Materials Literature
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The multiple solvent crystal structures (MSCS) method uses organic solvents to map the surfaces of proteins. It identifies binding sites and allows for a more thorough examination of protein plasticity and hydration than could be achieved by a single structure. The crystal structures of bovine pancreatic ribonuclease…
Experimental evidence of left-handed transmission is demonstrated through an array of ferromagnetic microwires. We used amorphous magnetic microwires to take advantage of both electric and magnetic responses locally generating a double negative medium at microwave frequencies, where the ferromagnetic resonance effects…
Subtle change: Spatiotemporal modulation of individual protein subdomains with light as the trigger signal becomes possible by using bivalent aptamers and introducing photolabile "caging groups" to switch individual aptamer modules ON or OFF differentially. To the best of our knowledge, this is the first study to show…
In this paper, the electromagnetic (EM) tunneling phenomenon in a sandwich structure consisting of an mu-negative (MNG) medium, air, and an epsilon-negative (ENG) medium is investigated by means of the transfer-matrix method and microwave experiments. Both results demonstrate that by properly choosing parameters, EM w…
Complex ac susceptibility measurements are reported on composite Au–Fe3O4 nanoparticles of two different configurations—the so-called “dumbbell” and “flower” configurations. The frequency-dependent blocking temperature was fitted to two separate models in an attempt to understand the relaxation and the role of interac…
Abstract A simple catalysis‐free approach that utilises a gas–solid reaction for the synthesis of large‐scale single‐crystalline PrB 6 nanorods using Pr and BCl 3 as starting materials is demonstrated. The nanorods exhibit a low turn‐on electric field (2.80 V µ‐b;m −1 at 10 µ‐b;A cm −2 ), a low threshold electric fiel…
The intermediate voltage electron microscope-tandem user facility in the Electron Microscopy Center at Argonne National Laboratory is described. The primary purpose of this facility is electron microscopy with in situ ion irradiation at controlled sample temperatures. To illustrate its capabilities and advantages a fe…
Cupriavidus sp. USMAA1020, a local isolate was able to biosynthesis poly(3-hydroxybutyrate-co-4-hydroxybutyrate) [P(3HB-co-4HB)] copolymer with various 4HB precursors as the sole carbon source. Manipulation of the culture conditions such as cell concentration, phosphate ratio and culture aeration significantly affecte…
Complex spatiotemporal structures develop during the process of aging glasses after cooling and of rejuvenating glasses on heating. The key to understanding these structures is the interplay between the activated reconfiguration events that generate mobility and the transport of mobility. These effects are both accoun…
POM alert: The incorporation of an amide oxygen atom into the framework of the Dawson-type polyoxometalate (POM) cluster [P(2)V(3)W(15)O(62)](9-) (see picture) allows the communication of electronic effects between the organic and the inorganic parts of the molecule, including fine-tuning of the redox properties of th…
A highly nanoporous material has been obtained by self-assembly of calixarene and porphyrin building blocks. This supramolecular zeolite-like structure was successively functionalized by diffusion and coordination of metal ions to form a new bifunctionalized nanoporous material containing a porphyrinic pigment togethe…
Spin correlations in ${\mathrm{La}}_{2\ensuremath{-}x}{\mathrm{Sr}}_{x}{\mathrm{CoO}}_{4}$ ($0.3\ensuremath{\le}x\ensuremath{\le}0.6$) have been studied by neutron scattering. The commensurate antiferromagnetic order of ${\mathrm{La}}_{2}{\mathrm{CoO}}_{4}$ persists in a very short range up to a Sr content of $x=0.3$,…
Abstract Society has been reaping the benefits of industrial polymers for a long time. Polymers have entered every market in a very influential manner, from the packaging industry to the construction business. The very properties that made polymers commercially viable are posing great environmental problems for our fu…
The levels of retention in codeposited layers of each of the three ITER materials (C, Be and W) are compared. Scaling laws, based on the conditions during the codeposition process (surface temperature, incident particle energy and ratio of the depositing fluxes), are presented to allow prediction of expected retention…
Characteristic formation of highly oriented indium-tin-oxide (ITO) nanocolumns is demonstrated using electron-beam evaporation with an obliquely incident nitrogen flux. The nanocolumn material exhibits broadband and omnidirectional antireflective characteristics up to an incidence angle of 70° for the 350–900 nm wavel…
Kevlar–nanotube composite fibers of high strength and toughness are demonstrated. Commercially available Kevlar fibers are soaked in a suspension of nanotubes in the solvent N-methylpyrrolidone, resulting in swelling of the fibers, and allowing the nanotubes to diffuse into the interior of the fiber (see image). The r…
A recombinant silk-elastin-like protein copolymer SELP-47K containing tandemly repeated amino acid sequence blocks from silk, GAGAGS, and elastin, GVGVP, was fabricated into microdiameter fibers using a wet-spinning technique. Raman spectral analysis revealed the formation of antiparallel beta-sheet crystals of the si…
A new approach to the fabrication of magnetic thermosensitive microcontainers of Fe(3)O(4) nanoparticles with poly(N-isopropylacrylamide) walls is presented. The microcontainers undergo a temperature-induced volume phase transition and present an impressive magnetic response. The microcontainers have a well-defined st…
The geometric and electronic structures of NaN, CuN, and AgN metal clusters are systematically studied based on the density functional theory over a wide range of cluster sizes 2=
This work examines the critical anisotropy required for the local stability of the collinear ground states of a geometrically-frustrated triangular-lattice antiferromagnet (TLA). Using a Holstein-Primakoff expansion, we calculate the spin-wave frequencies for the 1, 2, 3, 4, and 8-sublattice (SL) ground states of a TL…