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MCM-41 and Na–magadiite silicates internal voids probed by pyrene fluorescence spectroscopy

D.M. Sena、Heloise O. Pastore、Francisco Benedito Teixeira Pessine2009-01-01Physical Chemistry Chemical Physics

Investigation of the properties of two different silicate materials, namely MCM-41, with one-dimensional, cylindrical pores (4.04 nm diameter), and Na-magadiite, with a bidimensional, layered structure (1.67 nm between layers) was carried out. These materials may be used as sorbents, and their polarity is determinativ…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisClay minerals and soil interactions

A study on isothermal kinetics of glassy Sb9.1 Te20.1 Se70.8 alloy

A.A. Joraid、A.A. Abu-Sehly、S.N. Alamri2009-01-01Journal of Taibah University for Science

In this research, the activation energy of amorphous Sb9.1 Te20.1 Se70.8 crystallization was studied under isothermal conditions using a differential scanning calorimetric (DSC) technique. The activation energy for Sb9.1 Te20.1 Se70.8 crystallization was determined to be 124 ± 4 kJ mol-1. The Avrami exponent was obser…

Phase-change materials and chalcogenidesThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure

Machinability of Copper Sulfide-Dispersed Lead-Free Bronze

Hidekazu Sueyoshi、K. Inoue、Yuki Yamano 等 5 位作者2009-01-01MATERIALS TRANSACTIONS

Molybdenum sulfide (MoS2) was added to molten bronze consisting of Cu and Sn. Then, the machinability of the obtained bronze was examined from the viewpoints of cutting force, chip disposability and finished surface roughness. Copper sulfide (Cu2S)-dispersed bronze is produced by adding MoS2 to molten bronze. The disp…

Aluminum Alloy Microstructure PropertiesAluminum Alloys Composites PropertiesMetallurgy and Material Science

Mechanical Properties of Spheroidal Graphite Cast Iron Made by Reduced Pressure Frozen Mold Casting Process

Kazumichi Shimizu、Xinba Yaer、Masahito Tanaka 等 4 位作者2009-01-01MATERIALS TRANSACTIONS

The reduced pressure frozen mold casting process has been known as a recycling-based casting method with several advantages, such as improvement of the work environment, reduction of industrial waste and significant improvement of product yield. In this method, only water and silica sand were used to make mold, which…

Additive Manufacturing and 3D Printing TechnologiesMetallurgy and Material FormingMetal Alloys Wear and Properties

Structural Changes in Polyaniline upon Reaction with DPPH

Chyong Fang Hsu、Hui HPeng、Lijuan Zhang 等 5 位作者2009-01-01e-Journal of Surface Science and Nanotechnology

Polyaniline (PANI) powder was prepared using ammonium persulfate (APS) as the oxidant with an APS to aniline (ANI) ratio of 1.5. The powder was then reduced by hydrazine or dedoped using an aqueous ammonium solution. The antioxidant properties of these polymers were investigated through their reaction with the stable…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

Comparative study of the structures of Fe-Mn-Si-Cr-Ni shape memory alloys obtained by classical and by powder metallurgy, respectively

Leandru-Gheorghe Bujoreanu、Sergiu Stanciu、Burak Özkal 等 5 位作者2009-01-01ESOMAT 2009 - 8th European Symposium on Martensitic Transformations

Hot rolled specimens of low-manganese Fe-Mn-Si-Cr-Ni shape memory alloys, produced by classical and by powder metallurgy (CM and PM) with mechanical alloying, respectively, were analysed by tensile loadingunloading tests (TENS), by dilatometry (DIL), by X-ray diffraction (XRD) and scanning electron microscopy (SEM). S…

Metallic Glasses and Amorphous AlloysShape Memory Alloy TransformationsAdvanced materials and composites

Cell shrinkage of Isochrysis galbana (Prymneshiophyceae) during storage with preservatives

K. Iwasawa、Ai Murata、Satoru Taguchi2009-01-01Plankton and Benthos Research

Cell volume of Isochrysis galbana (Prymneshiophyceae) was determined with a microscope before and after fixation during storage at 4 and 25°C. The shrinkage effect at 4°C was not detectable but at 25°C. It was described by the exponential equation; Y=0.797+0.224 exp (−0.074 X) for 2% formaldehyde and Y=0.849+0.150 exp…

Algal biology and biofuel productionDiatoms and Algae ResearchBiocrusts and Microbial Ecology

Effect of plastic slip on thermomechanical behavior of NiTi polycrystals investigated by micromechanics modelling

V. Novák、Petr Šittner、Ján Pilch 等 4 位作者2009-01-01ESOMAT 2009 - 8th European Symposium on Martensitic Transformations

Earlier developed micromechanics crystallographic model of SMA polycrystals has been modified by incorporating plastic deformation as additional deformation mechanism. It is assumed that dislocation slip proceeds in austenite and B19' martensite phases in parallel with the processes derived from B2-B19'martensitic tra…

Metal and Thin Film MechanicsShape Memory Alloy TransformationsIntermetallics and Advanced Alloy Properties

Surface chemistry and reactivity of skin-passed hot dip galvanized coating

Jean-Michel Mataigne、Véronique Vaché、M. Repoux2009-01-01Revue de Métallurgie

GI coatings are covered by a very thin aluminum layer that precipitates after wiping. Anisotropic growing of zinc crystals during solidification induces a strong basal texture in GI coatings. Skin-pass induced changes in GI coating surface chemistry, crystallography and reactivity have been assessed. Local coating ana…

Mechanical Behavior of CompositesCorrosion Behavior and InhibitionMaterial Properties and Processing

Effect of Surface Treatment on the Hot Forming of the High Strength Ti-6Al-4V Fastener

Jeoung Han Kim、Chae Hoon Lee、Jae‐Keun Hong 等 5 位作者2009-01-01MATERIALS TRANSACTIONS

The Ti-6Al-4V alloy is a very attractive material for the fastener bolt of an aircraft because of its excellent combination of specific strength and corrosion resistance. However, poor workability and severe galling between work-piece and die material make it difficult to produce. The aim of the present work is to enh…

Metallurgy and Material FormingTitanium Alloys Microstructure and PropertiesMetal Alloys Wear and Properties

DYNAMIC-TENSILE-EXTRUSION RESPONSE OF FLUOROPOLYMERS

Eric Brown、C. P. Trujillo、G.T. Gray 等 8 位作者2009-01-01AIP conference proceedings

The current work applies the recently developed Dynamic-Tensile-Extrusion (Dyn-Ten-Ext) technique to polytetrafluoroethylene (PTFE) and polychlorotrifluoroethylene (PCTFE). Similar to the Taylor Impact Rod, Dynamic-Tensile-Extrusion is a strongly integrated test, probing a wide range of strain rates and stress states.…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesFiber-reinforced polymer composites

Ferroelectric Relaxor Behavior of Ba(Ti0.91Zr0.09)O3 Ceramics

Luan Dao-cheng、Ding Shihua、Tao Chen 等 4 位作者2009-01-01Ferroelectrics

Ba (Ti0.91Zr0.09) O3 ceramics doped with Bi2O3 and Li2O respectively were prepared by a solid phase reaction. The effect of A-site donor-acceptor doped on dielectric properties was investigated. Dielectric properties were measured from −30°C to 130°C at different frequencies. Relaxor behavior was observed with increas…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisDielectric properties of ceramics

SiC nanoparticles as potential carriers for biologically active substances

Ibeth Guevara-Lora、Cezary Czosnek、Aleksandra Smycz 等 5 位作者2009-01-01Journal of Physics Conference Series

Silicon carbide SiC thanks to its many advantageous properties has found numerous applications in diverse areas of technology. In this regard, its nanosized forms often with novel properties have been the subject of intense research in recent years. The aim of this study was to investigate the binding of biologically…

Nanoparticles: synthesis and applicationsSemiconductor materials and devicesGraphene and Nanomaterials Applications

Regularities of photostimulated conversions in nanometer aluminum layers

Э. П. Суровой、Н. В. Борисова2009-01-01Russian Journal of Physical Chemistry A

The gravimetric and optical spectroscopic methods reveals that light irradiation with λ = 300–750 nm and intensity I = 6.9 × 10 14 –1.1 × 10 16 quanta cm −2 s −1 for τ = 1–160 min in atmospheric conditions significantly changes the absorption and reflection spectra and mass of aluminum films ( d = 2–200 nm). The kinet…

Nanowire Synthesis and ApplicationsOptical Coatings and GratingsElectron and X-Ray Spectroscopy Techniques

Characterization of calcium phosphate deposited on valve metal by anodic oxidation with polarity inversion

Seigo Okawa、Kikuo Homma、Mitsugu Kanatani 等 4 位作者2009-01-01Dental Materials Journal

Electrochemical deposition of calcium phosphate (CAP) on valve metals such as Ta, Nb, and Zr, was performed by anodic oxidation with alternate polarity inversion at an applied 20 VDC. A saturated hydroxyapatite(HAP)-phosphoric acid solution (pH 3) was used as the electrolyte. FTIR, XRD, and XPS were employed to invest…

Bone Tissue Engineering MaterialsCorrosion Behavior and InhibitionAnodic Oxide Films and Nanostructures

Stresses induced in polymer crystals by the atomic-molecular internal dynamics

V. I. Vettegren、A. I. Slutsker、В. Б. Кулик2009-01-01Physics of the Solid State

The temperature dependences of the dynamic tensile stresses on the chemical bonds of the skeleton of chain molecules and the bonds between molecules in poly(ethylene) and polyamide 6 crystals are measured using X-ray diffraction and Raman spectroscopy in the temperature range 5–500 K. The relations of the dynamic stre…

Carbon Nanotubes in CompositesPolymer crystallization and propertiesMaterial Properties and Applications

Temperature-Sensitive Biodegradable Poly(ethylene glycol)

Jisun Lee、Min Kyung Joo、Jinheung Kim 等 6 位作者2009-01-01Journal of Biomaterials Science Polymer Edition

We report here that the incorporation of several disulfide bonds along poly(ethylene glycol) (PEG) gives temperature sensitivity, as well as biodegradability to PEG. To synthesize a PEG with temperature sensitivity in a physiologically important range (20-40 degrees C), PEGs with molecular masses of 400 and 600 Da wer…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesPolymer Surface Interaction Studies

Method of Evaluating Anomalous Eddy Current Loss in Electrical Steel Sheets

Chikara Kaido2009-01-01Journal of the Magnetics Society of Japan

This paper discusses the anomalous eddy current caused by magnetic domain wall movement. The anomalous eddy current due to the change of flux space harmonics distribution generated by domain wall movement is generally not affected by steel thickness, but by crystalline grain size. Then, if magnetic flux is concentrate…

Microstructure and Mechanical Properties of SteelsMagnetic Properties and ApplicationsNon-Destructive Testing Techniques

Enhancement factor, electrostatic force and emission current in a nanoneedle emitter

Evgeny G. Pogorelov、A. I. Zhbanov、Yia‐Chung Chang2009-01-01Europhysics Letters (EPL)

We consider field emission from carbon nanotubes and other elongated nanostructures. An exact solution for the electrostatic field between a metallic hemi-ellipsoidal needle on a plate (as a cathode) and a flat anode are presented. The basic idea is to replace the cathode by a linearly charged thread in a uniform elec…

Carbon Nanotubes in CompositesNanowire Synthesis and ApplicationsNeuroscience and Neural Engineering

Decolorization of Reactive Brilliant Red K-2BP in Aqueous Solution by Using Hydrodynamic Cavitation

Xikui Wang、Shuyong Zhang、Shuping Li2009-01-01Environmental Engineering Science

Decolorization of a dye reactive brilliant red K-2BP in aqueous solution by using hydrodynamic cavitation was investigated. Effects of operating parameters such as pressure, temperature, initial concentration of the dye, medium pH, and H2O2 addition on the decolorization of reactive brilliant red K-2BP were also discu…

Advanced oxidation water treatmentUltrasound and Cavitation PhenomenaEnvironmental remediation with nanomaterials