Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRaman spectroscopic identification of the S4N- and S3- ions in blue solutions of sulfur in liquid ammoniaT. Chivers and C. LauCite this: Inorg. Chem. 1982, 21, 1, 453–455Publication Date (Print):January 1, 1982Publication History Published online1 May 2002Published inissue 1…
Poly-beta-hydroxybutyrate has been identified in the cyanobacterium Spirulina platensis. The addition of reduced carbon compounds to the growth medium was not required for poly-beta-hydroxybutyrate accumulation. Poly-beta-hydroxybutyrate accumulated during exponential growth to 6% of the total dry weight and then decr…
Abstract The extent of phase separation in Nafion® perfluorosulfonate ionomer membranes has been studied by small‐angle neutron scattering (SANS). These polymers, which consist of a perfluorocarbon main chain and a sulfonate‐containing side group, can absorb up to 30% by weight of water. Previous studies have shown th…
Abstract A practical scheme for the calculation of excited states of the same symmetry as a given reference state is outlined in the context of the Hartree‐Fock method. In order to prevent the excited state from “collapsing” into a lower‐lying state, the prediagonalized Fock matrix is diagonalized in a restricted subs…
We describe a new flexoelectric volume effect in homogeneous electric field, in the nematic phase of MBBA. An initial splay-bend texture is created by strong antagonistic planar and homeotropic anchoring on two glass plates. This results in a volume flexoelectric polarization. A transverse DC electric field creates a…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMixed-ligand complexes of trivalent lanthanide ions with .beta.-diketones and heterocyclic aminesK. Iftikhar, M. Sayeed, and N. AhmadCite this: Inorg. Chem. 1982, 21, 1, 80–84Publication Date (Print):January 1, 1982Publication History Published online1 May 2002Published inis…
Basic principles of polymer science. Thermoplastics materials. Additives, blends and composites. Deformation behaviour of thermoplastics in relation to product design. Engineering interpretations of mechanical failures. Complementary engineering properties. Rheological behaviour of thermoplastics in relation to proces…
Hydrogen peroxide decomposition in 1–5 mol dm–3 KOH and 1–2 mol dm–3 NaOH solutions is a first-order reaction with respect to undissociated hydrogen peroxide. The decomposition is catalysed by compounds of heavy metals (Fe, Cu) present as trace impurities in these solutions and is first order with respect to them. The…
Abrasive wear tests have been carried out on three steels and a number of pure metals using a pin-on-drum instrument. Each steel was tested at several different hardness levels attained by varying the heat treatment and while the results show a relationship between abrasion resistance and hardness, this was not the li…
(Uploaded by Plazi from the Biodiversity Heritage Library) No abstract provided.
X-ray diffraction data (Ag Ka and Mo Net radiation) have been collected at 74 K on dimanganese decacarbonyl Mn2(CO)I 0, and the crystal structure was refined. The atomic positional and thermal parameters were determined from high-angle AgKa data to avoid systematic errors due to bonding effects. The molecular geometry…
Plastic composites are members of both the oldest and the newest of materials. The first reinforced polymeric-based materials are recorded in Genesis and Exodus in the Bible as being used by the people of Babylonia and Mesopotamia around 4000–2000 B.C. These materials consisted of bitumen-based pitch for building prod…
Abstract Collapse loads are overestimated by finite‐element or finite‐difference procedures when the material discretization does not allow locally incompressible plastic flow: for example, constant‐strain triangles or tetrahedra give unacceptable results. The use of different discretizations for the isotropic and dev…
Inelastic neutron scattering measurements have been used to determine the site occupied by hydrogen in alpha Zr-H and alpha and beta Ti-H. The measured optical peak frequencies were only consistent with hydrogen being located on the tetrahedral sites in all cases. The significance of the energy shift between the hydri…
We have studied the oxidation of layered compound GaSe with no dangling bonds on the cleaved surface using XPS and AES techniques. At room temperature, the cleaved surface is not oxidized in an oxygen atmosphere. When subjected to Ar ion sputtering, the surface starts to exhibit the behavior of metallic Ga owing to di…
Measurements are presented for the diamagnetic anisotropy of thirteen nematic liquid crystals. As any bias in the rotation around the long molecular axis is most probably small, the results probe accurately the temperature variations of S, the degree of orientational order. The critical behaviour of S near the nematic…
Points of progress in current understanding of rapid liquid to solid transformation are reviewed. Emphasis is placed on those aspects of the emerging science that would permit development of guidelines and predictive models for alloy design and process control to achieve desired microstructures and properties. Recentl…
3H-Glycine and 6-aminohexanoic acid were used as model amine compounds and reacted with glutaraldehyde. Based on the spectral characteristics and the molecular weights obtained from the reaction products, it is concluded that glutaraldehyde can modify amines to form an intermediate which absorbs at 300 nm and has a mo…
A study was made of the effect of moisture on the emanation coefficient and radon flux from uranium mill tailings. A sharp rise in emanation coefficient occurred as the moisture content was increased from the absolutely dry state to 2% water by weight. The emanation coefficients from water-saturated tailings were abou…
A dynamical model is presented which describes the random motion of an interface of two coexisting phases. The Euclidean invariant stochastic equation of motion for the coordinate of the interface is derived systematically from the time-dependent Ginzburg-Landau model in the limit of infinitely deep potential well of…