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Electrochemical Impedance Spectroscopic Study of Passive Zirconium

Jiahe Ai、Yingzi Chen、Mirna Urquidi‐Macdonald 等 4 位作者2006-12-04Journal of The Electrochemical Society

The development of deterministic models for predicting the accumulation of corrosion damage to zirconium and Zircaloys in boiling water reactor coolant environments requires the acquisition of values for various model parameters. In the present work, the point defect model (PDM) was further developed to account for th…

Nuclear reactor physics and engineeringRadioactive element chemistry and processingNuclear Materials and Properties

Preparation and Properties of Manganese Oxide/Carbon Composites by Reduction of Potassium Permanganate with Acetylene Black

Xingkang Huang、Hongjun Yue、Adel Attia 等 4 位作者2006-12-04Journal of The Electrochemical Society

Amorphous manganese oxide/carbon composites were synthesized by directly reducing potassium permanganate with acetylene black (AB) as a cheap reducing agent. A reaction is postulated and confirmed by checking the evolved gas and other species such as and left in the mother liquor. All the composites were characterized…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationTransition Metal Oxide Nanomaterials

Shape Memory and Superelasticity

William F. Hosford2006-12-04Cambridge University Press eBooks

Shape memory alloys With the shape memory effect, heating reverses prior plastic deformation. Alloys that exhibit this effect are ordered solid solutions that undergo a martensitic transformation on cooling. Shape memory effects were first observed in AuCd in 1932, but it was the discovery by Buehler et al. in of the…

Shape Memory Alloy TransformationsCreativity in Education and Neuroscience

Comparative Study of Cu–CVD Seed Layer Deposition on Ru and Ta Underlayers

Hoon Kim、Yukihiro Shimogaki2006-12-04Journal of The Electrochemical Society

Ru was evaluated as a new underlayer material for depositing ultrathin chemical vapor deposited (CVD) Cu seed layers, and the morphology and adhesion property of CVD Cu films on Ru were compared to that of Ta. CVD Cu films deposited on Ru showed higher nuclei density than Cu films deposited on Ta. Relatively low depos…

Metal and Thin Film MechanicsSemiconductor materials and devicesCopper Interconnects and Reliability

Assembly and measurement of a hybrid nanowire-bulk thermoelectric device

Jennifer Keyani、Angelica M. Stacy、Jeff Sharp2006-12-04Applied Physics Letters

Bi 1 − x Sb x nanowires are predicted to show an increased thermoelectric efficiency compared to bulk materials. The authors have synthesized dense Bi0.3Sb0.7 nanowire arrays by electrodeposition into porous anodic alumina and fabricated Ni electrical contacts to the wires. The nanowire/alumina composite was assembled…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Radiation and Cooling Technologies

Electrochemical and Photoelectrochemical Characterization of the Passive Film Formed on AISI 254SMO Super-Austenitic Stainless Steel

T.L. Sudesh L. Wijesinghe、Daniel John Blackwood2006-12-04Journal of The Electrochemical Society

The structure and composition of the passive film formed on the super-austenitic AISI 254SMO stainless steel in borate solution were studied using photocurrent spectroscopy coupled with electrochemical measurements. Charge passed calculations suggested that the Cr ( VI ) phase formed in the transpassive region is inso…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsWelding Techniques and Residual Stresses

Mixed Ionic and Electronic Conductivity of Undoped and Acceptor-Doped Er[sub 6]WO[sub 12]

Reidar Haugsrud、Harald Fjeld、Kristoffer Robin Haug 等 4 位作者2006-12-04Journal of The Electrochemical Society

The ac conductivities of and 1% Ca-doped have been characterized as a function of oxygen and water vapor partial pressures in the temperature range 300– . Partial conductivities have been determined from the open-circuit voltage of , , and concentration cells. The materials exhibit n- and p-type electronic conductivit…

Advancements in Solid Oxide Fuel CellsGas Sensing Nanomaterials and SensorsElectronic and Structural Properties of Oxides

Fabrication and Characterization of Porous Anodic Alumina Films from Impure Aluminum Foils

Daniel Lo、R. Arief Budiman2006-12-04Journal of The Electrochemical Society

We report here on the fabrication of porous anodic alumina (PAA) films from commercially available impure aluminum foil. While the expensive ultrapure PAA films are restricted to potential applications in nanoelectrophotonics, the impure PAA films are more suitable for large-scale applications, such as in catalysis an…

Photonic Crystals and ApplicationsAnodic Oxide Films and NanostructuresSmart Materials for Construction

Fabrication of probe-typed carbon nanotube point emitters

Seung Il Jung、Jai Seong Choi、Hyung Cheoul Shim 等 6 位作者2006-12-04Applied Physics Letters

Probe-typed carbon nanotube (CNT) point emitter was fabricated by attaching single-walled CNT (SWCNT) and double-walled CNT (DWCNT) bundles onto the atomic force microscope tip using dielectrophoresis method. The field emission current from SWCNT point emitter was 4.9μA at 750V, which is corresponding to the emission…

Carbon Nanotubes in CompositesForce Microscopy Techniques and ApplicationsMechanical and Optical Resonators

Small changes in particle-size distribution dramatically delay and enhance nucleation in hard sphere colloidal suspensions

Hans Joachim Schöpe、Gary Bryant、W. van Megen2006-12-04Physical Review E

We present hard-sphere crystallization kinetics for three samples with small differences in polydispersity. We show that an increase in polydispersity of 1% is sufficient to cause dramatic changes in the crystallization kinetics: crystallization is delayed by almost one decade in time and quantitative and qualitative…

Phase Equilibria and ThermodynamicsMaterial Dynamics and Propertiesnanoparticles nucleation surface interactions

Realization of a high capacitance density in Bi2Mg2∕3Nb4∕3O7 pyrochlore thin films deposited directly on polymer substrates for embedded capacitor applications

Jong Hyun Park、Cheng-Ji Xian、Nak‐Jin Seong 等 13 位作者2006-12-04Applied Physics Letters

Bi 2 Mg 2 ∕ 3 Nb 4 ∕ 3 O 7 (BMN) thin films were deposited on copper clad laminate substrates at temperatures below 150°C for embedded capacitor applications by pulsed laser deposition. The BMN films deposited at temperatures below 150°C showed smooth surface morphologies having root mean square roughness of approxima…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisNuclear materials and radiation effects

Which Is Easier to Reduce, Cu[sub 2]O or CuO?

Shigeyoshi Nakayama、Tokiko Kaji、Masahiro Shibata 等 5 位作者2006-12-04Journal of The Electrochemical Society

Chronopotentiometry (CP) using 0.1 M KCl as the electrolyte has been most frequently used for selective determination of cuprous and cupric oxides ( Cu 2 O and CuO ) formed on copper surfaces. However, there are conflicting views regarding the order of reduction of the oxides. This study was carried out to settle this…

ZnO doping and propertiesCorrosion Behavior and InhibitionCopper-based nanomaterials and applications

Electrochemical Lithium Intercalation/Deintercalation of Single-Crystalline V[sub 2]O[sub 5] Nanowires

Xiaoxia Li、Weiyang Li、Hua Ma 等 4 位作者2006-12-04Journal of The Electrochemical Society

This paper reports on the electrochemical lithium intercalation/deintercalation of single-crystalline V 2 O 5 nanowires that were synthesized by a two-step approach including a hydrothermal process and a post-calcinating treatment. Techniques of X-ray diffraction, field-effect scanning electron microscopy, transmissio…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationTransition Metal Oxide Nanomaterials

Combinational template-assisted fabrication of hierarchically ordered nanowire arrays on substrates for device applications

Maria A. S. Chong、Yuebing Zheng、Han Gao 等 4 位作者2006-12-04Applied Physics Letters

By combining two self-organized templates, the authors fabricate hierarchically ordered nanowire arrays on substrates. The nanowire arrays consist of periodic voids at the microscale and hexagonally packed nanowires at the nanoscale. The nanowires are created by selective electrodeposition using nanoporous anodic alum…

Nanofabrication and Lithography TechniquesAnodic Oxide Films and NanostructuresNanoporous metals and alloys

Biochemical and Structural Characterization of the Secreted Chorismate Mutase (Rv1885c) from Mycobacterium tuberculosis H 37 R v : an *AroQ Enzyme Not Regulated by the Aromatic Amino Acids

Sook‐Kyung Kim、Sathyavelu K. Reddy、Bryant C. Nelson 等 10 位作者2006-12-04Journal of Bacteriology

The gene Rv1885c from the genome of Mycobacterium tuberculosis H37Rv encodes a monofunctional and secreted chorismate mutase (*MtCM) with a 33-amino-acid cleavable signal sequence; hence, it belongs to the *AroQ class of chorismate mutases. Consistent with the heterologously expressed *MtCM having periplasmic destinat…

Bacterial Genetics and BiotechnologyRNA and protein synthesis mechanismsEnzyme Structure and Function

Pitting Corrosion of Zn and Zn-Al Coated Steels in pH 2 to 12 NaCl Solutions

Wujian Miao、Ivan Cole、Aaron K. Neufeld 等 4 位作者2006-12-04Journal of The Electrochemical Society

Corrosion behavior of hard zinc, Al (Galfan), and Al alloy (Zincalume or Galvalume) coated steels was studied using cyclic voltammetry and potential scan/hold technique in the presence of 0.10- over a pH range of 2 to 12. Influence of chloride concentration and electrolyte pH on pitting potential values of the above t…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Mixed Conductivity and Oxygen Permeability of Doped Pr[sub 2]NiO[sub 4]-Based Oxides

Shogo Miyoshi、Tetsuro Furuno、Oravan Sangoanruang 等 5 位作者2006-12-04Journal of The Electrochemical Society

-based oxides were studied as a series of new mixed electronic and oxide-ionic conductors for oxygen permeation membrane. High electronic conductivity was observed for the system and the temperature dependence was of metal-like behavior, i.e., it decreased with elevating temperature. The oxygen permeability of -based…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

First principles calculations on martensitic transformation and phase instability of Ni–Mn–Ga high temperature shape memory alloys

Jie Chen、Yan Li、Jiaxiang Shang 等 4 位作者2006-12-04Applied Physics Letters

Martensitic transformation and phase instability of Ni8+xMn4Ga4−x high-temperature shape memory alloys have been investigated by first principles calculations using the pseudopotentials plane wave method. The tetragonality (the ratio between the lattice parameter c and a) increases with the increasing of Ni content. T…

Shape Memory Alloy TransformationsTitanium Alloys Microstructure and Properties

A Study of Anodization Process during Pore Formation in Nanoporous Alumina Templates

Z. Wu、Christiaan Richter、L. Menon2006-12-04Journal of The Electrochemical Society

We have carried out a systematic investigation of the anodization procedure in order to determine the exact chemical mechanism of the dissolution process responsible for pore formation in nanoporous alumina templates. We measured the anodization current as a function of time and compared it with the thickness of porou…

Concrete Corrosion and DurabilityAnodic Oxide Films and NanostructuresSmart Materials for Construction

Deep Silicon Macropores Filled with Copper by Electrodeposition

Cheng Fang、E. Foca、Su-Fan Xu 等 5 位作者2006-12-04Journal of The Electrochemical Society

Deep macropores in n-type Si have been completely filled with copper ͑Cu͒.Homogeneous metal deposition inside the deep pores was achieved by means of electroplating using a solution containing only Cu 2 SO 4 mixed with H 2 SO 4 and no additives.Initial nucleation of the Cu deposition was confined to the bottom of the…

Silicon Nanostructures and PhotoluminescenceNanowire Synthesis and ApplicationsSemiconductor materials and interfaces