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Negative capacitance or inductive loop? – A general assessment of a common low frequency impedance feature

Dino Klotz2018-11-27Electrochemistry Communications

Impedance analysis is not an easy task. This becomes even more obvious if unusual shapes appear in the impedance diagram. Here, a low frequency hook with positive imaginary part is discussed that often leaves researchers clueless of how to handle it, especially if there is no common model for the device under test tha…

Conducting polymers and applicationsElectrochemical Analysis and ApplicationsAnalytical Chemistry and Sensors

Density Functional Theory Calculations of Oxygen Vacancy Formation and Subsequent Molecular Adsorption on Oxide Surfaces

Yoyo Hinuma、Takashi Toyao、Takashi Kamachi 等 8 位作者2018-11-27The Journal of Physical Chemistry C

Abstract The surface oxygen vacancy formation energy (EOvac) is an important parameter in determining the catalytic activity of metal oxides. Estimating these energies can therefore lead to data-driven design of promising catalyst candidates. In the present study, we determine EOvac for various insulating and semicond…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsMachine Learning in Materials Science

Impact of Nanoparticles on Brain Health: An Up to Date Overview

Daniel Mihai Teleanu、Cristina Chircov、Alexandru Mihai Grumezescu 等 5 位作者2018-11-27Journal of Clinical Medicine

Nanoparticles are zero-dimensional nanomaterials and, based on their nature, they can be categorized into organic, inorganic, and composites nanoparticles. Due to their unique physical and chemical properties, nanoparticles are extensively used in a variety of fields, including medicine, pharmaceutics, and food indust…

Nanoparticle-Based Drug DeliveryNanoparticles: synthesis and applicationsGraphene and Nanomaterials Applications

Pillared MXene with Ultralarge Interlayer Spacing as a Stable Matrix for High Performance Sodium Metal Anodes

Xinyong Tao、Chuanlong Wang、Huan Wang 等 9 位作者2018-11-27Advanced Functional Materials

Abstract Sodium (Na) metal is a promising alternative to lithium metal as an anode material for the next‐generation energy storage systems due to its high theoretical capacity, low cost, and natural abundance. However, dendritic/mossy Na growth caused by uncontrollable plating/stripping results in serious safe concern…

Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesMXene and MAX Phase Materials

Recyclable and Malleable Epoxy Thermoset Bearing Aromatic Imine Bonds

Shou Zhao、Mahdi M. Abu‐Omar2018-11-27Macromolecules

A method for preparing reprocessable epoxy thermoset is presented. The process is composed of synthesis of a bisphenol monomer bridged by an imine bond, glycidylation of the bisphenol, and cross-linking with a hardener to form thermoset. The resulting epoxy thermoset possesses comparable properties to conventional hig…

Polymer composites and self-healingEpoxy Resin Curing ProcessesCarbon dioxide utilization in catalysis

Zn‐Ion Hybrid Micro‐Supercapacitors with Ultrahigh Areal Energy Density and Long‐Term Durability

Panpan Zhang、Yang Li、Gang Wang 等 9 位作者2018-11-27Advanced Materials

Abstract On‐chip micro‐supercapacitors (MSCs), as promising power candidates for microdevices, typically exhibit high power density, large charge/discharge rates, and long cycling lifetimes. However, as for most reported MSCs, the unsatisfactory areal energy density (<10 µWh cm −2 ) still hinders their practical appli…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced battery technologies research

SchNetPack: A Deep Learning Toolbox For Atomistic Systems

Kristof T. Schütt、Pan Kessel、Michael Gastegger 等 6 位作者2018-11-27Journal of Chemical Theory and Computation

SchNetPack is a toolbox for the development and application of deep neural networks that predict potential energy surfaces and other quantum-chemical properties of molecules and materials. It contains basic building blocks of atomistic neural networks, manages their training, and provides simple access to common bench…

Computational Drug Discovery MethodsMachine Learning in Materials ScienceX-ray Diffraction in Crystallography

Electrospun MXene/carbon nanofibers as supercapacitor electrodes

Ariana Levitt、Mohamed Alhabeb、Christine B. Hatter 等 6 位作者2018-11-27Journal of Materials Chemistry A

MXene/carbon composite electrodes with high loadings of MXene were prepared via electrospinning. These flexible and free-standing electrodes exhibit high areal capacitance relative to pure carbon nanofibers and MXene-coated fibers and textiles.

Supercapacitor Materials and FabricationAdvanced Sensor and Energy Harvesting MaterialsMXene and MAX Phase Materials

Effect of surface carbonization on mechanical properties of LVL

Xuehua Wang、Yan Wu、Hong Chen 等 6 位作者2018-11-26BioResources

The wood veneer from Monopetalanthus species was heated under different temperatures (120 °C, 160 °C, 200 °C, and 240 °C) and then laminated as the surface of laminated veneer lumber (LVL). Bending modulus of elasticity (MOE), modulus of rupture (MOR), and impact toughness (IT) of the LVL were tested. The results show…

Wood Treatment and PropertiesNatural Fiber Reinforced CompositesLignin and Wood Chemistry

Role of HA and BG in engineering poly(ε‐caprolactone) porous scaffolds for accelerating cranial bone regeneration

Hua‐Mo Yin、Xiang Li、Peng Wang 等 8 位作者2018-11-26Journal of Biomedical Materials Research Part A

Effects of varied bioactive fillers on the biological behavior of porous polymer/inorganic composite scaffolds are lack of comprehensive comparison and remain elusive. Moreover, composite scaffolds with high porosity suffer from inferior mechanical performance. Herein, high-pressure molding and salt leaching were empl…

Bone Tissue Engineering MaterialsOrthopaedic implants and arthroplastyElectrospun Nanofibers in Biomedical Applications

Ultrahigh-Pressure Nitrogen Arcs Burning Inside Cylindrical Tubes

Fahim Abid、Kaveh Niayesh、Nina Sasaki Støa-Aanensen2018-11-26IEEE Transactions on Plasma Science

When the pressure and temperature of a fluid exceed a critical point, the fluid enters into the supercritical (SC) region. In this region, the physical properties are believed to be in favor of a good current interruption medium. This paper focuses on the arc voltage characteristics of nitrogen arcs burning inside cyl…

Diamond and Carbon-based Materials ResearchPlasma Applications and DiagnosticsVacuum and Plasma Arcs

Observation of electrochemically active Fe 3+ /Fe 4+ in LiCo 0.8 Fe 0.2 MnO 4 by in situ Mössbauer spectroscopy and X-ray absorption spectroscopy

Christoph Dräger、Florian Sigel、Ralf Witte 等 10 位作者2018-11-26Physical Chemistry Chemical Physics

LiCo0.8Fe0.2MnO4 has been investigated as an active material for the positive electrode in lithium-ion batteries (LIBs) with a discharge potential of around 5 V (vs. Li+|Li). After synthesis by a Pechini based sol-gel route, the structural and morphological properties have been investigated by X-ray diffraction, scann…

Advancements in Battery MaterialsMultiferroics and related materialsMagnetic Properties and Synthesis of Ferrites

Measuring monopole and dipole polarizability of acoustic meta-atoms

Joshua Jordaan、Stefan Punzet、Anton Melnikov 等 7 位作者2018-11-26Applied Physics Letters

We present a method to extract monopole and dipole polarizability from experimental measurements of two-dimensional acoustic meta-atoms. In contrast to extraction from numerical results, this enables all second-order effects and uncertainties in material properties to be accounted for. We apply the technique to 3D-pri…

Metamaterials and Metasurfaces ApplicationsAcoustic Wave Phenomena ResearchAerodynamics and Acoustics in Jet Flows

Physiological Studies of Chlorobiaceae Suggest that Bacillithiol Derivatives Are the Most Widespread Thiols in Bacteria

Jennifer Hiras、Sunil V. Sharma、Vidhyavathi Raman 等 9 位作者2018-11-26mBio

Low-molecular-weight thiols are key metabolites that participate in many basic cellular processes: central metabolism, detoxification, and oxidative stress resistance. Here we describe a new thiol, N-methyl-bacillithiol, found in an anaerobic phototrophic bacterium and identify a gene that is responsible for its synth…

Metabolomics and Mass Spectrometry StudiesEnzyme Structure and FunctionMicrobial Community Ecology and Physiology

Isovalent bismuth ion-induced growth of highly-disperse Sb 2 S 3 nanorods and their composite with p -CuSCN for self-powered photodetectors

Junli Wang、Yajie Qiao、Tingting Wang 等 6 位作者2018-11-26CrystEngComm

Trace amounts of Bi ions are able to cause the growth of highly-disperse, thin Sb 2 S 3 nanorods, which exhibit potential in UV-visible self-powered photodetectors when coupled with p -CuSCN crystal clusters.

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Laser-induced forward transfer from healing silver paste films

Emre Turkoz、M. Morales、SeungYeon Kang 等 7 位作者2018-11-26Applied Physics Letters

Laser-induced forward transfer (LIFT) is a nozzle-less printing technique where a controlled amount of material is transferred from a thin film to a receiver substrate with each laser pulse. Conventionally, each laser pulse is directed to a different spot on the donor ink film as the donor substrate is moved together…

Surface Modification and SuperhydrophobicityLaser Material Processing TechniquesElectrohydrodynamics and Fluid Dynamics

Thermally Induced Fullerene Domain Coarsening Process in Organic Solar Cells

Antonio Agresti、Sara Pescetelli、Yan Busby 等 4 位作者2018-11-26IEEE Transactions on Electron Devices

The recent advancements in power conversion efficiency for organic solar cells is still complained by their reliability and stability remaining the main bottlenecks for organic photovoltaics large scale production and commercialization. In this paper, we aim to provide further insights understanding in degradation pro…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

Drilling Process in γ-TiAl Intermetallic Alloys

A. Beranoagirre、Gorka Urbikaín、Amaia Calleja 等 4 位作者2018-11-26Materials

Gamma titanium aluminides (γ-TiAl) present an excellent behavior under high temperature conditions, being a feasible alternative to nickel-based superalloy components in the aeroengine sector. However, considered as a difficult to cut material, process cutting parameters require special study to guarantee component qu…

Advanced ceramic materials synthesisIntermetallics and Advanced Alloy PropertiesMXene and MAX Phase Materials

Intensity-modulated LED achieved through integrating p-GaN/n-ZnO heterojunction with multilevel RRAM

Qi Meng、Xue Zhang、Yang Liu 等 8 位作者2018-11-26Applied Physics Letters

We developed an intensity-modulated light-emitting device (LED) by integrating a p-GaN/n-ZnO heterojunction with multilevel resistive random access memory (RRAM). In this device, the luminous intensity of LED can be adjusted through regulating the injection current according to the variable resistance state of RRAM. A…

ZnO doping and propertiesSemiconductor materials and devicesAdvanced Memory and Neural Computing

Antibacterial properties of subphthalocyanine and subphthalocyanine-TiO 2 nanoparticles on Staphylococcus aureus and Escherichia coli

İsmail Öztürk、Ayça Tunçel、Mine Ince 等 6 位作者2018-11-26Journal of Porphyrins and Phthalocyanines

Nowadays the problem of antimicrobial resistance is the most important cause of morbidity and mortality in the treatment of infectious diseases worldwide. Treatment options for antimicrobial-resistant microorganisms are quite limited. Therefore, alternative treatment strategies are needed to control infectious disease…

Nanoplatforms for cancer theranosticsPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies