Materials Literature
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Their small sizes enable nanomaterials to express novel properties that have created a revolution in science and technology since their discovery in the 1990s. The new transport, morphology and material properties of nano-enabled products, however, have imposed revision of environmental, health, and safety risk assess…
Composite quantum chemical methods W1X-1 and CBS-QB3 are used to calculate the gas phase standard enthalpy of formation, entropy, and heat capacity of 38 phosphines and phosphine oxides for which reliable experimental thermochemical information is limited or simply nonexistent. For alkyl phosphines and phosphine oxide…
This study examined the effect of high temperature and Litsea cubeba oil with its main components against molds (Aspergillus niger, Aspergillus flavus, Penicillium sp., Penicillium cyclopium, Rhizopus sp., Fusarium sp., and Cladosporium sp.) on bamboo food packaging. Response surface methodology (RSM) with X1 (concent…
We have previously reported the synthesis of enantiopure β,γ-diamino acids and relevant short α/γ-peptide containing such building blocks. Complete nuclear magnetic resonance (NMR) studies, together with molecular modeling, highlighted the ability of a β,γ-diamino acid to induce various intramolecular turns. In this p…
Abstract Stabilization of biomolecules on matrices is critically important. Here we constructed composite nanofibers with magnetic features by electro‐spinning of magnetic nanoparticles (MNP) in an appropriate polymer matrix on a collector surface for multiple uses. ‘Poly(vinylalcohol)‐polyethyleneimine/Fe3O4 magnetic…
A tiling rule guides the formation of quasicrystalline superlattices of nanocrystals
Isothermal titration calorimetry (ITC) along with attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM/EDX) and high-performance liquid chromatography (HPLC) were employed to investigate the process of adsorption of…
GaN fins on GaN‐on‐sapphire templates are fabricated by continuous mode selective area metalorganic vapor phase epitaxy. The fins exhibit high aspect ratios and smooth nonpolar a‐plane sidewalls with an ultra‐low threading dislocation density of a few 105 cm−2 making them ideally suited for optoelectronic to electroni…
Abstract Zweizähnige Bor‐Lewis‐Säuren wurden ausgehend von 1,8‐Diethinylanthracen in zwei Schritten synthetisiert. Dazu wurden die endständigen Alkine zunächst stannyliert und anschließend Zinn‐Bor‐Austauschreaktionen mit verschiedenen Chlorboranen durchgeführt. Die Reaktionen liefern einen sehr selektiven Zugang zu d…
Tripoli from two Ukrainian deposits was studied in its natural and modified forms. The investigation of natural and modified tripoli involves the identification of their phase compositions through X-ray diffraction and the analysis of their water vapor adsorption-desorption isotherms. The obtained results are evidence…
Proceedings of the National Academy of Sciences (PNAS), a peer reviewed journal of the National Academy of Sciences (NAS) - an authoritative source of high-impact, original research that broadly spans the biological, physical, and social sciences.
Proctor's work on staircase plane partitions yields an exact enumeration of lozenge tilings of a halved hexagon on the triangular lattice. Rohatgi later extended this tiling enumeration to a halved hexagon with a triangle cut off from the boundary. In his previous paper, the author proved a common generalization of Pr…
Transmission electron microscopy, neutron diffraction, and synchrotron powder X-ray diffraction reveal a complex modulated structure on the doubly ordered perovskite NaLaCoWO 6 . Electron diffraction patterns as well as high-resolution transmission electron microscopy images clearly show a periodicity of 12 a p, where…
ABSTRACT Perfluoropolyalkylethers derived from hexafluoropropylene oxide were functionalized with maleimide groups. Irradiated by UV‐light, the new maleimide macromonomers demonstrated very fast polymerization kinetics with a curing time as fast as 8 s. The effect on photopolymerization of different features such as t…
The article has analyzed the world experience and main trends in the preparation of cadaveric skin for use in the treatment of patients with wounds of various etiologies. The history of the question is described from the first attempts of transplantation of the native skin to the creation of specialized banks of allog…
For multifunctional optimization design of honeycomb structures, the high stiffness hierarchical honeycombs with stochastic Voronoi substructures (HHSVS) are proposed by substituting cell walls of the regular hexagonal honeycombs (ORHH) with Voronoi honeycomb lattices of equal mass. In this study, the tunable linear e…
Spontaneous formation of isoaspartates (isoDs) often causes protein damage. l-Isoaspartate O-methyltransferase (PIMT) repairs isoD residues by catalyzing the formation of an unstable l-isoaspartyl methyl ester that spontaneously converts to an l-aspartyl residue. PIMTs are widely distributed in all three domains of li…
Following systematic scrutiny of the evidence in support of the hypothesis that the cardioprotective mechanism of action of dexrazoxane is mediated by a 'depletion' or 'downregulation' of Top2β protein levels in heart tissue, the author concludes that this hypothesis is untenable. In seeking to understand how dexrazox…
An integrated Kinetic Monte Carlo–structure–rheology model is developed for polyolefins produced using solution copolymerization of ethylene and α-olefins. The proposed algorithm is completely first-principle and can be used to simulate any homogeneous single-site polymerization process resulting in full topological a…
Abstract The aim of the present study was to investigate whether the use of drug-loaded microbubbles combined with ultrasound promotes the apoptosis of cancer cells by regulating B-cell lymphoma-2 (Bcl-2) and Bcl-2-associated X protein (Bax) expression. Adriamycin-loaded PLGA nanoparticles (ADM-NP) were fabricated usi…