Materials Literature
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Phytochemical screening of the roots of Gomphrena macrocephala, with particular attention to its triterpene glycoside constituents, has resulted in the isolation of two new oleanane glycosides (1 and 2) and a new taraxerane glycoside (3). The structures of 1-3 were determined as 11alpha,12alpha-epoxy-3beta-[(O-beta-D-…
The basic science in quantum transport of nano-scaled 'devices' is largely based on the availability of suitable model systems . Nanostructures built from conventional metals are typically in the diffusive transport regime. Semiconductors, as the starting material for nanodevices, are different. Because of the low car…
Density functional theory is employed to study Pd and Pd/Ni alloy monatomic chain-functionalized metallic single walled carbon nanotubes (SWNT(6,6)) and semiconducting SWNT(10,0), and their interactions with hydrogen molecules. The stable geometries and binding energies have been determined for both isolated chains an…
Reaction of two transition metal cations M (M = V V , Fe III ) on the open Wells–Dawson anion α-[{K(H 2 O) 2 }Si 2 W 18 O 66 ] 15– leads to dinuclear and tetranuclear complexes, respectively. The molecular anions [{KV 2 O 3 (H 2 O) 2 }(Si 2 W 18 O 66 )] 11– and [{Fe 4 (OH) 6 }(Si 2 W 18 O 66 )] 10– have been structura…
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The physicochemical and mechanical properties of amine-terminated covalently bound poly(ethylene glycol) (PEG) layers are dependent on fabrication methods. In particular, the use of a ϑ solvent yields dense polymer layers with properties not well described by traditional models. Light diffraction techniques were used…
Jewel-box: In a hierarchical process, three molecules of a calix[4]arene (blue) and six of barbituric or cyanuric acid (green) assemble into double-rosette boxes, which assemble into columns, which in turn assemble into columnar liquid-crystalline phases (see picture). The resulting mesophases have a remarkable therma…
Modulierbar: Optisch reversibel schaltbare fluoreszierende Verbindungen wurden synthetisiert, deren sichtbare Fluoreszenz mit Licht der Wellenlänge 360–400 nm bis auf 6 % unterdrückt und dann mit rotem Diodenlaserlicht wiederhergestellt werden kann. Die fluoreszierenden Schalter bieten Möglichkeiten für die Datenspeic…
In a stable condition: Oxyhydroxide colloids of chromium deposited on silica gel are selective, stable catalysts for the autoxidation of cyclohexane (CyH). The CrIII colloids, generated in situ, are immobilized by a column precipitation chromatographic technique (see picture). An increased yield of cyclohexanone (QO)…
The synthesis, characterization, and nucleophilic aromatic substitution (NAS) behavior of 3,5-difluorophenyl sulfone, 3, are reported. The reactivity of the electrophilic sites, activated by only a phenylsulfonyl group located in the meta position, in 3 was probed via NMR spectroscopy and model reactions and was deter…
The synthesis, characterization, and X-ray crystal structure of a well-defined yttrium(III) amide complex with the bis(thiophosphinic amide) ligand is reported. The new complex exhibits high rates and good control for lactide polymerization. The polymerization kinetics and mechanism are studied under a range of differ…
We report on the Fe17 high-spin molecular cluster and show that this system is an exemplification of nanostructured dipolar magnetism. Each Fe17 molecule, with spin S=35/2 and axial anisotropy as small as D approximately -0.02 K, is the magnetic unit that can be chemically arranged in different packing crystals while…
Nanocrystalline magnetite Fe3O4 samples with a grain size of about 40 nm have been synthesized by an optimized sol-gel method. The single phase of spinel magnetite was confirmed by both X-ray diffraction and transmission electron microscopy. It has been found that the magnetoresistance of the samples at low field (LFM…
First principles density functional pseudopotential calculations have been used to investigate the nature of interactions between single-walled carbon nanotubes (SWNTs) and intercalated transition metal metallocene complexes, M(eta-C(5)H(5))(2) (MCp(2)). Three composites, MCp(2)-graphene (d(t)=infinity), MCp(2)@(17,0)…
Magnetic measurements using a superconducting quantum interference device and magnetic force microscopy were performed on fullerene films irradiated with $250\phantom{\rule{0.3em}{0ex}}\mathrm{keV}$ Ar and $92\phantom{\rule{0.3em}{0ex}}\mathrm{MeV}$ Si ions, to compare the effects of electronic excitation and collisio…
A novel linear−dendritic copolymer containing thermoresponsive poly( N -isopropylacrylamide) (PNIPAAM), hydrophobic and biodegradable poly( l -lactic acid) (PLLA), and hydrophilic poly( l -lysine) (PLL) dendrons was designed, synthesized and characterized. The thermoresponsive- co -biodegradable linear−dendritic copol…
Abstract Three different electron beam irradiated fluoropolymers (ETFE, FEP, and PVDF) as well as their grafting reactions with styrene in different diluents were investigated by means of electron spin resonance (ESR). Depending on the atmosphere during irradiation, ESR spectra of peroxy and alkyl radicals were observ…
Abstract Poly(3‐hydroxybutyrate) (PHB)/layered double hydroxides (LDHs) nanocomposites were prepared by mixing PHB and poly(ethylene glycol) phosphonates (PEOPAs)‐modified LDH (PMLDH) in chloroform solution. Both X‐ray diffraction data and TEM micrographs of PHB/PMLDH nanocomposites indicate that the PMLDHs are random…
Abstract The anomalous fading (AF) of the Thermoluminescence (TL) signal has been observed in Durango apatite, and is believed to be caused by electrons transferred to the recombination sites via a tunnelling effect. The AF factor is a property unique for each glow‐peak of a glow‐curve and shows a remarkable stability…
This paper describes the synthesis and electrochemistry of biferrocenyl-terminated dendrimers and their beta-cyclodextrin (beta-CD) inclusion complexes in aqueous solution and at surfaces. Three generations of poly(propylene imine) (PPI) dendrimers, decorated with 4, 8, and 16 biferrocenyl (BFc) units, respectively, w…