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Evaluation of the interactions between polymeric chains and surfaces with different structures performed by an atomic force microscope

Rodrigo Lambert Oréfice、Anthony Brennan1998-10-01Materials Research

Interactions between polymers and inorganic surfaces are present in a series of phenomena involving processes such as coagulation and deffloculation of ceramic powder and adsorption of organic macromolecules on the surface of implants, among others. In this work, Atomic Force Microscopy (AFM) was modified to allow the…

Single-crystal SrTiO3 fiber grown by laser heated pedestal growth method: influence of ceramic feed rod preparation in fiber quality

D. Reyes Ardila、M.R.B. Andreeta、S.L. Cuffini 等 6 位作者1998-10-01Materials Research

The rapidly spreading use of optical fiber as a transmission medium has created an interest in fiber-compatible optical devices and methods for growing them, such as the Laser Heated Pedestal Growth (LHPG). This paper reports on the influence of the ceramic feed rod treatment on fiber quality and optimization of ceram…

Insights on the fractal-fracture behaviour relationship

José de Anchieta Rodrigues、Victor Carlos Pandolfelli1998-10-01Materials Research

The fractals theory has been increasingly applied in the field of materials science and engineering. Models of fractal lines and surfaces have been generated to describe the microstructural features of materials. Special interest is placed upon a description of the fracture surface based on a fractal geometry in order…

Evaluation of the solid/liquid interface undercooling during Sn-Se Eutectic growth

M. Zanotello、C.T. Rios、R.H.B. Jacon 等 4 位作者1998-10-01Materials Research

The Sn-Se eutectic solidification allows one to obtain a lamellar structure, formed by SnSe and SnSe2 compounds, which are p and n semiconducting types, respectively. The SnSe-SnSe2 eutectic composite is a promising material to be used in photovoltaic device manufacturing. In a lamellar eutectic microstructure, the ma…

Synthesis and luminescence spectroscopy of YNbO4 doped with Eu(III)

A.M.G. Massabni、G.J.M. Montandon、M.A. Couto dos Santos1998-10-01Materials Research

The solid compound YNbO4:Eu3+ was synthesized by an usual solid state reaction and a non-conventional method of thermal decomposition of precursors. X-ray diffraction data of the monoclinic YNbO4 were used to identify the crystalline M-fergusonite phase. The symmetry of the luminescent Eu3+ site is very close to the D…

Lanthanide and Transition Metal ComplexesGlass properties and applicationsLuminescence Properties of Advanced Materials

Glass phase expelling during liquid phase sintering of YSZ

Milton Ferreira de Souza、Dulcina Pinatti Ferreira de Souza1998-10-01Materials Research

Expelling of the liquid phase during sintering of ZrO2-6.5 mol% Y2O3- 0.5 mol% Pr2O3 ceramic was observed as a result of grain coarsening. ZrO2- 7.0 mol% Y2O3 samples, without Pr2O3 addition, do not show this effect under the same sintering conditions. The expelling process is caused by surface tension forces and attr…

Dynamic and fractal properties of SP-28 steel under high-speed loading conditions

Б. К. Барахтин、Yu. I. Meshcheryakov、G. G. Savenkov1998-10-01Technical Physics

Using an interferometric method to record the velocity of the free surface of a target subjected to two-dimensional shock loading, it is shown experimentally that the decrease in the compression pulse amplitude is due to the nonstationary nature of mesoscale processes — the amplitude decrease is progressively larger f…

Earthquake Detection and AnalysisHigh-Velocity Impact and Material BehaviorMaterial Properties and Failure Mechanisms

First-principles interatomic potentials for transition-metal aluminides. II. Application to Al-Co and Al-Ni phase diagrams

Mike Widom、John A. Moriarty1998-10-01Physical review. B, Condensed matter

Aluminum-rich intermetallic compounds and alloys are important for their technological applications and scientifically interesting for their complex structures such as quasicrystals. Detailed knowledge of interatomic interactions can help explain structural and mechanical properties of these systems. The first paper o…

Thermodynamic and Structural Properties of Metals and AlloysIntermetallics and Advanced Alloy PropertiesQuasicrystal Structures and Properties

Template Electropolymerization of Polypyrrole Nanostructures on Highly Ordered Pyrolytic Graphite Step and Pit Defects

J. D. Noll、M. A. Nicholson、P. Gregory Van Patten 等 5 位作者1998-10-01Journal of The Electrochemical Society

Polypyrrole nanostructures with diameters ⩽ 10 nm have been electropolymerized using step and pit defects on highly ordered pyrolytic graphite (HOPG) as templates for electropolymerization. Step defects were naturally occurring, and pits were formed via oxidation of freshly cleaved surfaces of an HOPG wafer by heating…

Conducting polymers and applicationsSurface Chemistry and CatalysisSupercapacitor Materials and Fabrication

Cu2O by XPS

R. P. Vasquez1998-10-01Surface Science Spectra

X-ray photoemission measurements of Cu2O are presented.

Copper-based nanomaterials and applicationsElectron and X-Ray Spectroscopy TechniquesCatalytic Processes in Materials Science

Evaluation of the fractionated crystallization of dispersed polyolefins in a polystyrene matrix

María L. Arnal、Mireya Matos、Rosa Morales 等 5 位作者1998-10-01Macromolecular Chemistry and Physics

When crystallisable polymers like isotactic poly(propylene) (iPP) or linear low density polyethylene (LLDPE) are finely dispersed in an incompatible matrix like atactic polystyrene (PS) a fractionated crystallisation process will develop if the number of dispersed droplets is greater than the number of active heteroge…

biodegradable polymer synthesis and propertiesPolymer Nanocomposites and PropertiesPolymer crystallization and properties

CuO by XPS

R. P. Vasquez1998-10-01Surface Science Spectra

X-ray photoemission measurements of CuO are presented.

Electron and X-Ray Spectroscopy TechniquesCopper-based nanomaterials and applicationsX-ray Diffraction in Crystallography

Optically Active Diarylethenes for Multimode Photoswitching Between Liquid-Crystalline Phases

Chagit Denekamp、Ben L. Feringa1998-10-01Advanced Materials

Multimode photoswitching between liquid-crystalline phases (nematic and isotropic) by photochromic organic molecules is reported here. The authors use optically active diarylethylenes to induce chirality in nematic liquid-crystalline (LC) phases and to obtain effective photomodulation of LC phases as well as gradual c…

Photorefractive and Nonlinear OpticsLiquid Crystal Research AdvancementsPhotochromic and Fluorescence Chemistry

Influence of particle volume fraction, shape, and aspect ratio on the behavior of particle-reinforced metal–matrix composites at high rates of strain

Yulong Li、K.T. Ramesh1998-10-01Acta Materialia

Compressive plastic deformation of particle-reinforced metal–matrix composites is investigated through numerical modeling at high rates of strain. The numerical modeling is performed using axisymmetric unit cell models, with the particles treated as elastic ellipsoids or cylinders embedded within a viscoplastic matrix…

Microstructure and mechanical propertiesHigh-Velocity Impact and Material BehaviorAluminum Alloys Composites Properties

Raman spectroscopy study of the ferrielectric-paraelectric transition in layeredCuInP2S6

Yu. M. Vysochanskiǐ、V. A. Stephanovich、A. A. Molnar 等 5 位作者1998-10-01Physical review. B, Condensed matter

The dynamics of the ferrielectric-paraelectric transition in lamellar ${\mathrm{CuInP}}_{2}{\mathrm{S}}_{6}$ is studied using Raman scattering. Band assignments for this system are established by comparison with published vibrational spectroscopy information on related chalcogenophosphates as well as with new data on…

Solid-state spectroscopy and crystallographyChalcogenide Semiconductor Thin FilmsCrystal Structures and Properties

Engineered Alignment in Media Equivalents: Magnetic Prealignment and Mandrel Compaction

Victor H. Barocas、T. S. Girton、Robert T. Tranquillo1998-10-01Journal of Biomechanical Engineering

We predicted and measured the evolution of smooth muscle cell (SMC) orientation in media-equivalents (MEs) for four fabrication conditions (F-, M-, F+, M+) under Free or Mandrel compaction (F/M) with and without magnetic prealignment of the collagen fibrils in the circumferential direction (+/-). Mandrel compaction re…

Advanced machining processes and optimizationCollagen: Extraction and CharacterizationCellular Mechanics and Interactions

Finite temperature dynamics of vortices in the two dimensional anisotropic Heisenberg model

Till Kamppeter、Franz G. Mertens、Angel Sanchez 等 6 位作者1998-10-01arXiv

We study the effects of finite temperature on the dynamics of non-planar vortices in the classical, two-dimensional anisotropic Heisenberg model with XY- or easy-plane symmetry. To this end, we analyze a generalized Landau-Lifshitz equation including additive white noise and Gilbert damping. Using a collective variabl…

Materials Sciencepatt-solnlin.PScond-mat.stat-mech

Evaporation and Step Edge Diffusion in MBE

S. Schinzer、M. Sokolowski、M. Biehl 等 4 位作者1998-10-01arXiv

Using kinetic Monte-Carlo simulations of a Solid-on-Solid model we investigate the influence of step edge diffusion (SED) and evaporation on Molecular Beam Epitaxy (MBE). Based on these investigations we propose two strategies to optimize MBE-growth. The strategies are applicable in different growth regimes: during la…

Materials Science

REGULATION OF ACETATE METABOLISM BY PROTEIN PHOSPHORYLATION IN ENTERIC BACTERIA

Alain J. Cozzone1998-10-01Annual Review of Microbiology

Growth of enteric bacteria on acetate as the sole source of carbon and energy requires operation of a particular anaplerotic pathway known as the glyoxylate bypass. In this pathway, two specific enzymes, isocitrate lyase and malate synthase, are activated to divert isocitrate from the tricarboxylic acid cycle and prev…

Enzyme Structure and FunctionBacterial Genetics and BiotechnologyAmino Acid Enzymes and Metabolism