Materials Literature
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Abstract The melting behavior of poly( L ‐lactic acid) film crystallized from the glassy state, either isothermally or nonisothermally, was studied by wide angle X‐ray diffraction (WAXD), small angle X‐ray scattering (SAXS), differential scanning calorimetry (DSC), and temperature‐modulated differential scanning calor…
Programmable metallization cell (PMC) memory is based on the electrochemical growth and removal of nanoscale metallic pathways in thin films of solid electrolyte. Our previous studies concentrated on electrolytes formed from silver-doped germanium selenide glasses but these materials are not able to withstand the temp…
Three generations of azido-terminated PEG-dendritic block copolymers have been synthesized and completely characterized by NMR and MALDI-TOF. A radial decrease of density, leading to more mobile protons at the outermost periphery, and an increasingly higher compactness of the core with generation have been determined…
A simple method based on a hydrothermal process using alkali salts as mineralizers is proposed for the synthesis of aligned bunches of boehmite (gamma-AlOOH) nanowires without a template's assistance. Most bunches of aligned boehmite nanowires are constructed by two separated shorter bundles with widths of 700 to appr…
Synthesis and peptide-guided self-assembly of an organo-soluble peptide-polymer conjugate, comprising a sequence-defined polypeptide and a poly(n-butyl acrylate), are described. The amino acid sequence of the peptide encodes a high tendency to adopt an antiparallel beta-sheet motif, and thus programs the formation of…
We have prepared amphiphilic dumbbell molecules consisting of hydrophobic alkyl chains and hydrophilic oligoether dendrons at each end of the rod segment. The molecular dumbbells, in aqueous solution, self-assemble into toroids as an intermediate nanostructure between spherical and long cylindrical micelles. The forma…
Highly open porous biodegradable scaffolds, based on gelatin A3, were fabricated with the aim of using them for tissue-engineering applications. The fabrication process is based on an emulsion-templating technique. In the preparation of gelatin scaffolds two different cross-linking procedures were adopted: (I) radical…
The effect of linker chain length on the energy transfer from CdSe quantum dots (QDs) to silicon phthalocyanine (Pc) photodynamic therapy agents was investigated by steady-state and femtosecond time-resolved spectroscopy with 500 nm light for the specific excitation of the QD energy donor. The conjugation between the…
Magnetoresistance and radio frequency penetration depth techniques are used to study grain connectivity and broadening of superconducting transition. We study and compare these issues in clean polycrytalline samples of three different superconducting systems e.g. MgB2, NbSe2 and Bi2Sr2Ca2Cu3O10. From the rf response,…
We consider a model of a molecular junction made of BDT (benzene dithiol) molecule trapped between two Au(100) leads. Using the ab initio approach implemented in the SIESTA package we look for the optimal configuration of the molecule as a function of a distance between the leads. We find that for the distance long en…
In this work we have studied systematically the changes in the magnetic behavior of highly oriented pyrolytic graphite (HOPG) samples after proton irradiation in the MeV energy range. Superconducting quantum interferometer device (SQUID) results obtained from samples with thousands of localized spots of micrometer siz…
The discovery of carbon nanotubes and C 60 fullerenes has created an enormous impact on possible new nanomechanical devices. Owing to their unique mechanical and electronic properties, such as low weight, high strength, flexibility and thermal stability, carbon nanotubes and C 60 fullerenes are of considerable interes…
The Hohenberg-Kohn (HK) theorem is one of the most fundamental theorems of quantum mechanics, and constitutes the basis for the very successful density-functional approach to inhomogeneous interacting many-particle systems. Here we show that in formulations of density-functional theory (DFT) that employ more than one…
MgB2/Fe tapes with 2.5-15 at.% ZrB2 additions were prepared through the in situ powder-in-tube method. Compared to the pure tape, a significant improvement in the in-field critical current density Jc was observed, most notably for 10 at.% doping, while the critical temperature decreased slightly. At 4.2 K, the transpo…
We introduce a new chemical vapor deposition (CVD) process that can be used to selectively deposit materials of many different types. The technique makes use of the plasmon resonance in nanoscale metal structures to produce the local heating necessary to initiate deposition when illuminated by a focused low-power lase…
Successive oxidation processes in a heterobimetallic iron–ruthenium complex (see picture) “switch” the optical transitions at long wavelengths, and these linear electrochromic effects are accompanied by changes in the nonlinear optical properties of the complex.
Owing to their unusual properties, carbon nanostructures such as nanotubes and fullerenes have caused many new nanomechanical devices to be proposed. One such application is that of nanoscale oscillators which operate in the gigahertz range, the so-called gigahertz oscillators. Such devices have potential applications…
When a mesoscopic two dimensional four-terminal Hall cross-bar with Rashba and/or Dresselhaus spin-orbit interaction (SOI) is subjected to a perpendicular uniform magnetic field $B$, both integer quantum Hall effect (IQHE) and mesoscopic spin-Hall effect (MSHE) may exist when disorder strength $W$ in the sample is wea…
First principles total-energy pseudopotential calculations have been performed to investigate STM images of the (110) cross-sectional surface of Mn-doped GaAs. We have considered configurations with Mn in interstitial positions in the uppermost surface layers with Mn surrounded by As (Int$_{As}$) or Ga (Int$_{Ga}$) at…
We report on the finite size effects in the Verwey transition of stress-free magnetite Fe3O4 thin films. A limit thickness of 20 nm is evidenced, above which the transition temperature TV is constant and close to 120 K (bulk value) and below which no genuine transition is observed. Field Cooled and Zero Field Cooled m…