Materials Literature
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Abstract Vermutlich werden synthetische 2D‐Polymere auf vielen Gebieten der Naturwissenschaft und Technik Bedeutung erlangen, und zwar grundlegende ebenso wie praktische. Daher überrascht es, dass auf diesem Gebiet bisher so wenige Fortschritte zu verzeichnen sind. In den letzten Jahrzehnten sind zwar viele Ansätze zu…
In cases where direct suture of two nerve stumps is not feasible, generally a scaffold is required to bridge the gap and guide nerve regeneration. The scaffold used in nerve tissue engineering applications requires optimal guidance effect, mechanical strength, and cellular compatibility. A number of studies suggest th…
A novel kind of miniature boat that might have many potential applications was fabricated from superhydrophobic copper meshes for the first time. These boats not only floated freely on a water surface but also exhibited striking loading capacities. By selection of the pore size of copper meshes, a loading capacity gre…
We report the enhanced transmission of electromagnetic waves through a single subwavelength aperture by using a split-ring resonator (SRR) at microwave frequencies. By placing a single SRR at the near field of the aperture, strongly localized electromagnetic fields are effectively coupled to the aperture with a radius…
Volume alteration in solid materials is a common cause of material failure. Here we investigate the crack formation in thin elastic layers attached to a substrate. We show that small variations in the volume contraction and substrate restraint can produce widely different crack patterns ranging from spirals to complex…
We report a time resolved imaging and micromagnetic simulation study of the relaxation dynamics of a magnetic vortex in the non-linear regime. We use time-resolved photoemission electron microscopy and micromagnetic calculations to examine the emergence of non-linear vortex dynamics in patterned Ni80Fe20 disks in the…
The design, construction, and preliminary characterization of a novel family of spider silk-like block copolymers are described. The design was based on the assembly of individual spider silk modules, in particular, polyalanine (A) and glycine-rich (B) blocks, that display different phase behavior in aqueous solution.…
Different samples of Zn1-xMnxO series have been prepared by conventional solid state sintering method. It has been identified, up to what extent of doping enable us to synthesize single-phase polycrystalline Mn doped ZnO samples which is one of the prerequisite for dilute magnetic semiconductor and we have analyzed it…
We present a model for Desorption Induce by (Multiple) Electronic Transitions (DIET/DIMET) based on potential energy surfaces calculated with the Delta Self-Consistent Field extension of Density Functional Theory. We calculate potential energy surfaces of CO and NO molecules adsorbed on various transition metal surfac…
POSITION OF ADHESIVE BONDING IN THE FIELD OF JOINING TECHNIQUES HISTORICAL DEVELOPMENT OD ADHESIVE BONDING ADHESION Classical Theories Chemical Reactions in Boundary Layers Behavior of Adhesion in Material Compounds New Aspects in the Field of Adhesion Conclusions CHEMISTRY AND PROPERTIES OF ADHESIVES Pressure Sensiti…
Sequential reaction of LH3 (LH3 = (S)P[N(Me)N=CH-C6H3-2-OH-3-OMe]3) with Co(OAc)2 x 4 H2O followed by reaction with lanthanide salts afforded trinuclear heterobimetalllic compounds {[L2Co2Ln][X]} [Ln = Eu (1), X = Cl; Ln = Tb (2), Dy (3), Ho (4), X = NO3] in excellent yields. These compounds retain their integrity in…
It has been shown that the combining of the electrical effect on the exchange bias field with giant magneto-resistance effect of the graphene/ferromagnet hybrid structures reveals a new non-volatile magnetic random access memory device conception. In such device an electric bias realizes the writing bits instead a mag…
Trace detection of polycyclic aromatic hydrocarbons is reported in this work on dithiocarbamate calix[4]arene functionalized Ag nanoparticles by using surface-enhanced Raman scattering (SERS). SERS spectra informed about the existence of the pollutant by measuring its characteristic fingerprint vibrational features. I…
Layered metal phosphonate, zinc phenylphosphonate (PPZn), reinforced poly(L-lactide) (PLLA) composites were fabricated by a melt-mixing technique. The nonisothermal and isothermal crystallization, melting behavior, spherulite morphology, crystalline structure, and static and dynamic mechanical properties of the PLLA/P…
Using pulsed optically detected magnetic resonance techniques, we directly probe electron-spin resonance transitions in the excited-state of single nitrogen-vacancy (NV) color centers in diamond. Unambiguous assignment of excited state fine structure is made, based on changes of NV defect photoluminescence lifetime. T…
We examined the effect of prolyl-hydroxyproline (Pro-Hyp), which occurs in human peripheral blood after ingestion of collagen peptide, on the migration and growth of mouse skin fibroblasts. Mouse skin discs were cultured on a 24-well plastic plate in a fetal bovine serum (FBS)-free medium. Addition of Pro-Hyp (200 nmo…
A biodegradable positron-emitting dendritic nanoprobe targeted at alpha(v)beta(3) integrin, a biological marker known to modulate angiogenesis, was developed for the noninvasive imaging of angiogenesis. The nanoprobe has a modular multivalent core-shell architecture consisting of a biodegradable heterobifunctional den…
Abstract Anorganisches Enzym? Ceroxidnanopartikel zeigen einzigartige Oxidaseaktivität bei niedrigen pH‐Werten. Diese Redoxkatalysatoren können in Immunassays (ELISA) verwendet werden, wenn sie mit geeigneten Liganden modifiziert sind (siehe Bild; hellblau, gelb: Nanopartikel mit Liganden). Diese Modifizierung ermögli…
Two factors are critical for understanding silks: the nanoscale semicrystalline folding structure, which gives high strength and toughness, and the degree of hydration of the disordered fraction, which modifies these material properties. The combination of these two factors allows for a massive range of mechanical pro…
The condition under which the Wenzel or Cassie equation correctly estimates the most stable contact angle is reiterated and demonstrated: these equations do hold when the drop size is sufficiently large compared with the wavelength of roughness or chemical heterogeneity. The numerical demonstrations somewhat mimic rec…