Materials Literature
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The electronic stability of gas-phase dianions of arbitrary size, X(2-), is determined by the first universal method to calculate second electron affinities, A(2). The model expresses A(2,calc) = A(1) - (7/6)η(0) by the first electron affinity, A(1), and chemical hardness, η(0), of the neutral "grandparent" species. A…
This study was carried out to obtain visual simulations of twill weave woven fabrics on a computer screen using certain fabric parameters. Warp and weft yarns in twill weave fabric structures are inclined in fabric longitudinal and transverse directions, and also stick out of the fabric plane because of being subjecte…
A novel active biocatalytic reaction system is proposed by covalently immobilizing porcine pancreas trypsin within the thermoresponsive polymer shell of superparamagnetic Fe₃O₄ nanoparticles.Active ester-functional nanocarriers suitable for the immobilization of amino functional targets are obtained in a single polyme…
Linoleic acid-protected gold nanoparticles have been synthesized through the chemical reduction of tetrachloroaurate ions by ethanol in presence of sodium linoleate. The structure of these nanoparticles is investigated using transmission electron microscopy, which shows that the Au nanoparticles are spherical in shape…
Abstract Commercial polydisperse atactic poly(methyl methacrylate) (PMMA) exhibits a decreased glass transition temperature ( T g ) when the film thickness is less than ∼60 nm, whereas more model atactic PMMA shows an increased T g in thin films supported on clean silicon wafers. NMR indicates no difference in tactici…
Thin films of hybrid arrays of cadmium selenide quantum dots and polymer grafted gold nanoparticles have been prepared using a BCP template. Controlling the dispersion and location of the respective nanoparticles allows us to tune the exciton-plasmon interaction in such hybrid arrays and hence control their optical pr…
Dendritic growth of fresnoite, a barium titanium silicate, is achieved at 1200 °C from a glass with the composition Ba 2 TiSi 2.75 O 9.5 using electrochemically induced nucleation. The highly oriented main trunk is formed with primary and secondary branches which obey this rule. In between the branches, a fourth hiera…
Silicon nanowires and nanoneedles show promise for many device applications in nanoelectronics and nanophotonics, but the remaining challenge is to grow them at low temperatures on low-cost materials. Here we present plasma-enhanced chemical vapor deposition of crystalline/amorphous Si nanoneedles on glass at temperat…
The photostabilization of poly(methy methacrylate) (PMMA) films by 2N-salicylidene-5-(substituted)-1,3,4-thiadiazole compounds was investigated. The PMMA films containing concentration of complexes 0.5% by weight were produced by the casting method from chloroform solvent. The photostabilization activities of these co…
The structural properties and the single-file diffusion in one-dimensional interacting colloidal systems are studied by means of Brownian dynamics simulations. We consider three types of particle interactions, namely, Weeks-Chandler-Andersen, screened Coulomb, and superparamagnetic potentials. We find that, regardless…
This paper presents results of the processing of nanocomposites based on epoxy and nanofillers, namely multiwalled carbon nanotubes (up to 10 wt%) and carbon black (up to 15 wt%). The twin screw extruded nanocomposites showed increases in electrical and thermal conductivities, tensile strength, microhardness and glass…
The Pd/silicon carbide (SiC) reaction rate in tristructural isotropic (TRISO)‐coated fuel particles has been studied. We have shown that it is possible to reduce the attack by palladium significantly by controlling the SiC microstructure. Large grain sizes as well as high coating rates did not increase the attack by P…
In recent years nano‐sized particles have been focused on bacteriostasis. We investigated antimicrobial activities by applying two types of silver nanoparticles on cotton fabric. These are MesoSilver particles and silver chloride compounds (Silpure). Silver chloride, used in aqueous dispersion, is mixed with a monomer…
BACKGROUND: Methylotrophic (methanol-utilizing) bacteria offer great potential as cell factories in the production of numerous products from biomass-derived methanol. Bio-methanol is essentially a non-food substrate, an advantage over sugar-utilizing cell factories. Low-value products as well as fine chemicals and adv…
The title problem is solved for an internally pressurised hole within the framework of plane-stress finite-strain plasticity. Material behaviour is modelled by the Tresca-associated flow theory with arbitrary hardening (softening), accounting for thickness changes and elastic compressibility. Three distinct plastic zo…
Electrical and gas sensing properties polyaniline-chloroaluminium phthalocyanine (PAni-ClAlPc) composite thin films were investigated to study the gas sensing behavior of composites. Devices (chemiresistor gas sensors) were prepared by spin coating method from PAni as the base of composites and ClAlPc (with different…
A modified procedure for electrocrystallization of organic conductors with paramagnetic anions has been proposed and a number of known and new BEDT-TTF salts with tris(oxalato)ferrate anion have been synthesized.
Iron (III) chloride tetraphenylporphyrin (FeTPPCl) thin films are prepared on quartz and glass substrates at room temperature by thermal evaporation technique. The X-ray diffraction showed the amorphous nature for both the as-deposited and the annealed films at 423 K in air for 2 h, whereas the powder has the tetragon…
Advances in basic knowledge relevant to the pseudocapacitive and electrocatalytic properties of RuO(2) materials require a detailed understanding of the redox chemistry that occurs at the electrode interface. Although several redox processes have been identified via dc cyclic voltammograms derived from surface-confine…
We theoretically consider the commensurability problem of AB diblock lamellar phase confined between parallel plates, in cylinder, and in sphere calculating the free energy of confined lamellar phase which is generalized in terms of dimensionality of confinement (d) and conformational asymmetry (ɛ). We find that the f…