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Sorption and transport of CO2 in PVF2/PMMA Blends

J. S. Chiou、Donald R. Paul1986-07-01Journal of Applied Polymer Science

Abstract The sorption and transport of CO 2 in miscible PVF 2 /PMMA blends are reported at 35°C as a function of pressure from 1 to 25 atm. Significant plasticization by CO 2 is evident for all blend compositions. This effect induced further crystallization of PVF 2 for some blends, altered the shape of sorption isoth…

Polymer crystallization and propertiesPolymer Foaming and CompositesPolymer Science and PVC

The three-dimensional structure of porcine heart mitochondrial malate dehydrogenase at 3.0-A resolution.

Steven L. Roderick、Leonard Banaszak1986-07-01Journal of Biological Chemistry

In a previous study, we reported the apparent similarity between a low resolution electron density map of mitochondrial malate dehydrogenase and a model of cytoplasmic malate dehydrogenase (Roderick, S. L., and Banaszak, L. J. (1983) J. Biol. Chem. 258, 11636-11642). We have since determined the polypeptide chain conf…

Protein Structure and DynamicsMetabolism and Genetic DisordersEnzyme Structure and Function

Redox migration mechanism of charge transport in molecularly doped polymers

John S. Facci、M. Štolka1986-07-01Philosophical Magazine B

A simple model of hopping transport in a molecularly doped polymer is described based on a small electric-field perturbation of diffusional (random walk) electron self-exchange reactions in the solid state. A master expression is derived which quantitatively accounts for the electrical field, temperature and concentra…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsElectrochemical Analysis and Applications

A convenient synthesis of a "gable"-type porphyrin

Jonathan L. Sessler、Jeff Hugdahl、Martin R. Johnson1986-07-01The Journal of Organic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA convenient synthesis of a "gable"-type porphyrinJonathan L. Sessler, Jeff Hugdahl, and Martin R. JohnsonCite this: J. Org. Chem. 1986, 51, 14, 2838–2840Publication Date (Print):July 1, 1986Publication History Published online1 May 2002Published inissue 1 July 1986https://p…

Supramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine ChemistrySurface Chemistry and Catalysis

Cloning and sequencing of the major intracellular serine protease gene of Bacillus subtilis

YOSHINOBU KOIDE、Akira Nakamura、T Uozumi 等 4 位作者1986-07-01Journal of Bacteriology

A Bacillus subtilis 2.7-kilobase DNA fragment containing an intracellular protease gene was cloned into Escherichia coli. The transformants produced an intracellular protease of approximately 35,000 Mr whose activity was inhibited by both phenylmethylsulfonyl fluoride and EDTA. Introduction of the fragment on a multic…

Bacteriophages and microbial interactionsEnzyme Structure and FunctionEnzyme Production and Characterization

Liquid-Crystalline Behaviour in the n-Alkyl Gluconamides and Other Related Carbohydrates

B. Pfannemüller、Wolfram Welte、E. Chin 等 4 位作者1986-07-01Liquid Crystals

Many alkyl derivatives of carbohydrates are used as detergents for cell wall membranes. This study describes the liquid-crystalline properties of a number of these systems. The combination of a hydrophilic carbohydrate moiety and a hydrophobic aliphatic substituent leads to the formation of both thermotropic and lyotr…

Liquid Crystal Research AdvancementsPolysaccharides and Plant Cell WallsPlant Reproductive Biology

Preparation and NMR studies of pentacoordinated silicon anions

Robert Damrauer、Stephen E. Danahey1986-07-01Organometallics

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPreparation and NMR studies of pentacoordinated silicon anionsRobert Damrauer and Stephen E. DanaheyCite this: Organometallics 1986, 5, 7, 1490–1494Publication Date (Print):July 1, 1986Publication History Published online1 May 2002Published inissue 1 July 1986https://pubs.ac…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisMechanical and Optical Resonators

In situ generated colloidal semiconductor cadmium sulfide particles in dihexadecyl phosphate vesicles: quantum size and symmetry effects

Yves M. Tricot、János H. Fendler1986-07-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTIn situ generated colloidal semiconductor cadmium sulfide particles in dihexadecyl phosphate vesicles: quantum size and symmetry effectsYves M. Tricot and Janos H. FendlerCite this: J. Phys. Chem. 1986, 90, 15, 3369–3374Publication Date (Print):July 1, 1986Publication Histor…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesElectrochemical Analysis and Applications

Phase behavior of amorphous binary mixtures of perdeuterated and normal 1,4-polybutadienes

Frank S. Bates、G. D. Wígnall、S. B. Dierker1986-07-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhase behavior of amorphous binary mixtures of perdeuterated and normal 1,4-polybutadienesF. S. Bates, G. D. Wignall, and S. B. DierkerCite this: Macromolecules 1986, 19, 7, 1938–1945Publication Date (Print):July 1, 1986Publication History Published online1 May 2002Published…

Liquid Crystal Research AdvancementsPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Conduction-electron-spin resonance in organic conductors:αandβphases of di[bis(ethylenedithiolo)tetrathiafulvalene]triiodide [(BEDT-TTF)2I3]

Tadashi Sugano、Gunzi Saito、Minoru Kinoshita1986-07-01Physical review. B, Condensed matter

The electron-spin resonance g value, linewidth, line shape, and spin susceptibility of single crystals of the \ensuremath{\alpha} and \ensuremath{\beta} phases of di[bis(ethylenedithiolo)tetrathiafulvalene]triiodide [(BEDT-TTF${)}_{2}$${\mathrm{I}}_{3}$] are each found to show marked temperature and angular dependence…

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchElectron Spin Resonance Studies

Theoretical study of the heats of formation of Si2Hn (n = 0-6) compounds and trisilane

Pauline Ho、Michael E. Coltrin、J. Stephen Binkley 等 4 位作者1986-07-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTheoretical study of the heats of formation of Si2Hn (n = 0-6) compounds and trisilanePauline Ho, Michael E. Coltrin, J. S. Binkley, and C. F. MeliusCite this: J. Phys. Chem. 1986, 90, 15, 3399–3406Publication Date (Print):July 1, 1986Publication History Published online1 Ma…

Advanced Chemical Physics StudiesMesoporous Materials and CatalysisCatalysis and Oxidation Reactions

The refined structure of vitamin D-dependent calcium-binding protein from bovine intestine. Molecular details, ion binding, and implications for the structure of other calcium-binding proteins.

Doletha M. E. Szebenyi、Keith Moffat1986-07-01Journal of Biological Chemistry

The structure of bovine intestinal calcium-binding protein (ICaBP) has been determined crystallographically at a resolution of 2.3 A and refined by a least squares technique to an R factor of 17.8%. The refined structure includes all 600 non-hydrogen protein atoms, two bound calcium ions, and solvent consisting of one…

Protein Structure and DynamicsEnzyme Structure and FunctionBiochemical and Molecular Research

An Explanation for the "Two Fiber Axes" Problem in Human Enamel by X-ray Diffraction

Fumio Hirota1986-07-01Journal of Dental Research

Since Thewlis found the "two fiber axes" patterns on x-ray diffractograms of human enamel in 1934, many investigators have studied this problem. However, a definite answer has not yet been obtained. The present detailed x-ray diffraction study showed that the "two fiber axes" patterns in human enamel were caused by re…

Advanced X-ray Imaging TechniquesNuclear Physics and ApplicationsRadiation Shielding Materials Analysis

Carbon Black Treadwear Ratings from Laboratory Tests

E. M. Dánnenberg1986-07-01Rubber Chemistry and Technology

Abstract It has been seen from the above survey that a few of the treadwear predictor correlations have the required accuracy to provide a satisfactory alternative to road testing of tires for the wear performance of carbon blacks, depending on requirements and circumstances. Correlations based on laboratory rubber te…

Asphalt Pavement Performance EvaluationPolymer Nanocomposites and PropertiesLubricants and Their Additives

Coil dimensions of polystyrenes in isorefractive viscous solvents by small-angle neutron scattering

Timothy P. Lodge、K. C. Hermann、Michael R. Landry1986-07-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCoil dimensions of polystyrenes in isorefractive viscous solvents by small-angle neutron scatteringT. P. Lodge, K. C. Hermann, and M. R. LandryCite this: Macromolecules 1986, 19, 7, 1996–2002Publication Date (Print):July 1, 1986Publication History Published online1 May 2002P…

Liquid Crystal Research AdvancementsPolymer Nanocomposites and PropertiesSurfactants and Colloidal Systems

17—AN ANALYSIS OF THE AIR-JET YARN-TEXTURING PROCESS PART III: FILAMENT BEHAVIOUR DURING TEXTURING

Memiş Acar、R. K. Turton、G. R. Wray1986-07-01Journal of the Textile Institute

Experiments performed with a current industrial-texturing nozzle on a specially designed singlehead texturing machine are described. These involve the use of high-speed still and cine photography, together with measurements of yarn speed on emergence from the nozzle and yarn-tension measurements at various stages of t…

Textile materials and evaluations

The Amorphous to Crystalline Transformation of Anodic Aluminum Oxide during Anodization in an Ammonium Citrate Electrolyte

Gudrun A. Hutchins、C. T. Chen1986-07-01Journal of The Electrochemical Society

The growth of crystalline anodic aluminum oxide during anodization in an aqueous ammonium citrate electrolyte has been investigated. Crystalline sites were observed to nucleate only during the early growth of the oxide film, and their number was dependent upon the electrolyte temperature and the crystallographic orien…

Photonic Crystals and ApplicationsAcoustic Wave Resonator TechnologiesAnodic Oxide Films and Nanostructures

Spectroelectrochemistry of (.mu.-oxo)bis[phthalocyaninato)iron(III)]

Lawrence A. Bottomley、Claudio Ercolani、J.‐N. GORCE 等 5 位作者1986-07-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSpectroelectrochemistry of (.mu.-oxo)bis[phthalocyaninato)iron(III)]Lawrence A. Bottomley, Claudio Ercolani, Jean Noel Gorce, Giovanna Pennesi, and Gentilina RossiCite this: Inorg. Chem. 1986, 25, 14, 2338–2342Publication Date (Print):July 1, 1986Publication History Publishe…

Porphyrin and Phthalocyanine ChemistryElectrochemical Analysis and ApplicationsMetal-Catalyzed Oxygenation Mechanisms

An Assessment of Clinch River Breeder Reactor Core Disruptive Accident Energetics

T.G. Theofanous、C.R. Bell1986-07-01Nuclear Science and Engineering

A methodology is developed for the evaluation of the energetic consequences of postulated core disruptive accidents (CDAs), in liquid-metal fast breeder reactors. The methodology provides a framework for integrating the results of mechanistic analyses, including whole-core simulations (SAS, SIMMER), special effects an…

Nuclear reactor physics and engineeringNuclear Materials and PropertiesNuclear Engineering Thermal-Hydraulics

Spectroscopic Photoresponse of the Passive Film Formed on Iron

Kazuhisa Azumi、Toshiaki Ohtsuka、Norio Sato1986-07-01Journal of The Electrochemical Society

Spectroscopic photoresponse of the passive film formed on iron in neutral borate solution was studied. The spectroscopic three parameter reflectometry and the photoelectrochemical technique were employed to obtain the spectra of absorption coefficient and photocurrent. From these spectra, a conversion efficiency, η, f…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsIron oxide chemistry and applications