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Electrolyte tuning in dye-sensitized solar cells with N-heterocyclic carbene (NHC) iron(II) sensitizers

Mariia Karpacheva、Catherine E. Housecroft、Edwin C. Constable2018-12-21Beilstein Journal of Nanotechnology

We demonstrate that the performances of dye-sensitized solar cells (DSCs) sensitized with a previously reported N-heterocyclic carbene iron(II) dye in the presence of chenodeoxycholic acid co-adsorbant, can be considerably improved by altering the composition of the electrolyte while retaining an I−/I3− redox shuttle.…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesQuantum Dots Synthesis And Properties

A Slim Polymer Film with a Seamless Panoramic Field of View: The Radially Distributed Waveguide Encoded Lattice (RDWEL)

Hao Lin、Ian D. Hosein、Kathryn A. Benincasa 等 4 位作者2018-12-21Advanced Optical Materials

Abstract The nearly hemispherical field of view (FOV) of arthropodal compound eyes has inspired analogs ranging from curved, lens‐patterned domes to planar constructs patterned with microlenses. A radial distribution of cylindrical waveguides that monotonically spans ±33° confers an FOV of 115° to a slim (≤3 mm) polym…

Photonic and Optical DevicesLiquid Crystal Research AdvancementsAdvanced optical system design

Water-Soluble Humic Materials Regulate Quorum Sensing in Sinorhizobium meliloti Through a Novel Repressor of expR

Yuanyuan Xu、Jinshui Yang、Cong Liu 等 9 位作者2018-12-21Frontiers in Microbiology

Quorum sensing (QS) plays an important role in the growth, nodulation, and nitrogen fixation of rhizobia. In this study, we show that water-soluble humic materials (WSHM) repress the expression of the QS related genes sinI, sinR, and expR in Sinorhizobium meliloti. This decreased the production of N-acetyl homoserine…

Legume Nitrogen Fixing SymbiosisGeochemistry and Elemental AnalysisLayered Double Hydroxides Synthesis and Applications

Zn Phthalocyanine Derivatives for Solution‐Processed Small Molecule Organic Solar Cells

Fatma Aslihan Sarı、Mehmet Kazıcı、Ersan Harputlu 等 9 位作者2018-12-21ChemistrySelect

Abstract Zinc phthalocyanine derivatives, 1 and 2 , having either electron donating octyl‐thiol group or electron accepting octyl‐sulfonyl groups have been synthesized to serve as new electron donor components for bulk heterojunction (BHJ) solar cells. BHJ solar cells, in which the active layer consist of zinc phthalo…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

The Influence of Inter-Cooling and Electromagnetic Stirring above Liquidus on the Formation of Primary Al3Zr and Grain Refinement in an Al-0.2%Zr Alloy

Tianyang Guan、Zhifeng Zhang、Yuelong Bai 等 8 位作者2018-12-21Materials

The nucleation and grain growth that occur during solidification have been extensively examined, but insight into the influence of an external field on the formation of heterogeneous crystal nuclei above the liquidus remains unclear in the peritectic refinement mechanism. In this work, we studied the effect of cooling…

Aluminum Alloy Microstructure PropertiesAluminum Alloys Composites PropertiesSolidification and crystal growth phenomena

Organische Photosäuren‐ und Photobasenbildner für Polymerisationen: Jüngste Fortschritte und Herausforderungen

Nicolas Zivic、Paula K. Kuroishi、Frédéric Dumur 等 6 位作者2018-12-21Angewandte Chemie

Abstract Photopolymerisation, oder in anderen Worten die Nutzung von Licht als Auslöser einer Polymerisationsreaktion, ist eine der vielversprechendsten Technologien zur Herstellung anspruchsvoller Polymere. Eine der Schlüsselkomponenten der Photopolymerisation ist die photoaktive Spezies. Diese ist in der Lage, durch…

Advanced Polymer Synthesis and CharacterizationPhotochromic and Fluorescence ChemistryPhotopolymerization techniques and applications

Electrohydrodynamic-Enhanced Natural Convection in an Enclosure by a Nonsymmetric Electric Field

F. C. Lai2018-12-21Journal of Thermophysics and Heat Transfer

The present study investigates heat transfer enhancement of natural convection in an air-filled enclosure by a nonsymmetric electric field. The geometry considered is a two-dimensional cavity with an aspect ratio of five. The electrical field is generated from a wire electrode charged with a high voltage of direct cur…

High voltage insulation and dielectric phenomenaAerosol Filtration and Electrostatic PrecipitationElectrohydrodynamics and Fluid Dynamics

Theoretical insight into the electrocatalytic reduction of CO 2 with different metal ratios and reaction mechanisms on palladium–copper alloys

Minmin Xing、Ling Guo、Zijun Hao2018-12-21Dalton Transactions

Environmental impacts of continued CO2 production have led to an increased need for new methods of CO2 removal and energy development. Electrochemical reduction of CO2 has been shown to be a good method through recent studies. Alloys are of special interest for these applications, because of their unique chemical and…

Advanced Thermoelectric Materials and DevicesIonic liquids properties and applicationsCO2 Reduction Techniques and Catalysts

Multiple adjustable optical Tamm states in one-dimensional photonic quasicrystals with predesigned bandgaps

Yue Fei、Youwen Liu、Daxing Dong 等 6 位作者2018-12-21Optics Express

We proposed an approach to get multiple and adjustable optical Tamm states (OTSs) by constructing a structure consisting of a metal layer and one-dimensional photonic quasicrystals with preassigned bandgaps. In the structure, multiple OTSs excited simultaneously in each bandgap were observed. We explored the physics m…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchPhotonic Crystals and Applications

pH-independent dissolution enhancement for multiple poorly water-soluble drugs by nano-sized solid dispersions based on hydrophobic–hydrophilic conjugates

Chau T. M. Tran、Phuong H.L. Tran、Thao T.D. Tran2018-12-21Drug Development and Industrial Pharmacy

The objective of this study was to achieve an optimal formulation of hydrophilic-hydrophobic conjugates for nano-sized solid dispersions (SDs) with enhanced dissolution of multiple drugs in different gastrointestinal (GI) tract environments. A new conjugate powder with an optimized process was used to fabricate SDs th…

Nanoparticle-Based Drug DeliveryDrug Solubulity and Delivery SystemsAdvanced Drug Delivery Systems

Two-photon and three-photon absorption in ZnO nanocrystals embedded in Al2O3 matrix influenced by defect states

Gang Wang、Si Xiao、Yuhui Peng 等 6 位作者2018-12-21Optics Letters

The broadband nonlinear absorption in ZnO nanocrystals embedded in Al2O3 matrix was investigated by Z-scan and pump–probe techniques from 400 nm to 800 nm. The effective two-photon absorption and three-photon absorption coefficients were determined to be ∼1.1×103 cm/GW at 400 nm and ∼1.1×10−1 cm3/GW2 at 800 nm, respec…

ZnO doping and propertiesNonlinear Optical Materials ResearchNonlinear Optical Materials Studies

Real-Time Investigation of Recovery, Recrystallization and Austenite Transformation during Annealing of a Cold-Rolled Steel Using High Energy X-ray Diffraction (HEXRD)

Marc Moreno、Julien Teixeira、Guillaume Géandier 等 7 位作者2018-12-21Metals

The annealing process of cold-rolled ferrite/pearlite steel involves numerous metallurgical mechanisms as recovery/recrystallization of deformed phases, ripening of carbide microstructure, and austenite transformation in the intercritical domain. The interactions between these mechanisms govern the morphogenesis of th…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsMetal Alloys Wear and Properties

Influence of Synthesis Conditions on Microstructure and NO2 Sensing Properties of WO3 Porous Films Synthesized by Non-Hydrolytic Sol–Gel Method

Sikai Zhao、Yanbai Shen、Pengfei Zhou 等 9 位作者2018-12-21Nanomaterials

Nanostructured tungsten trioxide porous films were prepared by a non-hydrolytic sol⁻gel method following the inorganic route in which ethanol and PEG were used as the oxygen-donor and structure-directing reagent, respectively. The effects of aging time of the precursor solution, PEG content, and calcination temperatur…

Gas Sensing Nanomaterials and SensorsTransition Metal Oxide NanomaterialsAnalytical Chemistry and Sensors

Peculiar Aggregation Features in Poly(3-hexylthiophene)/Chlorobenzene Solutions

Han Yi、Chi‐Chung Hua2018-12-21Macromolecules

We report on anomalous structure and relaxation features of the aggregate clusters fostered in a representative series of dilute poly(3-hexylthiophene)/chlorobenzene (P3HT/CB) solutions (3, 5, 8, and 10 mg/mL), as resolved by multiscale dynamic/static analysis schemes including depolarized/polarized dynamic light scat…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsSynthesis and properties of polymers

Does capillary evaporation limit the accessibility of nonaqueous electrolytes to the ultrasmall pores of carbon electrodes?

Kun Liu、Pengfei Zhang、Jianzhong Wu2018-12-21The Journal of Chemical Physics

Porous carbons have been widely utilized as electrode materials for capacitive energy storage. Whereas the importance of pore size and geometry on the device performance has been well recognized, little guidance is available for identification of carbon materials with ideal porous structures. In this work, we study th…

Supercapacitor Materials and FabricationIonic liquids properties and applicationsElectrochemical Analysis and Applications

High-quality SiN x / p -GaN metal-insulator-semiconductor interface with low-density trap states

Bing Ren、Meiyong Liao、Masatomo Sumiya 等 7 位作者2018-12-21Journal of Physics D Applied Physics

Abstract We report on a high-quality p -GaN metal-insulator-semiconductor (MIS) capacitors with sharp interface morphology and the lowest interface trap density by using SiN x as the gate dielectric layer. Transmission electron microscopy and x-ray photoelectron spectroscopy (XPS) analysis revealed a high-quality inte…

GaN-based semiconductor devices and materialsSemiconductor materials and devicesGa2O3 and related materials

Characterization of composites based on polyoxymethylene and effect of silicone addition on mechanical and tribological behavior

Patrycja Bazan、Stanisław Kuciel、Marek Nykiel2018-12-21Polymer Engineering and Science

Additives to polymer materials allow to obtain a wide range of functional properties. The improvement of wear and durability of plastics is achieved by the use of powder or fibrous fillers and complex modifications of structure. The aim of the work was to examine the physical, mechanical and tribological properties of…

Natural Fiber Reinforced CompositesTribology and Wear AnalysisMaterial Properties and Applications

Active, Autonomous, and Adaptive Polymeric Particles for Biomedical Applications

Shauni Keller、B. Jelle Toebes、Daniela A. Wilson2018-12-21Biomacromolecules

Nature's motors are complex and efficient systems, which are able to respond to many different stimuli present in the cell. Nanomotors for biomedical applications are designed to mimic nature's complexity; however, they usually lack biocompatibility and the ability to adapt to their environment. Polymeric vesicles can…

Nanoparticle-Based Drug DeliveryHydrogels: synthesis, properties, applicationsMicro and Nano Robotics

Effect of the particle size of pear pomace on the quality of enriched layer and sponge cakes

Andrés F. Rocha Parra、Mayara Belorio、Pablo D. Ribotta 等 5 位作者2018-12-21International Journal of Food Science & Technology

Abstract Pear pomace (PP) is a by‐product of the fruit industry with a high content of fibre. Its potential as an ingredient at 15% or 30% level for sponge and layer cakes was investigated. Three PP powders with different particle sizes (fine, medium and coarse) were obtained. Batter microstructure, density and viscos…

Food composition and propertiesNatural Fiber Reinforced Compositesbiodegradable polymer synthesis and properties