Materials Literature
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Seeding a mixture of boehmite (AIOOH) and colloidal ZrO 2 with α‐alumina particles and sintering at 1400°C for 100 min results in 98% density. The low sintering temperature, relative to conventional powder processing, is a result of the small alumina particle size (∼0.3 μm) obtained during the θ‐to α‐alumina transform…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDoes one-electron transfer to nickel(II) porphyrins involve the metal or the porphyrin ligand?Doris Lexa, Michel Momenteau, Joel Mispelter, and Jean Michel SaveantCite this: Inorg. Chem. 1989, 28, 1, 30–35Publication Date (Print):January 1, 1989Publication History Published…
The structure of (NEt4)4S2Mo18,O62·CH3CN has been determined by the single-crystal X-ray method. The crystals are triclinic, space group P, with cell parameters a= 15.062(4), b= 23.296(4), c= 13.813(4)Å, and α= 97.66(4), β= 115.98(2), γ= 84.63(4)°, and Z= 2. The structure model was refined by full-matrix least squares…
Physicochemical and catalytic properties of heteropolyacids of the series H3 +nPVnMo12–nO40(n= 0–3), both pure and supported on the potassium salt K3PMo12O40, have been investigated. Thin acid coats formed on such a support display modified properties and enhanced thermal stability. In particular, it is postulated tha…
Cellulose fibers such as cotton, linen, viscose rayon, and polynosic fibers were treated with low temperature plasmas of O 2 , N2, H2, Ar, CO, CH4, and CF 4 . For comparison wool, silk, nylon 6, and poly ( ethylene terephthalate ) (PET) were also subjected to the plasma treatments. The relative free-radical intensity…
Conducting polypyrrole can be photochemically deposited onto any type of surface by visible light irradiation of the surface covered with a multicomponent solution (pyrrole, electron acceptor, photoactive species).
(1989). MFIT: Multiple spectra fitting program. Synchrotron Radiation News: Vol. 2, No. 1, pp. 24-26.
This paper investigates theoretically the stability of non-flow-aligning nematics in simple shear flow by analyzing the relevant continuum equations. With the aid of numerical techniques, it proves possible to predict thresholds for instability to perturbations both within and out of the shear plane, based on the full…
Abstract The isothermal crystallization kinetics, the morphology and melting behaviour of blends of poly(tetramethylene terephthalate) {poly(butylene terephthalate), (PBT)} with a thermotropic liquid‐crystalline polyester, poly(decamethylene 4,4′‐terephthaloyldioxydibenzoate) (HTH10), were studied in the composition r…
Abstract Die Dihydroazulene 1a – d werden ausgehend von Cycloheptatrienylium‐tetrafluoroborat ( 8 ) hergestellt. Zwischenverbindungen sind substituierte Cycloheptatriene 10 – 13 . Die Dicyanvinylderivate 12 bzw. 13 werden durch Dehydrogenierung in die Vinylheptafulvene 2 umgewandelt, die wiederum thermisch in 1 umlage…
The aim of the present paper is limited to a survey of part of the prolonged research activity of the Padova group in Italy on the structural and electronic properties of organic charge transfer (CT) crystals studied by optical spectroscopy methods. The presentation is given in the form of a short review, without atte…
ADVERTISEMENT RETURN TO ISSUEPREVArticleAn intrinsically photosensitive polyimideJ. A. Moore and A. N. DasheffCite this: Chem. Mater. 1989, 1, 1, 163–166Publication Date (Print):January 1, 1989Publication History Published online1 May 2002Published inissue 1 January 1989https://pubs.acs.org/doi/10.1021/cm00001a029http…
3-Alkyl substitution of the polypyrrole monomer leads to highly conductive and electroactive polymers and permits control, to a large extent, of their hydrophobic character.
The growth of crystals of NH 4 Br from a supersaturated solution is studied. We find regimes where crystals grow in form of “faceted dendrites”, i.e. with a global parabolic shape and facets close to the tip. A power law is found for the decrease of the size of the facets with velocity. We further study the evolution…
The relationships between the from of crystallites and their adsorption properties have been investigated on ZnO samples of various origins by means of electron microscopy, X-ray diffraction and adsorption calorimetry. Three polycrystalline ZnO samples have been studied: one obtained by ignition of zinc metal (Kadox)…
—Surface modification of poly(tetrafluor oethylene) (PTFE) by NH3-plasma treatment was investigated by means of contact angle measurement, XPS, and ATR FT/IR spectroscopy. The modified surfaces were adhesively bonded to nitril rubber. The NH3-plasma irradiation made PTFE surfaces hydrophilic. The contact angle of wate…
Monomers consisting of N-alkyl-substituted-2,5-bis(2-thienyl)pyrroles and thier electro-oxidatively generated polymers display electrochemical and optical properties which reflect the steric demands of the alkyl substituents.
Abstract A simple one‐dimensional mathematical model validated with high‐temperature entrained‐flow reactor data successfully explained dispersed calcium hydroxide particle surface area evolution resulting from concomitant calcination and sintering. An integrated first‐order calcination rate expression and a second‐or…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPotential dependence of the relative conductivity of poly(3-methylthiophene): electrochemical reduction in acetonitrile and liquid ammoniaRichard M. Crooks, Oliver M. R. Chyan, and Mark S. WrightonCite this: Chem. Mater. 1989, 1, 1, 2–4Publication Date (Print):January 1, 198…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTLattice-engineered micromodulation of intramolecular electron-transfer rates in trinuclear mixed-valence iron acetate complexesHo G. Jang, Steven J. Geib, Yuki Kaneko, Motohiro Nakano, Michio Sorai, Arnold L. Rheingold, Bernard Montez, and David N. HendricksonCite this: J. A…