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Understanding of metal-insulator transition in VO2 based on experimental and theoretical investigations of magnetic features

Renyan Zhang、Qingshan Fu、Chih-Kai Yin 等 10 位作者2018-11-14Scientific Reports

Abstract The metal-insulator transition temperature T c in VO 2 is experimentally shown to be almost the same as a magnetic transition temperature T m characterized by an abrupt decrease in susceptibility, suggesting the evidence of the same underlying origin for both transitions. The measurement of susceptibility sho…

Advanced Memory and Neural ComputingTransition Metal Oxide NanomaterialsGa2O3 and related materials

Mechanically Assembled, Three-Dimensional Hierarchical Structures of Cellular Graphene with Programmed Geometries and Outstanding Electromechanical Properties

Yun Ling、Xiatian Zhuang、Zheng Xu 等 10 位作者2018-11-14ACS Nano

Three-dimensional (3D) cellular graphene structures have wide applications in energy storage, catalysis, polymer composites, electromagnetic shielding, and many others. However, the current strategies to form cellular graphene are only able to realize limited structure control and are hard to achieve the construction…

Graphene research and applicationsSupercapacitor Materials and FabricationMXene and MAX Phase Materials

Practical and Theoretical Study on the Inhibitory Influences of New Azomethine Derivatives Containing an 8-Hydroxyquinoline Moiety for the Corrosion of Carbon Steel in 1 M HCl

A. El-Yaktini、A. Lachiri、M. Elfaydy 等 10 位作者2018-11-14Oriental Journal Of Chemistry

The inhibition ability of a new Azomethine derivatives containing the 8-hydroxyquinoline (BDHQ and MDHQ) towards carbon steel corrosion in HCl solution was studied at various concentrations and temperatures using weight loss, polarization curves and electrochemical impedance spectroscopy (EIS) methods. The experimenta…

Corrosion Behavior and InhibitionInorganic and Organometallic ChemistryConcrete Corrosion and Durability

Modification, hybridization and applications of saponite: An overview

Chun Hui Zhou、Qian Zhou、Qi Qi Wu 等 8 位作者2018-11-14Applied Clay Science

Modification of saponite (Sap) by surface engineering and intercalation chemistry introduces guest species into the structure of Sap and enhances the functionalities of the resultant Sap-based hybrids or composites. This review summarizes and evaluates latest scientific advances in the strategies for surface engineeri…

Polymer Nanocomposites and PropertiesMesoporous Materials and CatalysisClay minerals and soil interactions

Mobility Deception in Nanoscale Transistors: An Untold Contact Story

Joseph R. Nasr、Daniel S. Schulman、Amritanand Sebastian 等 5 位作者2018-11-14Advanced Materials

Abstract Mobility is a critical parameter that is routinely used for benchmarking the performance of field‐effect transistors (FETs) based on novel nanomaterials. In fact, mobility values are often used to champion nanomaterials since high‐performance devices necessitate high mobility values. The current belief is tha…

2D Materials and ApplicationsAdvanced Memory and Neural ComputingFerroelectric and Negative Capacitance Devices

Electrical Conductivity Modeling of Graphene-based Conductor Materials

Leo Rizzi、Andreas Zienert、Jörg Schuster 等 5 位作者2018-11-14ACS Applied Materials & Interfaces

Graphene-based conductors such as films and fibers aim to transfer graphene's extraordinary properties to the macroscopic scale. They show great potential for large-scale applications, but there is a lack of theoretical models to describe their electrical characteristics. We present a network simulation method to mode…

Advancements in Battery MaterialsCarbon Nanotubes in CompositesGraphene research and applications

Binary Thermal Encoding by Energy Shielding and Harvesting Units

Run Hu、Shiyao Huang、Meng Wang 等 6 位作者2018-11-14Physical Review Applied

Optical and thermal metamaterial-based structures have been extensively explored, yielding many interesting functionalities; in what other ways can they be used? This study, following the basic rules of transformation optics (here thermotics), demonstrates another application: thermal encoding, based on binary states…

Metamaterials and Metasurfaces ApplicationsPhase-change materials and chalcogenidesThermal Radiation and Cooling Technologies

Impact of Silanization on the Structure, Dispersion Properties, and Biodegradability of Nanocellulose as a Nanocomposite Filler

Benjamin Frank、David P. Durkin、Emily R. Caudill 等 8 位作者2018-11-14ACS Applied Nano Materials

For nanocellulose to function effectively as a nanofiller in polymers, its interfacial properties are often modified to enhance the dispersion of nanocellulose in the polymer matrix. However, the effect of different surface modification strategies on the persistence of nanocellulose in the environment is unclear. In t…

Advanced Cellulose Research Studiesbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications

Multifunctional La0.67Sr0.33MnO3 (LSMO) Thin Films Integrated on Mica Substrates toward Flexible Spintronics and Electronics

Jijie Huang、Han Wang、Han Wang 等 7 位作者2018-11-14ACS Applied Materials & Interfaces

Integrating oxide thin films on flexible substrates is a critical step toward future applications of multifunctional oxides for flexible electronics and spintronic devices. As a demonstration, multifunctional La 0.67 Sr 0.33 MnO 3 (LSMO) thin films have been deposited on flexible mica substrates. The crystallinity and…

ZnO doping and propertiesMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Direct Decomposition of NOx over TiO2 Supported Transition Metal Oxides at Low Temperatures

Devaiah Damma、Thirupathi Boningari、Padmanabha Reddy Ettireddy 等 5 位作者2018-11-14Industrial & Engineering Chemistry Research

TiO 2 supported transition metal oxides were investigated for the direct decomposition of nitrogen oxides (NO x ) at lower temperatures. The results showed that the catalytic performance strongly depends on the kind of transition metal oxide deposited on the TiO 2 . Among the various catalysts examined, Mn/TiO 2 and C…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsIndustrial Gas Emission Control

Phase stability and weak metallic bonding within ternary‐layered borides CrAlB, Cr 2 AlB 2 , Cr 3 AlB 4 , and Cr 4 AlB 6

Yuelei Bai、Xinxin Qi、Xiaodong He 等 8 位作者2018-11-14Journal of the American Ceramic Society

Abstract To explore the potential for use of the Cr–Al–B borides, Cr 2 AlB 2 , Cr 3 AlB 4 , and Cr 4 AlB 6 as well as hypothetical CrAlB are investigated using density functional theory. In the CrAl(CrB 2 ) n series strong covalent bonding is present between the B and Cr atoms with, significantly, much weaker metallic…

Aluminum Alloys Composites PropertiesBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials

Redox‐Mediator‐Enhanced Electrochemical Capacitors: Recent Advances and Future Perspectives

Lintong Hu、Tianyou Zhai、Huiqiao Li 等 4 位作者2018-11-14ChemSusChem

Supercapacitors deliver exceptional power densities, high cycling stability, and inherent safety but suffer from low energy densities. Many methods to enhance the energy density are based on exploring electrode materials with well-developed structures and designing asymmetric systems with wide voltage windows. The ene…

Supercapacitor Materials and FabricationConducting polymers and applicationsAdvanced battery technologies research

Recyclable Dielectric Polymer Nanocomposites with Voltage Stabilizer Interface: Toward New Generation of High Voltage Direct Current Cable Insulation

Yahan Gao、Xingyi Huang、Daomin Min 等 5 位作者2018-11-14ACS Sustainable Chemistry & Engineering

Long-distance and large-capacity transmission systems have been strongly demanded in modern society, which requires the development of high voltage direct current (HVDC) cables. However, the currently used cross-linked polyethylene (XLPE) insulated cables not only cannot fulfill the environmental sustainability but al…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationDielectric materials and actuators

Nanogel Functionalization: A Versatile Approach To Meet the Challenges of Drug and Gene Delivery

Emanuele Mauri、Giuseppe Perale、Filippo Rossi2018-11-14ACS Applied Nano Materials

The design of nanostructures carrying therapeutic molecules represents the new frontier in the biological and medical fields. In particular, researchers have identified nanogels as promising tools in response to the critical issues of intracellular delivery: because of their peculiar properties, including swelling beh…

Nanoparticle-Based Drug DeliveryRNA Interference and Gene DeliveryPolymer Surface Interaction Studies

Near-infrared chiral plasmonic metasurface absorbers

Leixin Ouyang、Wei Wang、Daniel Rosenmann 等 6 位作者2018-11-14Optics Express

Chirality plays an essential role in the fields of biology, medicine and physics. However, natural materials exhibit very weak chiroptical response. In this paper, near-infrared chiral plasmonic metasurface absorbers are demonstrated to selectively absorb either the left-handed or right-handed circularly polarized lig…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchAdvanced Antenna and Metasurface Technologies

Epoxy‐Based Nanocomposites for High‐Voltage Insulation: A Review

Mohammed Mostafa Adnan、Erlend Grytli Tveten、Julia Glaum 等 7 位作者2018-11-14Advanced Electronic Materials

Abstract Epoxy nanocomposites, with inorganic oxide nanoparticles as filler, can exhibit novel property combinations, such as enhanced mechanical strength, higher thermal conductivity, increased dielectric breakdown strength, and reduced complex permittivity. Therefore, they have interesting applications in nanodielec…

High voltage insulation and dielectric phenomenaElectromagnetic wave absorption materialsDielectric materials and actuators

Biomimetic Bottlebrush Polymer Coatings for Fabrication of Ultralow Fouling Surfaces

Yinqiang Xia、Vahid Adibnia、Renliang Huang 等 13 位作者2018-11-14Angewandte Chemie International Edition

Abstract Demand for long‐lasting antifouling surfaces has steered the development of accessible, novel, biocompatible and environmentally friendly materials. Inspired by lubricin (LUB), a component of mammalian synovial fluid with excellent antifouling properties, three block polymers offering stability, efficacy, and…

Bone Tissue Engineering MaterialsSurface Modification and SuperhydrophobicityPolymer Surface Interaction Studies

Amorphous Vanadium Oxide Thin Films as Stable Performing Cathodes of Lithium and Sodium-Ion Batteries

Shaikshavali Petnikota、Rodney Chua、Yang Zhou 等 5 位作者2018-11-14Nanoscale Research Letters

Herein, we report additive- and binder-free pristine amorphous vanadium oxide (a-VOx) for Li- and Na-ion battery application. Thin films of a-VOx with a thickness of about 650 nm are grown onto stainless steel substrate from crystalline V2O5 target using pulsed laser deposition (PLD) technique. Under varying oxygen pa…

Advancements in Battery MaterialsZnO doping and propertiesTransition Metal Oxide Nanomaterials

Single shot time-resolved magnetic x-ray absorption at a Free Electron Laser

Emmanuelle Jal、Mikako Makita、Benedikt Rösner 等 21 位作者2018-11-14arXiv

Ultrafast dynamics are generally investigated using stroboscopic pump-probe measurements, which characterize the sample properties for a single, specific time delay. These measurements are then repeated for a series of discrete time delays to reconstruct the overall time trace of the process. As a consequence, this ap…

Materials Science

High Reversibility of Lattice Oxygen Redox in Na-ion and Li-ion Batteries Quantified by Direct Bulk Probes of both Anionic and Cationic Redox Reactions

Kehua Dai、Jinpeng Wu、Zengqing Zhuo 等 20 位作者2018-11-14arXiv

The reversibility and cyclability of anionic redox in battery electrodes hold the key to its practical employments. Here, through mapping of resonant inelastic X-ray scattering (mRIXS), we have independently quantified the evolving redox states of both cations and anions in Na2/3Mg1/3Mn2/3O2. The bulk-Mn redox emerges…

Materials ScienceApplied PhysicsChemical Physics