attention because of high thermal and mechanical stabilities of the assembled morphologies. Of diverse assembled structures, liquid crystalline peptide nanowires exhibiting optical and mechanical anisotropies can be a valuabl…
The chemical reactivity of freshly prepared porous silicon is similar to that of a reducing agent on the surface of the nanocrystallites. Ag+ spontaneously reduces to form Ag0 granular coatings on the surface of porous silicon at the expense of the oxidation of silicon hydride and silicon. Atomic Force Microscopy show…
Abstract A novel method for the preparation of 1,3-bis(2,2-dimethyl-1,3-dioxan-5-yloxy)propan-2-ol, a branched oligoglycerols (BGL), was developed from 1,3-diallylated glycerol in excellent yield.
Graphene-CuO nanocomposite was synthesized by a simple wet chemical approach. Using Cu(CH3COO)2 as the starting material, CuO was synthesized and loaded on the graphene sheets through the reaction with NH3H2O in alkaline system. Transmission electron microscopy, powder X-ray diffraction, X-ray photoelectron spectrosco…
The biodegradable polyanhydride copolymers P(CPP-SA) composed of p-carboxyhenoxy propane (CPP) and sebacic acid (SA) at weight ratios of 20:80, 35:65 and 50:50 were polymerized by a melt polycondensation process without catalyst. The copolymers were characterized by fourier transform infrared spectroscopy (FT-IR), 1H-…
Purpose The purpose of the paper is to examine the synthesis of polyaniline (PAn) and poly( m ‐toluidine) (PmT) via an inverse emulsion polymerisation pathway and evaluate of the synthesised polymers as corrosion inhibitors for steel protection in surface coatings. Design/methodology/approach PAn and PmT were prepared…
Synthesis of platinum nanoclusters (PNCs), with its advantages of high surface area and reduced materials costs, represents a greatly interesting class of nanomaterials. In this paper, a one-step, rapid and efficient aqueous-phase reaction to straightforwardly produce PNCs in high yield is proposed without the need fo…
Doped ceria has been considered for high oxygen ion conductivity for solid oxide fuel cells. In the present study, 20 mole% samarium doped nano ceria powder was prepared by wet chemical synthesis and sintered at different temperatures to retain submicron grains (> 92-96% density). ionic conductivity of the sintered pe…
The plasticity of Ti3SnC2, a recently synthesized MAX phase, was investigated. Localized deformation was induced by nanoindentation in a polycrystalline sample, and the resulting surface topography was observed by atomic force microscopy (AFM). For several grains, buckling around the indent was observed, in agreement…
Three genes, nadA, nadB, and nadC, involved in NAD de novo biosynthesis are broadly conserved in the genomes of numerous bacterial species. In the genome of Corynebacterium glutamicum, nadA and nadC but not nadB are annotated. The nadA and nadC genes are located in a gene cluster containing two other genes, designated…
beta-Ketothiolases catalyze the first step of poly(3-hydroxybutyrate) [poly(3HB)] synthesis in bacteria by condensing two molecules of acetyl coenzyme A (acetyl-CoA) to acetoacetyl-CoA. Analyses of the genome sequence of Ralstonia eutropha H16 revealed 15 isoenzymes of PhaA in this bacterium. In this study, we generat…
The carrier type and density in Bi2Se3 single crystals are systematically tuned by introducing a calcium (Ca) dopant. A carrier density of ~1x1017 cm-3 which corresponds to ~25 meV in the Fermi energy is obtained in both n- and p-type materials. Electrical transport properties show that the insulating behavior is achi…
We investigate the propagation and scattering of highly nonlinear waves in disordered granular chains composed of diatomic (two-mass) units of spheres that interact via Hertzian contact. Using ideas from statistical mechanics, we consider each diatomic unit to be a "spin", so that a granular chain can be viewed as a s…
Silver nanoparticles (SNPs) translocate to the brain through the blood stream after they are implanted in vivo. The aim of this study was to investigate the distribution of SNPs that crossed through the blood-brain barrier (BBB). An in vitro BBB model established by co-cultures of rat brain microvessel vascular endoth…