Materials Literature
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An accurate full-potential linear augmented plane waves method has been used to investigate the structural stability, half-metallic ferromagnetism of the zinc-blende phase of the ferromagnetic semiconductor alloy ${\text{Al}}_{1\ensuremath{-}x}{\text{Cr}}_{x}\text{As}$. The relative stability of the zinc-blende phase…
Abstract In this study, biodegradable blend of Poly (Ethylene‐ co ‐Vinyl Acetate) (EVA) and Ethyl Cellulose (EC) were prepared. Ethylene vinyl alcohol (EVOH) copolymer was used as an interfacial compatibilizer to enhance adhesion between EVA and EC. The melt blended compatibilized biocomposites were examined for mecha…
Abstract An effective solution mixing method starting from a synthesis solution of SiO 2 nanoparticles was developed for dispersing nanoparticles into high‐density polyethylene (HDPE). Spherical SiO 2 nanoparticles with narrow size distribution (50–100 nm) were prepared by Stöber method, and solvents of the synthesis…
Photoexcited dynamics of a spin-density-wave (SDW) state in an organic linear-chain compound bis-(tetramethyl-tetraselenafulvalene)hexafluorophosphate, ${(\text{TMTSF})}_{2}{\text{PF}}_{6}$, is investigated by optical pump and terahertz probe experiments. After the ultrashort laser-pulse excitation, a sudden closing f…
Abstract A number of series of poly(acrylic acids) (PAA) of differing end‐groups and molecular weights prepared using atom transfer radical polymerization were used as inhibitors for the crystallization of calcium oxalate at 23 and 80°C. As measured by turbidimetry and conductivity and as expected from previous report…
Abstract A number of organosilicon precursors for silicon carbide and silicon carbonitride thin‐film coatings, such as silanes, carbosilanes, aminosilanes, and disilazane, respectively, were characterized in terms of their reactivity in a remote microwave plasma chemical vapor deposition process, which was induced usi…
A facile and easily reproducible technique for assembling biohybrid nanoparticles is a core feature that is highly desired for biomedical applications, considering the nature and limited lifespan of the biopolymers used. Here we show a simple and effective method to enfold single-walled carbon nanotubes (SWNTs) using…
We report eight new A(2)B-type (M(n+)) corrolate compounds (two structural studies) that include the oxo[5,15-bis(pentafluorophenyl)-10-R-corrolatochromium(V)] [R = 2-/3-thienyl (1a/2a), 3-thianaphthyl (3a)] species. The first examples of meso-A(2) (thienyl)- and Cr-A(2)B-corrole types are represented herein. Characte…
Abstract The low‐temperature physical aging of amorphous poly( L ‐lactide) (PLLA) at 25–50°C below glass transition temperature ( T g ) was carried out for 90 days. The physical aging significantly increased the T g and glass transition enthalpy, but did not cause crystallization, regardless of aging temperature. The…
Abstract The effect of nanoclay on the morphology and properties of poly(methyl methacrylate) (PMMA)/high‐density polyethylene (HDPE) blends was studied. A scanning electron microscopy study of the PMMA/HDPE (70/30 w/w) blends with nanoclay indicated a reduction in the average domain sizes of the dispersed HDPE phase…
The ability to create structurally complex, accurate micropatterns in biocompatible and biodegradable nanofiber mats is important in maximally mimicking the natural extracellular matrix (ECM) for cell biology and tissue engineering. We present a simple, versatile method for the selective deposition of nanofibers with…
Abstract Glycerol is one of the most versatile and valuable chemical substances and is utilized in a variety of commercial products with no known adverse pharmacological or environmental effects. Moreover, it exhibits good chemical stability and inertness under biological conditions. We have designed and developed Can…
Incommensurate satellite reflections modulating along the 〈110〉* directions have been observed in the electron diffraction patterns of single crystals of the relaxor ferroelectric Pb 2 ScTaO 6 (PST) recorded via transmission electron microscopy. The satellites occur characteristically within a specific temperature ran…
Four chromophores containing bromo substituents, a ployimide with bromo-containing chromophores, four reference functional polyimides, and fourteen reference chromophores were synthesized for studying effect of bromo substituents on nonlinear optical (NLO) properties of materials and chromophores. The results of hyper…
Increasing evidence suggests that culturing cancer cells in three dimensions more accurately recapitulates the complexity of tumor biology. Many of these models utilize reconstituted basement membrane derived from animals which contain a variable amount of growth factors and cytokines that can influence the growth of…
The formation and decomposition of a layered structure of ammonium fluorolanthate during the preparation of Ce 3+ -doped sodium yttrium fluoride nanomaterials are investigated by XRD, TGA, TEM, FTIR, and photoluminescence spectroscopy. The influences of sonication and temperature of heating on the structural changes,…
Interactions between vascular endothelial cells (EC) and materials are central to biomedical applications such as vascular graft endothelialization or vascularization of an engineered tissue substitute. To improve implant success, biomaterial surfaces are designed to modulate EC adhesion and responses. In vivo, EC lin…
The first synthesis of a triphenylmethine (TM) library of compounds and screening of their Surface Enhanced Raman Scattering (SERS) capability was carried out to identify novel Raman reporters with high sensitivity. We identified three novel SERS reporters (B2, B7, and C7) with higher signal intensity than that of com…
We report on the formation of complexes between zwitterionic phospholipid vesicles and an anionic fluorescent conjugated polyelectrolyte and the effect of mono- and divalent cations on the photophysical properties of these complexes. Our goal is to gain an understanding of the interplay of morphology and exciton trans…
The control over 10 nm scale porosity derived from self-assembly of copolymers is an extremely promising method for the synthesis of organic–inorganic hybrid materials applied, for example, in solar cells. Here, we report the thin film behaviour of a poly(4-fluorostyrene)-b-poly(D,L-lactide) PFS-b-PLA block copolymer…