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Plasma etching of CVD diamond films using an ECR-type oxygen source

Shuji Kiyohara、Y. Yagi、Katsumi Mori1999-12-01Nanotechnology

The etching characteristics of CVD (chemical vapour deposition) diamond films processed with an ECR (electron cyclotron resonance) oxygen plasma are investigated. The etching rate increases linearly with increasing microwave power in the range from 100 to 300 W. For any value of microwave power, the etching rate first…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchForce Microscopy Techniques and Applications

Optical Properties of Bismuth Telluride Thin Films, Bi2Te3/Si(100) and Bi2Te3/SiO2/Si(100)

El. H. Kaddouri、T. Maurice、X. Gratens 等 8 位作者1999-12-01physica status solidi (a)

In this work, we have studied bismuth telluride (Bi2Te3) thin films on Si(100) and SiO2/Si(100) substrates grown by Hot Wall Epitaxy (HWE) technique. The morphology of the surface was controlled by Atomic Force Microscopy (AFM). Reflection and transmission experiments in the mid-infrared (MIR) spectral range were perf…

Advanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin FilmsAdvanced Semiconductor Detectors and Materials

Surface Phonons, Electronic Structure and Chemical Reactivity of Diamond (100)(2 ×1) Surface

Md. Zakir Hossain、Toshitaka Kubo、Tetsuya Aruga 等 7 位作者1999-12-01Japanese Journal of Applied Physics

Surface phonons, electronic structure and chemical reactivity of the diamond (100)(2 ×1) surface have been studied using electron energy loss spectroscopy (EELS), thermal desorption spectroscopy (TDS) and low-energy electron diffraction (LEED). Vibrational losses are observed at ∼80, 92, 123, 135, 147 and 165 meV for…

Diamond and Carbon-based Materials ResearchElectronic and Structural Properties of OxidesAdvanced Materials Characterization Techniques

New Approach to Strain Rate Sensitivity of Concrete in Compression

S. Zheng、U. Häussler-Combe、J. Eibl1999-12-01Journal of Engineering Mechanics

A constitutive law to model the strain-rate-dependent compression behavior of concrete is proposed. It is derived from a mechanical model, where inertia effects influence damage formation. To verify this model an experimental method based on the split Hopkinson bar (SHB) technique is described, one that considers the…

Energetic Materials and CombustionHigh-Velocity Impact and Material BehaviorStructural Response to Dynamic Loads

Order–disorder phenomena determined by high-resolution powder diffraction: the structures of tetrakis(trimethylsilyl)methane C[Si(CH3)3]4 and tetrakis(trimethylsilyl)silane Si[Si(CH3)3]4

Robert E. Dinnebier、W. A. Dollase、Xavier Helluy 等 9 位作者1999-12-01Acta Crystallographica Section B Structural Science

The compounds tetrakis(trimethylsilyl)methane C[Si(CH(3))(3)](4) (TC) and tetrakis(trimethylsilyl)silane Si[Si(CH(3))(3)](4) (TSi) have crystal structures with the molecules in a cubic closed-packed (c.c.p.) stacking. At room temperature both structures have space group Fm{\bar 3}m (Z = 4) with a = 13.5218 (1) Å, V =…

Crystallography and molecular interactionsCrystal Structures and PropertiesX-ray Diffraction in Crystallography

Electrochemical behavior of a new electroactive polyimide derived from aniline trimer

Wen Lu、Xian Sheng Meng、Zhi Yuan Wang1999-12-01Journal of Polymer Science Part A Polymer Chemistry

The electrochemical behavior of a soluble polyimide (Tani-polyimide) derived from an aniline trimer was investigated. Similar to processes observed in polyaniline, two typical redox processes involving protonation and ion insertion were observed. Due to the presence of an isolated, short quinonediimine or N,N′-dipheny…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsAnalytical Chemistry and Sensors

Structure of Monodisperse and Bimodal Brushes

E. P. K. Currie、Marnix Wagemaker、M.A. Cohen Stuart 等 4 位作者1999-12-01Macromolecules

The structure of monodisperse and bimodal brushes consisting of poly(ethylene oxide) (PEO) at the air/water interface is investigated with neutron reflectivity, and the results are compared with the structure predicted by the Scheutjens−Fleer self-consistent-field lattice model. The monomer density profile of a monodi…

Surfactants and Colloidal SystemsPolymer Surface Interaction StudiesPickering emulsions and particle stabilization

Influence of interchange reactions on the crystallization and melting behavior of nylon 6,6 blended with other nylons

Parvinder Walia、Rakesh Kumar Gupta、Chang T. Kiang1999-12-01Polymer Engineering and Science

Abstract The thermal behavior of blends of nylon 6,6, with an amorphous polyamide, Trogamid‐T, and a semicrystalline polyamide, nylon 6,12, was studied. The blends were prepared both by solution blending and by melt blending, using a Maxwell extruder and a twin screw extruder. The concentration of the blends ranged fr…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Light emitting porous silicon diode based on a silicon/porous silicon heterojunction

Lorenzo Pavesi、Rosa Chierchia、P. Bellutti 等 15 位作者1999-12-01Journal of Applied Physics

A new structure is proposed to improve the external quantum efficiency of porous silicon (PS) light emitting diodes (LED). It is based on a heterojunction between n-type doped silicon and PS. The heterojunction is formed due to the doping selectivity of the etching process used to form PS. The improvement of the propo…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Linear augmented-plane-wave frozen-phonon calculation, shell-model lattice dynamics, and specific-heat measurement of SnO

S. Koval、R. Burriel、M. G. Stachiotti 等 8 位作者1999-12-01Physical review. B, Condensed matter

An ab initio linear augmented-plane-wave (LAPW) calculation of the zone-center phonon frequencies of SnO has been performed. ${E}_{g}$ symmetry has been ascribed to the mode observed at $113 {\mathrm{cm}}^{\ensuremath{-}1}$ in Raman measurements, discarding a previous ${B}_{1g}$ assignment. The other phonon modes meas…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsSolid-state spectroscopy and crystallography

Influence of Chemical Reactions in Magnesia‐Graphite Refractories: II, Effects of Aluminum and Graphite Contents in Generic Products

Carmen Baudı́n、Carlos Alvarez、Robert E. Moore1999-12-01Journal of the American Ceramic Society

A group of magnesia‐graphite and magnesia‐graphite‐aluminum materials, the compositions of which represent a wide range of graphite contents (~10‐16.4 wt%), aluminum contents (0‐5.2 wt%), and MgO and graphite qualities, were fabricated, using standard commercial practices. Chemical analysis and determination of room‐t…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesFiber-reinforced polymer composites

Static tester for characterization of phase-change, dye–polymer, and magneto-optical media for optical data storage

Masud Mansuripur、J. Kevin Erwin、Warren Bletscher 等 8 位作者1999-12-01Applied Optics

We have designed and built a static tester around a commercially available polarized light microscope. This device employs two semiconductor laser diodes (at 643- and 680-nm wavelengths) for the purpose of recording small marks on various media for optical data storage and for the simultaneous monitoring of the record…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsPhase-change materials and chalcogenides

α- und β-BaCu2X2 (X ≙ S, Se) - Darstellung von Einkristallen in Kaliumchalkogenocyanat-Schmelzen

J. Huster、W. Bronger1999-12-01Zeitschrift für anorganische und allgemeine Chemie

α- und β-BaCu2S2, wie auch die entsprechenden isotypen Selenide, wurden bei 480 °C in einer Kaliumthio- beziehungsweise Kaliumselenocyanatschmelze als Kristalle erhalten. Die Darstellung des goldgelben α-BaCu2S2 war bisher in reiner Form nicht gelungen [1]. Einkristallstrukturuntersuchungen von allen vier Substanzen b…

Crystal Structures and PropertiesIron-based superconductors researchNanocluster Synthesis and Applications

Transmission electron microscopy of the vertical crystal layer and cuticle of the eggshell of the domestic fowl

A. C. Fraser、Maureen Bain、S. E. Solomon1999-12-01British Poultry Science

1. Eggshell pieces (1 cm2) were decalcified using a solution of EDTA (200 g/litre, pH 6.9 to 7.0) in paraformaldehyde (2 g/litre) and glutaraldehyde (0.5 g/litre) in phosphate buffer. 2. They were prepared for transmission electron microscopy (TEM). 3. TEM identified a vertically aligned matrix associated with the ver…

Animal Nutrition and PhysiologyMeat and Animal Product QualityCalcium Carbonate Crystallization and Inhibition

Synthesis, Spectroscopy, Electrochemistry, and Mesomorphism of Triple-Decker Porphyrins Consisting of Two Cerium Ions and Three 5,15-Diarylporphyrins

Hideya Miwa、Nagao Kobayashi、Kazue Ban 等 4 位作者1999-12-01Bulletin of the Chemical Society of Japan

Abstract Triple-decker sandwich complexes, which consist of two cerium ions and three strip-like diarylporphyrins, have been synthesized and their spectroscopic and electrochemical properties and mesomorphism are reported and compared with those of the corresponding double deckers and the parent monomers. The Soret ba…

Molecular Sensors and Ion DetectionSupramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine Chemistry

Removal of silver from photographic wastewater effluent using Acinetobacter baumannii BL54

Mohammad Reza Shakibaie、Balu P. Kapadnis、Pershant Dhakephalker 等 4 位作者1999-12-01Canadian Journal of Microbiology

Acinetobacter baumannii BL54, a silver (Ag) resistant micro-organism was isolated from clinical samples collected at the Armed Forces Medical College hospital in Pune, India. The strain BL54 removed a high quantity of silver (2.85 mg/g biomass) from photographic wastewater effluent. Treatment of the cells with 10 mM E…

Nanoparticles: synthesis and applicationsPharmaceutical and Antibiotic Environmental ImpactsChromium effects and bioremediation

Glyphosate-Hydrotalcite Interaction as Influenced by pH

María J. Sánchez‐Martín、M. Villa、M. Sánchez‐Camazano1999-12-01Clays and Clay Minerals

Abstract Adsorption and the mechanism of adsorption of the herbicide glyphosate [N-(phosphonomethyl) glycine] by hydrotalcite (HT) and by hydrotalcite calcined at 500°C (HT500) was studied. The values of the Freundlich K constant of the adsorption isotherms and the distribution coefficients, Kd, depend on the pH of th…

Clay minerals and soil interactionsIron oxide chemistry and applicationsLayered Double Hydroxides Synthesis and Applications

Thermal expansion in the orthorhombic γ phase ofZrW2O8

John S. O. Evans、J. D. Jorgensen、S. Short 等 6 位作者1999-12-01Physical review. B, Condensed matter

The thermal expansion of the orthorhombic \ensuremath{\gamma} phase of ${\mathrm{ZrW}}_{2}{\mathrm{O}}_{8}$ has been measured using neutron powder diffraction from 4.6 to 410 K, where it transforms to the cubic \ensuremath{\alpha} phase. At low temperature, $\ensuremath{\gamma}{\ensuremath{-}\mathrm{Z}\mathrm{r}\mathr…

Ferroelectric and Piezoelectric MaterialsAdvanced Battery Materials and TechnologiesThermal Expansion and Ionic Conductivity

Analysis of the scanning electron microscope mirror method for studying space charge in insulators

H. J. Wintle1999-12-01Journal of Applied Physics

We give a detailed analysis of the scanning electron microscope mirror method for studying a cloud of charge stored near the surface of an insulator, paying particular attention to the approximations that are often made. We discuss the effect of the finite size of the experimental chamber, of the thickness of the samp…

Semiconductor materials and devicesHigh voltage insulation and dielectric phenomenaElectron and X-Ray Spectroscopy Techniques

Synthesis and activity of NH2‐ and COOH‐terminal elastase recognition sequences on cotton

J. Vincent Edwards、Sarah Batiste、E.M. . Gibbins 等 4 位作者1999-12-01Journal of Peptide Research

The application of peptide recognition sequences of elastase to fibers of wound dressings is a possible route to inhibiting high levels of destructive elastase in the chronic wound. For this reason we have synthesized the elastase recognition sequence Val-Pro-Val on both cotton cellulose, and carboxymethylated cellulo…

Wound Healing and TreatmentsDyeing and Modifying Textile FibersSilk-based biomaterials and applications