Materials Literature
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We extend the design of radially symmetric invisibility cloaks through transformation optics as proposed by Pendry et al. [Science 312, 1780 (2006)] to coated cylinders of an arbitrary cross section. The validity of our Fourier-based approach is confirmed by both analytical and numerical results for a cloak displaying…
We have investigated the influence of nuclear geometric relaxation on the extent of the excited-state electronic delocalization in conjugated zinc porphyrin oligomers using ultrafast transient photoluminescence spectroscopy. By use of metal-coordinating templates that force the oligomers into specific geometries in so…
B und N als Rückgrat: Lösliche lineare Polyaminoboran-Homopolymere und -Copolymere mit hohen Molekulargewichten wurden durch die iridiumkatalysierte Dehydrokupplung der leicht erhältlichen Amin-Boran-Addukte RNH2⋅BH3 synthetisiert (R=H, Me, nBu).
Recent research in the field of LbL assembly is summarized and categorized as fabrication, sensing, drug release/delivery, and cell technology. Special emphasis is given to topics such as cell-membrane-mimic assembly, fabrication of free-standing biomolecular structures including protein microtubes, detection of DNA a…
Functional giants: Amphiphilic bioconjugates can be synthesized in situ by grafting polystyrene from a protein (see scheme). The resulting giant amphiphiles display low polydispersities and the characteristic aggregation properties of amphiphilic biomacromolecules. A second, catalytically active guest protein can also…
The kinetics and mechanism of ether and alkanol cleavage reactions on Brønsted acid catalysts based on polyoxometalate (POM) clusters are described in terms of the identity and dynamics of elementary steps and the stability of the transition states involved. Measured rates and theoretical calculations show that the en…
This paper deals with the synthesis of short Saccaharum Cilliare fibre (SC) reinforced Urea‐Formaldehyde (UF) matrix based polymer composites. Present work reveals that mechanical properties such as: tensile strength, compressive strength, flexural strength and wear resistance of the UF matrix increase up to 30% fibre…
The Medium-Chain Dehydrogenase/Reductase Engineering Database (MDRED, http://www.mdred.uni-stuttgart.de) has been established to serve as an analysis tool for a systematic investigation of sequence-structure-function relationships. It includes sequence and structure information of 2684 and 42 medium-chain dehydrogenas…
This book is an update and major revision to Radiological Assessment: A Textbook on Environmental Dose Analysis published by the U.S. Nuclear Regulatory Commission in 1983. It focuses on risk to the public because decision makers typically use that endpoint to allocate resources and resolve issues. Chapters in the boo…
Abstract The long‐term thermal‐oxidative aging behavior of polyamide 6 (PA6) was studied by comparison with the stabilized sample in this work. The variation of mechanical properties of the pure and the stabilized samples of PA6 with aging time at 110°C, 130°C, and 150°C were investigated, respectively. The aging mech…
We report on how to tune the density of zinc oxide (ZnO) nanowire arrays in a wide range (more than 5 orders of magnitude) in a low temperature (80 °C) solution-phase growth process. A model based on the coexistence of nanowire growth and etching of the ultrathin (<3.5 nm) ZnO seed-layer was proposed to explain the ef…
Self-assembled monolayer-protected nanoparticles are promising candidates for applications, such as sensing and drug delivery, in which the molecular ligands' interactions with the surrounding environment play a crucial role. We recently showed that, when gold nanoparticles are coated with a binary mixture of immiscib…
Abstract Calcium alginate yarn (30 fibers) and calcium alginate nanocomposite yarn (30 fibers) containing 0.05–2.00% w/w chitin whiskers were both prepared by wet spinning process. The whiskers were prepared by acid hydrolysis of chitin from shrimp shells. The average length and width of the whiskers were 343 and 46 n…
Abstract For the miniaturization of microelectronics, carbon nanotubes (CNTs) are regarded as ideal candidates for the next generation of nanoelectronics because of their excellent properties. To realize CNT‐based electronics, intramolecular junctions are required components, which can not only connect different CNTs…
A phase-field approach for quantitative simulations of grain growth in anisotropic systems is introduced, together with a new methodology to derive appropriate model parameters that reproduce given misorientation and inclination dependent grain boundary energy and mobility in the simulations. The proposed model formul…
Two novel distyryl-boradiazaindacene dyes with dimethylaminostyryl and pyridylethenyl substituents display opposite spectral shifts on protonation with TFA in organic solvents. This bidirectional switching of the dyes can be shown to be directly related to ICT donor and acceptor characteristics of the substituents att…
We use first-principles methods to investigate the adsorption of Cu, Pb, Ag, and Mg onto a H-terminated Si surface. We show that Cu and Pb can adsorb strongly while Ag and Mg are fairly inert. In addition, two types of adsorption states are seen to exist for Pb. We also study the clustering energetics of Cu and Pb on…
Thin film growth of ferroelectric or multiferroic materials on SrTiO3(111) with a buffer electrode has been hampered by the difficulty of growing flat electrodes on this polar orientation. We report on the growth and characterization of SrRuO3 thin films deposited by pulsed laser deposition on SrTiO3(111). We show tha…
The phenomenological theory of ferroelectricity in spiral magnets presented in [M. Mostovoy, Phys. Rev. Lett. 96, 067601 (2006)] is generalized to describe consistently states with both uniform and modulated-in-space ferroelectric polarizations. A key point in this description is the symmetric part of the magnetoelect…
Responsive polymer microgels can be employed for the preparation of stimuli-sensitive emulsions. The microgels used in this study are based on cross-linked copolymers including N-isopropylacrylamide and methacrylic acid. We conducted the synthesis under acidic and basic conditions to investigate the effect of changes…