Materials Literature
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Abstract The vibrational modes of clay minerals are uniquely accessible to FT Raman spectroscopy, but this potentially powerful technique has found limited application to the study of clay mineral structure. Raman spectra in the 50 to 3800 cm −1 region were obtained for a number of kandite clays. The kandite clay mine…
A combination of multiple-angle-of-incidence ellipsometry (MAIE) and environmental SEM (ESEM) was used to characterize the microstructure of acrylic latices during all four stages of film formation, starting from an aqueous colloidal dispersion (Stage I) and evolving to a continuous coating having no internal solid-so…
The synthesis and basic characterisation are reported for 85 new solids of the general formula [ML(x)][Ln-(dipic)(3)] . nH(2)O (M = Cr or Co; L = urea, ammonia, and various amines; Ln = La-Lu, plus Y; dipic = pyridine-2,6-dicarboxylate). Syntheses of some seven Cs-3[Ln(dipic)(3)] and [N(C2H5)(4)](3)[Ln(dipic)(3)] spec…
Abstract A new, general synthesis of the first β ‐substituted tetra‐ and hexaalkyl terpyrroles is described. Also described are two new classes of expanded porphyrins derived from the hexaalkyl terpyrrole. The key step in the terpyrrole formation is the copper( II )‐mediated oxidative coupling of the LDA‐derived enola…
The flexural stiffness of the rachis varies along the length of a primary feather, between primaries and between species; the possible contribution of variations in the longitudinal Young's modulus of feather keratin to this was assessed. Tensile tests on compact keratin from eight species of birds belonging to differ…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Use of Hydrotalcite as an Anion AbsorbentLinda M. Parker, Neil B. Milestone, and Roger H. NewmanCite this: Ind. Eng. Chem. Res. 1995, 34, 4, 1196–1202Publication Date (Print):April 1, 1995Publication History Published online1 May 2002Published inissue 1 April 1995https:/…
π‐conjugated polymers substituted with optically active side chains (see Figure) have been studied using circular dichroism, a powerful technique which reveals conformational changes. Thermochroism with a unique stereomutation (see this month's cover also) has been observed in regioregular chiral polythiophenes. magni…
The third‐order nonlinear optical susceptibilities, X (3) , of TeO 2 ‐based glasses containing transition metal oxides (M = Sc 2 O 3 , TiO 2 , V 2 O 5 , Nb 2 O 5 , MoO 3 , Ta 2 O 5 , and WO 3 ) glasses have been measured by the third harmonic generation (THG) method in order to investigate the effect of the empty d ‐o…
To evaluate the effect of surface treatment and surface microtexture on cellular behavior, smooth and microtextured silicone substrata were produced. The microtextured substrata possessed parallel surface grooves with a width and spacing of 2.0 (SilD02), 5.0 (SilD05), and 10 microns (SilD10). The groove depth was appr…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStructure and Properties of Poly(acrylic acid)-Doped PolyanilineShow-An Chen and Hsun-Tsing LeeCite this: Macromolecules 1995, 28, 8, 2858–2866Publication Date (Print):April 1, 1995Publication History Published online1 May 2002Published inissue 1 April 1995https://pubs.acs.o…
Abstract Dendritic polymers, perfectly branched dendrimers as well as hyperbranched materials, are discussed in some detail. The variety of the synthetic routes to perfect dendrimers and some highlights of the achieved structures document the rapid increase of activity in this field. Much information on growth, defect…
PURPOSE: Since liposomal encapsulation of anticancer drugs may enhance antitumor activity while reducing toxicity in vitro, we evaluated liposomally encapsulated daunorubucin (DaunoXome; Vestar, Inc, San Dimas, CA) for safety, pharmacokinetics, and potential efficacy in patients with AIDS-related Kaposi's sarcoma (AID…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTFluorescence Studies of Poly(p-phenyleneethynylene)s: The Effect of Anthracene SubstitutionTimothy M. Swager, Caroline J. Gil, and Mark S. WrightonCite this: J. Phys. Chem. 1995, 99, 14, 4886–4893Publication Date (Print):April 1, 1995Publication History Published online1 May…