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Micropatterning of Ferroelectric Bi 4Ti 3O 12 Using Electron-Beam-Induced Reaction of Metal Octylate Films

Soichiro Okamura、Y. Yagi、Shizutoshi Ando 等 5 位作者1996-12-01Japanese Journal of Applied Physics

Micropatterning of ferroelectric Bi 4 Ti 3 O 12 was carried out using an electron-beam-induced reaction of metal octylate films. Bismuth and titanium octylates were used as starting materials. Precursor solutions were prepared by mixing the octylates at a Bi:Ti molar ratio of 5.2:3.0 and diluting with acetone. The met…

Ferroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsMicrowave Dielectric Ceramics Synthesis

Effect of Pressure and Shear Stress on Crystallization Behaviors in Injection Molding

Hiroshi Itô、Keiji Minagawa、Jun‐ichi Takimoto 等 5 位作者1996-12-01International Polymer Processing

Abstract We studied in detail the effects of pressure and shear stress on the crystallization behaviors during injection molding process. Crystallization of isotactic-polypropylene (iPP) was simulated for various injection flow rates. The crystallization started during the filling stage under long filling condition. M…

Polymer crystallization and propertiesInjection Molding Process and PropertiesPolymer Foaming and Composites

Helicobacter pylorigeneshpcopAandhpcopPconstitute a cop operon involved in copper export

Zhongming Ge、Diane E. Taylor1996-12-01FEMS Microbiology Letters

We previously reported that a gene hpcopA isolated from Helicobacter pylori is associated with copper transport. In the present study, the DNA upstream of the hpcopA was cloned and the nucleotide sequence analyzed. An open reading frame coding for 124 amino acids was predicted, which was connected in frame to the hpco…

Helicobacter pylori-related gastroenterology studiesCorrosion Behavior and InhibitionTrace Elements in Health

Removal of Pinholes and Bubbles from Rotationally Moulded Products

A G Spence、R. J. Crawford1996-12-01Proceedings of the Institution of Mechanical Engineers Part B Journal of Engineering Manufacture

The rotational moulding processing method for plastics is steadily expanding its product range and market areas. However, a drawback of the process has always been the surface pinholes and internal bubbles which occur in the products due to the inherent nature of the process. In an attempt to alleviate this problem, a…

biodegradable polymer synthesis and propertiesPolymer Foaming and CompositesMaterial Properties and Processing

Physical Aspects of Dexibuprofen and Racemic Ibuprofen

G. Leising、Roland Resel、Franz Stelzer 等 6 位作者1996-12-01The Journal of Clinical Pharmacology

This article presents a comparative study of ibuprofen materials in their solid state. Ibuprofen crystallizes into two different structures for the S(+) enantiomer (dexibuprofen) and racemic ibuprofen. The crystal structure of ibuprofen, its optical absorption and photoluminescence, and the thermodynamic results (melt…

Crystallography and molecular interactionsAnalytical Chemistry and ChromatographyCrystallization and Solubility Studies

Vaporization of LaCrO 3 : Partial and Integral Thermodynamic Properties

Dong‐Huyn Peck、M. Miller、Dietmar Kobertz 等 5 位作者1996-12-01Journal of the American Ceramic Society

The vaporization of LaCrO 3 (s) and samples of the composition LaCrO 3 + La 2 O 3 was investigated in the temperature range of 1887‐2333 K by Knudsen effusion mass spectrometry using Knudsen cells made of tungsten lined completely with iridium. The species Cr(g), CrO(g ), CrO 2 (g), and LaO(g) were identified in the v…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Extrusion of polypropylene foams with hydrocerol and isopentane

Amir Hossein Behravesh、Chul B. Park、Lewis K. Cheung 等 4 位作者1996-12-01Journal of Vinyl and Additive Technology

Abstract An experimental investigation was conducted to research the cell nucleation behavior in the extrusion foam processing of polypropylene (PP) using hydrocerol and isopentane. While the hydrocerol and isopentane are considered to function as the nucleating agent which determines the cell‐population density and a…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesPolymer Foaming and Composites

Monoclinic Spin Hamiltonian Analysis of EPR Spectra of Mn2+ in BiVO4 Single Crystals

Tae Ho Yeom、Czesław Rudowicz、Sung Ho Choh 等 4 位作者1996-12-01physica status solidi (b)

Abstract X‐band EPR spectra of Mn 2+ in ferroelastic BiVO 4 single crystals at room temperature taken in three orthogonal planes are analyzed using a twestage least‐squares fitting procedure. The absence of site splitting from the spectra shows unequivocally that Mn 2+ lies on a site with two‐fold rotation symmetry, w…

Perovskite Materials and ApplicationsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Transformation and Densification of Nanocrystalline θ‐Alumina during Sinter Forging

Christopher S. Nordahl、Gary L. Messing1996-12-01Journal of the American Ceramic Society

The sinter forging behavior of α‐Al 2 O 3 seeded and unseeded nanocrystalline θ‐Al 2 O 3 was investigated as a function of temperature, stress, and strain rate. Seeded samples exhibited the highest degree of plastic deformation during the θ‐ to α‐AI 2 O 3 phase transformation. As a result, microstructure control, incr…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesPowder Metallurgy Techniques and Materials

Arch-texture in cholesteric liquid crystals

Jean Baudry、M. Brazovskaia、L. Lejček 等 5 位作者1996-12-01Liquid Crystals

We have observed an arch-texture in cholesteric liquid crystals sandwiched between two glass plates making a small wedge angle. The anchoring is homeotropic on one plate and planar on the opposite one. This texture is locally periodic and composed of parallel stripes whose average direction rotates by 180° each time t…

Liquid Crystal Research Advancements

Degumming of silk with different protease enzymes

M L Gulrajani、Shailja Vaidya Gupta、Abhilasha Gupta 等 4 位作者1996-12-01OpenAlex

Silk was degummed with eight different commercially available enzymes, viz. Degummase lOOOL, Protosol, Trypsin, AIcalase, Protease A, Protease N, Pepsin and Protease M. The degumming conditions with respect to concentration and time were optimised for each enzyme. Enzyme activity, an important intrinsic property, and…

Dyeing and Modifying Textile FibersSilk-based biomaterials and applicationsSilkworms and Sericulture Research

p‐Toluenesulfonyl esters in cellulose modifications: acylation of remaining hydroxyl groups

Thomas Heinze、Kerstin Rahn、M. E. A. P. Jaspers 等 4 位作者1996-12-01Macromolecular Chemistry and Physics

Abstract New soluble cellulosics with interesting molecular structures and properties were obtained by the acylation of remaining hydroxyl groups of pure, homogeneously synthesized p ‐toluenesulfonylcelluloses of different degree of p ‐toluenesulfonyl (tosyl) substitution (DS Tosyl ) ranging from 0.5 to 2.0 in pyridin…

Biofuel production and bioconversionAdvanced Cellulose Research StudiesLignin and Wood Chemistry

Distribution of cation exchange capacity between organic matter and mineral fractions in acid forest soils (Vosges mountains, France)

M.-P. Turpault、Pascal Bonnaud、J. FIGHTER 等 5 位作者1996-12-01European Journal of Soil Science

Summary The cation exchange capacity (CEC) of 18 samples (<2 mm) of five acid soils developed on granite or gneiss was measured before and after H 2 O 2 treatment from pH‐unbuffered extraction solution (1 N KCl). The pH in water of the soils ranged from 3.4–4.7. The samples were separated into seven fractions (<…

Soil and Unsaturated FlowClay minerals and soil interactionsMine drainage and remediation techniques

Particle‐Inhibited Grain Growth in Al 2 O 3 ‐SiC: II, Equilibrium and Kinetic Analyses

Laura C. Stearns、Martin P. Harmer1996-12-01Journal of the American Ceramic Society

The grain‐growth data presented in a companion paper for the Al 2 O 3 ‐SiC system are analyzed. Central to the analysis is the experimentally observed relationship between the fraction of particles on grain boundaries, φ, and the average grain size, G. This relationship is included in both the equilibrium‐grain‐size e…

Advanced ceramic materials synthesisAluminum Alloy Microstructure PropertiesAluminum Alloys Composites Properties

Adsorption of Cd and Zn on montmorillonite in the presence of a cationic pesticide

T. Undabeytia、E. Morillo、Celia Maqueda1996-12-01Clay Minerals

Abstract The adsorption of Cd and Zn on a standard montmorillonite (SAZ-1) in the presence of the cationic pesticide chlordimeform, both in solution (simultaneous adsorption) and when the pesticide is previously adsorbed on the clay (successive adsorption) has been studied. The adsorption of Zn decreases when the chlo…

Heavy metals in environmentClay minerals and soil interactionsMine drainage and remediation techniques

Macromolecular Crystal Growth in Microgravity

Alexander McPherson1996-12-01Crystallography Reviews

Evidence from a variety of space experiments confirms that gravity does, in some cases, have a significant effect on the crystallization of macromolecules. This has been demonstrated by numerous investigators employing a wide range of instruments and proteins. In the absence of gravity, convective transport of solute…

Photosynthetic Processes and MechanismsEnzyme Structure and FunctionProtein Interaction Studies and Fluorescence Analysis

Crystal Structure Modeling of a Highly Disordered Potassium Birnessite

Kerry L. Holland、J.R. Walker1996-12-01Clays and Clay Minerals

Abstract The structure of a highly disordered synthetic birnessite was studied by comparing powder X-ray diffraction (XRD) data with calculated patterns generated by BIRNDIF and WILDFIRE© in an attempt to describe the nature of disorder and to estimate the size of the coherent diffracting domains. The material has a t…

Crystal Structures and PropertiesAdvanced Condensed Matter PhysicsX-ray Diffraction in Crystallography

Structure and dynamics of primary hydration shell of phosphatidylcholine bilayers at subzero temperatures

Chen-Hsi Hsieh、Wenzhi Wu1996-12-01Biophysical Journal

Deuterium NMR relaxation and intensity measurements of the 2H-labeled H2O/dimyristoyl phosphatidylcholine bilayer were performed to understand the molecular origin of the freezing event of phospholipid headgroup and the structure and dynamics of unfrozen water molecules in the interbilayer space at subzero temperature…

Lipid Membrane Structure and BehaviorMaterial Dynamics and PropertiesSpectroscopy and Quantum Chemical Studies

X‐ray Photoelectron Spectroscopy Investigation on the Low‐Temperature Degradation of 2 mol% Y 2 O 3 ‐ZrO 2 Ceramics

Jing‐Feng Li、Ryuzo Watanabe、Bo‐Ping Zhang 等 5 位作者1996-12-01Journal of the American Ceramic Society

2 mol% Y 2 O 3 ‐ZrO 2 polycrystals were annealed in water and under vacuum to highlight the effect of the presence of H 2 O on the low‐temperature degradation transformation. The specimen surfaces with monoclinic phases transformed during annealing in the different environments were analyzed by X‐ray photoelectron spe…

Advanced ceramic materials synthesisAdvanced materials and compositesNuclear materials and radiation effects

Composite polyaniline/calixarene Langmuir - Blodgett films for gas sensing

Nickolay V. Lavrik、Danilo De Rossi、Z.I. Kazantseva 等 9 位作者1996-12-01Nanotechnology

Mixtures of the polyaniline (emeraldine base) and phosphorylated calix[4]resorcinolarene derivative (CA) are proposed to prepare LB films for conductometric gas sensors. They are quite stable at the air - water interface and give LB films of high quality. The average thickness of the mixed monolayers is found to be 1.…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors