Materials Literature
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Noninvasive diagnostic by imaging combined with a contrast agent (CA) is by now the most used technique to get insight into human bodies. X-ray and magnetic resonance imaging (MRI) are widely used technologies providing complementary results. Nowadays, it seems clear that bimodal CAs could be an emerging approach to i…
The elastic strain of conventional metals is usually below ∼1%. As the metals' sizes decrease to approximate a few nanometers, their elastic strains can approach ∼8%, and they usually exhibit pseudoelastic strain that can be as large as ∼35%. Previous studies suggested that the pseudoelastic behaviors of nanocrystals…
In the last decade, transparent amorphous oxide semiconductors (TAOS) have become an essential component of many electronics, from ultra high resolution displays to solar cells. However, these disordered oxides typically rely on expensive component metals like indium to provide sufficient charge carrier conduction, an…
Polyimides are used in microelectronics as they possess the essential high tensile properties, high thermal stability and low dielectric constant. As the further reduction in their dielectric constant is indispensable for such applications, in this study it was loaded with the porous covalent organic framework (COF‐LZ…
A novel flame‐retardant chain extension agent (9,10‐dihydro‐9‐oxa‐10‐phosphaphenanthrene‐10‐oxide)‐3,5‐triglycidyl isocyanurate defined as DOPO‐TGIC was synthesized, and its chemical structure was well characterized and confirmed. The effect of DOPO‐TGIC as a synergistic agent on the flame retardancy, rheology, therma…
The coordination environment of titanium of the catalysts was investigated by DRUV–vis, Raman and 47/49 Ti MAS-NMR spectroscopies and solid-state electrochemical techniques.
It is demonstrated that transparent amorphous oxide semiconductors (TAOS) can be excellent thermoelectric (TE) materials, since their thermal conductivity (κ) through a randomly disordered structure is quite low, while their electrical conductivity and carrier mobility (μ) are high, compared to crystalline semiconduct…
New microporous homopolymers were readily prepared from norbornadiene-2,5, its dimer and trimer by addition (vinyl) polymerization of the corresponding monomers with 60–98% yields. As a catalyst Pd-N-heterocyclic carbene complex or Ni(II) 2-ethylhexanoate activated with Na+[B(3,5-(CF3)2C6H3)4]− or methylaluminoxane wa…
Compound samples based on the mineral-like magnesium potassium phosphate matrix MgKPO4 × 6H2O were synthesized by solidification of high level waste surrogate. Phase composition and structure of synthesized samples were studied by XRD and SEM methods. Compressive strength of the compounds is 12 ± 3 MPa. Coefficient of…
Abstract The synthesis of ZnO/SiO 2 nanocomposite doped with Co, Cu and Mn nanoparticles were performed using sol‐gel method. Rietveld refinement analysis was done for the X‐ray diffraction data and results showed that all samples are single wurtzite hexagonal phase and have an average crystallite size ~14 nm. The lat…
The low-cost, heavy metal ion (Cu(II)) adsorptive multi-structured nanofibrous membranes of silicon oxide naonoparticles in-situ anchored polyvinylidene fluoride-hexafluoropropylene (SiO₂@PVDF-HFP) fibers were fabricated by the facile electrospinning technique combined with sol⁻gel strategy. To explore the benefits of…
In the present study, porous magnesium-xzeolite (x= 0, 3, 5 and 7 wt.%) composite scaffolds containing different amounts of zeolite were synthesized through combination of powder metallurgy (PM) and space holder (SH) techniques. The findings demonstrated that incorporation of zeolite into Mg composite scaffolds leads…
Abstract Charge carrier transport in multilayer van der Waals (vdW) materials, which comprise multiple conducting layers, is well described using Thomas–Fermi charge screening (λTF) and interlayer resistance (Rint). When both effects occur in carrier transport, a channel centroid migrates along the c‐axis according to…
Abstract Development of supramolecular methods to further activate a highly reactive intermediate is a fascinating strategy to create novel potent catalysts for activation of inert chemicals. Herein, a supramolecular approach to enhance the oxidizing ability of a high‐valent oxo species of a nitrido‐bridged iron porph…
A member of the propellane family – a novel chiral compound DDDDP – that shows second harmonic generation in its crystalline form.
A novel pillared-layer Cd-MOF was synthesized as luminescent sensor for detection of nitroaromatic explosives with highly selective and recyclable properties. The study also shows that the photoinduced electron transfer and resonance energy transfer were possible mechanisms of fluorescence quenching.
Fish gelatin nanoparticle is produced using Tilapia fish skin for the first time by the twostep desolvation method.Fish gelatin is chosen for producing gelatin nanoparticles because no experiment have been done in using fish gelatin and to counter the problem associated with the use of mammalian gelatin, such as bovin…
Several studies have shown that chitosan possesses characteristics favorable for promoting dermal regeneration and accelerated wound healing. In this work we have reported the work that has been done on the development and characterization of biocompatible and biodegradable chitosan based matrices to be used as skin s…
Abstract We present an efficient methodology for the synthesis of tetrafunctionalized double‐decker silsesquioxanes via hydrosilylation reaction. An investigation of the catalytic system, olefin structure, chemical and steric surrounding of Si−H moiety in the respective reagent was carried out on the progress, selecti…
Nitrogen-doped carbon dots were synthesized via the chemical breakdown of electrospun polyacrylonitrile-based carbon nanofibers and employed as a fluorescent sensing platform.