Materials Literature
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Understanding the toxicity of silica nanoparticles (SiO(2)) on the cellular level is crucial for rational design of these nanomaterials for biomedical applications. Herein, we explore the impacts of geometry, porosity, and surface charge of SiO(2) on cellular toxicity and hemolytic activity. Nonporous Stöber silica na…
This paper reviews progress that has been made in the use of Raman spectroscopy to study graphene and carbon nanotubes. These are two nanostructured forms of sp2 carbon materials that are of major current interest. These nanostructured materials have attracted particular attention because of their simplicity, small ph…
Nanoparticles are an essential component in the emerging field of nanomedical imaging and therapy. When deployed in vivo, these materials are typically protected from the immune system by polyethylene glycol (PEG). A wide variety of strategies to coat and characterize nanoparticles with PEG has established important t…
Graphene, a two-dimensional, single-layer sheet of sp(2) hybridized carbon atoms, has attracted tremendous attention and research interest, owing to its exceptional physical properties, such as high electronic conductivity, good thermal stability, and excellent mechanical strength. Other forms of graphene-related mate…
Statistical and probabilistic behaviors of fibers forming fiber webs of all kinds are of great significance in the determination of the uniformity and physical properties of the webs commonly found in many industrial products such as filters, membranes and non-woven fabrics. However, in studying the spatial geometry o…
열원으로 열풍과 마이크로파를 이용하여 비극성 ethylene-propylene-diene terpolymer(EPDM)/카본블랙 컴파운드 제조에 있어서 시편의 두께 및 첨가제 함량에 따른 가황속도의 영향을 비교 조사하였다. 열풍가황의 경우, 컴파운드의 두께가 가장 중요한 인자로서 EPDM의 나쁜 열전도도 특성으로 인하여 컴파운드의 두께가 증가할수록 가황속도는 느려졌으며 두께 3 mm 컴파운드의 완전 가황은 250 ℃에서 7분 이상이 소요되었다. 반면에 마이크로파 가황에서는 컴파운드의 두께에 의한 영향은 없었으나 극성첨가제인 카본블랙 함량에 큰 영향을 받았다. 카본블…
Inelastic neutron scattering was employed to study the magnetic excitations of Mn${}^{3+}$ dimers in LaMn${}_{0.1}$Ga${}_{0.9}$O${}_{3}$. The nearest-neighbor interaction of Mn${}^{3+}$ ions is ferromagnetic in the basal (a-b) plane, but antiferromagnetic along the $c$ direction; thus two different types of dimer exci…
The purpose of this work is to present the experiment results by a dynamic adsorption of water vapor on pelletized zeolites (ADZ300, ADZ400, and ADZ500) in fixed bed. The breakthrough curves of water vapor with several different concentrations and temperature in the range of 25~45 <TEX>$^{\circ}C$</TEX> on zeolite bed…
Inhibition of the hydrogen embrittlement of Ni-Ti superelastic alloy in an acidulated phosphate fluoride (APF) solution has been attempted by adding various amounts of H(2)O(2). In a 0.2% APF solution, hydrogen absorption is markedly inhibited by adding H(2)O(2), although corrosion is slightly enhanced by increasing t…
Abstract The effect of silica nanofiller surface chemistry on compounded particle size and high strain particle dewetting in a semitransparent nanosilica‐filled elastomer composite was determined using backscattered visible light and transmitted light, respectively. The integrated intensities of backscattered light fr…
1,4-Dihydroxy-2-naphthoyl-coenzyme A (DHNA-CoA) synthase, or MenB, catalyzes an intramolecular Claisen condensation involving two oxyanion intermediates in the biosynthetic pathway of menaquinone, an essential respiration electron transporter in many microorganisms. Here we report the finding that the DHNA-CoA product…
and experimental backgrounds are considered for developing a much simpler, more technological and effective method (in comparison with the known megabar compression dynamic and static methods) of producing a high-density solid molecular ("reversible") hydrogen carrier by means of hydrogen intercalation (at the cost of…
We inquire into the possible coexistence of macroscopic and microstructured phases in random Q-block copolymers built of incompatible monomer types A and B with equal average concentrations. In our microscopic model, one block comprises M identical monomers. The block-type sequence distribution is Markovian and charac…
Metal soaps of Ximenia americana seed oil (XSO) and Balanites aegyptiaca seed oil (BSO) were prepared by metathesis in aqueous alcohol solution. The thermal stability of the metal carboxylates (soaps) was studied thermogravimetrically in the temperature range 50 – 500°C under nitro…
Abstract This work aims to systematically study a reactive extrusion process for the synthesis of graft copolymers with polystyrene (PS) as backbone and polyamide 6 (PA6) as grafts. The underlying chemistry relies on the use of a random copolymer of styrene (St) and 3‐isopropenyl‐α,α‐dimethylbenzene isocyanate (TMI),…
Abstract A nanostructured Ni 50 Co 50 mixture was prepared by high‐energy ball milling in a planetary ball mill (Frisch P7) under an argon atmosphere. Scanning electron microscopy and X‐ray diffraction (XRD) have been used to study the morphology of the powder particles, microstructure, and structure evolution. Detail…
Some porous titanium dioxide (TiO 2 ) films were prepared on flexible substrates by the method of micro‐arc oxidation (MAO) combined with magnetron sputtering (MS). The original material of MAO was Ti films prepared by MS, which was composed of columnar crystals with a diameter of less than 150 nm. The results indicat…
Abstract New poly(ether ether ketone)s and poly (ether ether ketone ketone)s were synthesized by polycondensation of each of the three bisphenols, viz., 4,4′‐(octahydro‐2(1H)‐naphthylidene)bisphenol, 4,4′‐(octahydro‐2(1H)‐naphthylidene)bis‐3‐methylphenol, and 4,4′‐(octahydro‐2(1H)‐naphthylidene)bis‐3,5‐dimethylphenol…
Abstract The cyanoethylation of cotton fabric was carried out using aqueous sodium hydroxide with acrylonitrile in presence of solvents like acetone and ethanol in different concentrations. The modified cellulose was investigated with vertical wicking test, X‐ray diffraction (XRD), thermogravimetry‐differential therma…
Neutron diffraction experiments have been performed on powder samples of LaMnO(3) below and above the Jahn-Teller transition temperature of 750 K. Experimental investigations are assisted by density functional theory calculations. Theoretical studies are carried out for the orbitally ordered state of LaMnO(3) which al…