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Preparation of Low-Density Macrocellular Tin Dioxide Foam with Variable Window Size

Qincui Gu、Keiji Nagai、T. Norimatsu 等 8 位作者2005-02-08Chemistry of Materials

Low-density porous tin dioxide (∼0.5 g/cm 3 ) was prepared from a SnCl 4 /ethanol/H 2 O mixture and polystyrene (PS) template. Such a low density made the as-synthesized tin dioxide act as a promising target material for laser-induced extreme ultraviolet (EUV) emission. The resulting structure of the as-synthesized ti…

Catalytic Processes in Materials ScienceTransition Metal Oxide NanomaterialsAerogels and thermal insulation

Molecular Containers Based on Amphiphilic PS-b-PMVE Dendrigraft Copolymers: Topology, Organization, and Aqueous Solution Properties

Michel Schappacher、Jean‐Luc Putaux、Christelle Lefebvre 等 4 位作者2005-02-08Journal of the American Chemical Society

The synthesis, characteristics, and properties of amphipatic, water-soluble dendrigrafts, with a polystyrene core and polystyrene-b-poly(methyl vinyl ether) (PS-b-PMVE) diblock as external branches, are described. The dendrigrafts are observed by AFM and TEM as egglike or long cylindrical objects which can self-organi…

Advanced Polymer Synthesis and CharacterizationPorphyrin and Phthalocyanine ChemistryDendrimers and Hyperbranched Polymers

Polarization holograms in azo dye-doped polymer dissolved liquid crystal composites

Hiroshi Ono、Fumihiro Takahashi、Akira Emoto 等 4 位作者2005-02-08Journal of Applied Physics

We have investigated holographic recordings in azobenzene-containing amorphous polymers (AP) and polymer-dissolved liquid-crystalline composites (PDLCC) with two waves that have orthogonal linear polarizations. Only linear photobirefringence was induced in AP, while both linear and circular photobirefringences were in…

Liquid Crystal Research AdvancementsPhotorefractive and Nonlinear OpticsAdvanced Optical Imaging Technologies

New light‐colored poly(ether imide)s based on 2,5‐di‐tert‐butylhydroquinone bis(ether anhydride) and aromatic diamines

Chin‐Ping Yang、Mei‐Yuan Hsu2005-02-08Journal of Polymer Science Part A Polymer Chemistry

Abstract A series of poly(ether imide)s (PEIs), III a–k , with light color and good physical properties were prepared from 1,4‐bis(3,4‐dicarboxypheoxy)‐2,5‐di‐ tert ‐butylbenzene dianhydride ( I ) with various aromatic diamines ( II a–k ) via a conventional two‐stage procedure that included a ring‐opening polyaddition…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersSilicone and Siloxane Chemistry

The Explanation of the Increase in Slope at the Tg in the Plot of d‐Spacing Versus Temperature in Polyacrylonitrile

Z. Bashir、Sanjay Rastogi2005-02-08Journal of Macromolecular Science Part B

Oriented fibers of atactic Polyacrylonitrile (PAN) show a diffraction pattern consisting of just two equatorial peaks. The plot of d‐spacing vs. temperature shows a linear increase up to about 85–100°C, followed by another linear region with augmented slope. This increase in slope occurs at a temperature that coincide…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesPolymer Nanocomposites and Properties

Stable poly(methyl methacrylate‐co‐divinylbenzene) microspheres via precipitation polymerization

Sunhye Yang、Sang Eun Shim、Soonja Choe2005-02-08Journal of Polymer Science Part A Polymer Chemistry

Stable poly(MMA-co-DVB) microspheres were prepared by precipitation polymerization using acetonitrile as the main medium under various polymerization conditions including monomer and initiator concentrations.

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesSynthesis and properties of polymers

Magnetic anomalies and canting effects in nanocrystalline spinel copper ferrites CuxFe3−xO4

S. J. Stewart、R. C. Mercader、R. E. Vandenberghe 等 5 位作者2005-02-08Journal of Applied Physics

The magnetic behavior of nanocrystalline copper spinel ferrites CuxFe3−xO4 (0.42⩽x⩽1) exhibiting different degrees of crystallinity, have been investigated by means of in-field Mössbauer and dc magnetic measurements. The samples were obtained by a coprecipitation method and were subsequently high-energy ball milled fo…

Magnetic properties of thin filmsMagnetic Properties and Synthesis of FerritesMagneto-Optical Properties and Applications

Strong correlation effects of the Re5delectrons on the metal-insulator transition inCa2FeReO6

Hideaki Iwasawa、T. Saitoh、Y. Yamashita 等 8 位作者2005-02-08Physical Review B

We have investigated the electronic structure of polycrystalline ${\mathrm{Ca}}_{2}\mathrm{Fe}\mathrm{Re}{\mathrm{O}}_{6}$ using photoemission spectroscopy and band-structure calculations within the local-density $\text{approximation}+U$ $(\mathrm{LDA}+U)$ scheme. In valence-band photoemission spectra, a double-peak s…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Organic−Inorganic Poly(Methyl Methacrylate) Hybrids with Confined Polyhedral Oligosilsesquioxane Macromonomers

Oliver Toepfer、Daniel Neumann、Namita Roy Choudhury 等 5 位作者2005-02-08Chemistry of Materials

We herein report the synthesis of organic−inorganic hybrid poly(methyl methacrylate) containing polyhedral oligosilsesquioxanes. Octakis(3-hydroxypropyldimethylsiloxy)octasilsesquioxane (OHPS) was synthesized from octakis(hydridodimethylsiloxy)octasilsesquioxane [Si 8 O 12 (OSiMe 2 H) 8, Q 8 M 8 H ] following literatu…

Advanced ceramic materials synthesisSynthesis and properties of polymersSilicone and Siloxane Chemistry

A comparison of relaxation processes in structurally related van der Waals glass formers: The role of internal degrees of freedom

S. Kahle、Jacek Gapiński、G. Hinze 等 5 位作者2005-02-08The Journal of Chemical Physics

Depolarized dynamic light scattering (DLS), dielectric relaxation (DS), and deuterium NMR studies of fragile van der Waals glass forming liquids phenylphthalein-dimethylether (PDE) and cresolphthalein-dimethylether (KDE) are presented. In PDE a new dielectric loss process was found, which can be attributed to the 180…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesThermodynamic properties of mixtures

Selective removal of tannins from medicinal plant extracts using a collagen fiber adsorbent

Xuepin Liao、Bi Shi2005-02-08Journal of the Science of Food and Agriculture

Abstract A novel adsorbent, used for the selective removal of tannins from medicinal plant extracts, was prepared from bovine skin collagen fiber. Some typical active constituents of medicinal plants were selected as probe molecules to investigate the adsorption selectivity of the collagen fiber adsorbent to tannins.…

Phytochemicals and Antioxidant Activitiesbiodegradable polymer synthesis and propertiesCollagen: Extraction and Characterization

Grafting of Amino Functional Monomer onto Initiator-Modified Polystyrene Particles

Anna Musyanovych、Hans‐Jürgen P. Adler2005-02-08Langmuir

Polystyrene nanoparticles with grafted chains of an amino functionalized polymer were prepared by a two-step polymerization process. In the first step, the polystyrene seed particles were synthesized by the conventional batch emulsion polymerization using terpolymer HAS (hydroperoxide monomer, acrylic acid, and styren…

biodegradable polymer synthesis and propertiesPolymer Surface Interaction StudiesProtein purification and stability

Thermal lens study of the OH− influence on the fluorescence efficiency of Yb3+-doped phosphate glasses

Carlos Jacinto、Samuel L. Oliveira、L.A.O. Nunes 等 5 位作者2005-02-08Applied Physics Letters

In this work, the thermal lens (TL) technique is used to determine the fluorescence quantum efficiency (η) of Yb3+-doped phosphate glasses. The role of nonradiative processes such as energy migration among Yb ions and the interaction with OH− radicals are presented and discussed. Two sets of samples with the same Yb c…

Glass properties and applicationsPhotorefractive and Nonlinear OpticsSolid State Laser Technologies

Structure control of CdS nanobelts and their luminescence properties

Chunrui Wang、K. M. Ip、S. K. Hark 等 4 位作者2005-02-08Journal of Applied Physics

Single crystalline CdS (hexagonal) nanobelts have been synthesized using thermal evaporation at temperatures ranging from 1000to1200°C. These nanobelts universally grow along the [120] crystalline direction. The nanobelts fabricated at 1000°C appear to be much more uniform than those at 1200°C. Moreover, the surface o…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Magnetoresistance in Ag2+δSe with high silver excess

Marc Kreutzbruck、Boris Mogwitz、Friederike J. Gruhl 等 6 位作者2005-02-08Applied Physics Letters

In the present study, we investigated the galvanomagnetic transport properties of polycrystalline AgxSe thin films with silver excess in the range from x=1.5 to 18. The results prove that the silver excess controls the transition from linear magnetoresistance (MR) behavior to the quadratic ordinary MR and the temperat…

Quantum and electron transport phenomenaAdvanced Thermoelectric Materials and DevicesMagnetic and transport properties of perovskites and related materials

Porosity Control of LSM/YSZ Cathode Coating Deposited by Electrospraying

A. Princivalle、D. Perednis、Roberto Neagu 等 4 位作者2005-02-08Chemistry of Materials

The deposition of a composite electrode, which consisted of a mixture of a solid electrolyte (YSZ) and an electrocatalytic material (LSM), on an YSZ substrate was studied using the electrostatic spray deposition (ESD) technique. Films with various morphologies were obtained. The surface morphology was strongly influen…

Catalytic Processes in Materials ScienceAdvancements in Solid Oxide Fuel CellsGas Sensing Nanomaterials and Sensors

Isovalent Doping Strategy for Manganese Introduction into III-V Diluted Magnetic Semiconductor Nanoparticles: InP:Mn

Kanchana Somaskandan、G. M. Tsoĭ、L. E. Wenger 等 4 位作者2005-02-08Chemistry of Materials

III−V based diluted magnetic semiconductor (DMS) nanoparticles of In (1 - x ) Mn x P ( x ≤ 0.0135) have been prepared by slow heating of the reagents in trioctylphosphine oxide (TOPO) or by high-temperature injection of reagents dissolved in trioctylphosphine (TOP) into hot TOPO. The materials were prepared using eith…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

In Situ Study of the Thermoresponsive Behavior of Micropatterned Hydrogel Films by Imaging Ellipsometry

Dirk Schmaljohann、Mirko Nitschke、R. Schulze 等 6 位作者2005-02-08Langmuir

A patterned hydrogel was immobilized on a polymer substrate by low-pressure argon plasma treatment using a masking technique. The polymer sample showed a thermoresponsive aggregation behavior in the region of 35-37 degrees C. The micropatterned, thermoresponsive hydrogel film has been characterized with imaging ellips…

Liquid Crystal Research AdvancementsHydrogels: synthesis, properties, applicationsSurfactants and Colloidal Systems

Stable Nonspherical Fluorine-Containing Colloidal Dispersions: Synthesis and Film Formation

W Dreher、William L. Jarrett、Marek W. Urban2005-02-08Macromolecules

A simple synthetic method for preparing stable colloidal dispersions that form polymeric films containing fluorinated acrylates is presented. The simultaneous presence of the dual tail anionic fluorosurfactant phosphoric acid bis(tridecafluorooctyl) ester ammonium salt (FSP) and sodium dodecyl sulfate (SDS) surfactant…

Surface Modification and SuperhydrophobicityAdvanced Polymer Synthesis and CharacterizationPolymer Surface Interaction Studies

Phase Behavior and Photooptical Properties of Liquid Crystalline Functionalized Copolymers with Low-Molecular-Mass Dopants Stabilized by Hydrogen Bonds

А. В. Медведев、Evgeny Barmatov、A. S. Medvedev 等 7 位作者2005-02-08Macromolecules

The approach of deriving new photooptically active polymeric substances by hydrogen bonding between functionalized liquid crystalline (LC) copolymers and low-molecular-mass dopants, containing photochromic azobenzene fragments, is described. The formation of intermolecular hydrogen bonds between carboxylic groups of f…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsPhotochromic and Fluorescence Chemistry