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Redetermination of the borax structure from laboratory X-ray data at 145 K

Graeme J. Gainsford、Tim Kemmitt、C.D. Higham2008-04-23Acta Crystallographica Section E Structure Reports Online

THE TITLE COMPOUND, SODIUM TETRABORATE DECAHYDRATE (MINERAL NAME: borax), Na(2)[B(4)O(5)(OH)(4)]·8H(2)O, has been studied previously using X-ray [Morimoto (1956). Miner. J.2, 1-18] and neutron [Levy & Lisensky (1978). Acta Cryst. B34, 3502-3510] diffraction data. The structure contains tetra-borate anions [B(4)O(5)(OH…

X-ray Spectroscopy and Fluorescence AnalysisChemical Synthesis and CharacterizationX-ray Diffraction in Crystallography

Effect of Dispersion Condition of Calcium Carbonate on the Crystallization and Melting Behavior of Polypropylene/CaCO3Nanocomposites

Ran Tao、Zheng Ying Liu、Wei Yang 等 4 位作者2008-04-23Polymer-Plastics Technology and Engineering

Polypropylene/calcium carbonate (PP/CaCO3) nanocomposites were prepared by melt compounding (C-1) and novel compounding process (C-2), respectively. Scanning electronic microscope (SEM) results illustrated that CaCO3 nanoparticles were well dispersed at nanoscale in C-2, whereas the nanoparticles were mostly aggregate…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Basic Studies for Modeling Complex Weft Knitted Fabric Structures Part III: A Geometrical Model for 1 × 1 Purl Fabrics

Arif Kurbak、Ali Serkan Soydan2008-04-23Textile Research Journal

In this work, a geometrical model for 1 × 1 purl fabric is created by using Kurbak's (1998) model of plain knitted fabric. Drawings of the structure were created by using the graphics program 3DS-MAX. The loop shape obtained was a similar shape to what has been obtained experimentally in real fabrics.

Dyeing and Modifying Textile FibersTextile materials and evaluationsColor Science and Applications

Interfacial interactions and performance of polyamide 6/modified attapulgite clay nanocomposites

Bingli Pan、Junfang Ren、Qunfeng Yue 等 6 位作者2008-04-23Polymer Composites

Abstract Attapulgite (AT) clay was firstly treated with sodium polyacrylate (PAS), then polyamide 6 (PA6)/AT nanocomposites were prepared by simple melt compounding. Transmission electron microscope (TEM) and Fourier transform infrared spectrometry (FT‐IR) of treated AT confirm the success of purifying and surface mod…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Preparation and Characterization of Edible Films Based on Soy Protein Isolate-Fatty Acid Blends

Preetishree Nayak、Preetishree Nayak、Abhisek Sasmal 等 8 位作者2008-04-23Polymer-Plastics Technology and Engineering

Edible films containing soy protein isolate, long-chain fatty acids, and cross-linkers using glycerol as the plasticizer have been prepared. FTIR spectra reveal the presence of different groups present in the biofilms. The WVP value is highest in the case of films with 10% oleic acid and decreases with increasing conc…

Nanocomposite Films for Food Packagingbiodegradable polymer synthesis and propertiesFood Chemistry and Fat Analysis

Influence of acoustic streaming on the stability of a laterally heated three-dimensional cavity

W. Dridi、Daniel Henry、H. Ben Hadid2008-04-23Physical Review E

The flows induced by acoustic streaming in a three-dimensional side-heated parallelepiped cavity of length Ax representative of crystal growth configurations are numerically studied. Both the structure of the flows and their stability properties are determined. The flows have different symmetries, belonging to the gro…

Solidification and crystal growth phenomenaCrystallization and Solubility Studiesnanoparticles nucleation surface interactions

Structural and functional characterization of a novel phosphatase from the Arabidopsis thaliana gene locus At1g05000

David J. Aceti、E. Bitto、Alexander F. Yakunin 等 12 位作者2008-04-23Proteins Structure Function and Bioinformatics

The crystal structure of the protein product of the gene locus At1g05000, a hypothetical protein from A. thaliana, was determined by the multiple-wavelength anomalous diffraction method and was refined to an R factor of 20.4% (R(free) = 24.9%) at 3.3 A. The protein adopts the alpha/beta fold found in cysteine phosphat…

Enzyme Structure and FunctionEnzyme function and inhibitionBiochemical and Molecular Research

Preparation and characterization of functionalized carbon nanotubes/poly(phthalazinone ether sulfone ketone)s composites

Xuebin Feng、Gongxiong Liao、Wei He 等 6 位作者2008-04-23Polymer Composites

Abstract Multiwalled carbon nanotubes (MWNT) were successfully functionalized with phthalazinone‐containing diamine (DHPZDA) groups by the amidation reaction. The morphologies and structures of the DHPZDA‐functionalized MWNT (MWNT‐DHPZDA) were characterized by scanning electron microscope, Fourier transform infrared,…

Carbon Nanotubes in CompositesConducting polymers and applicationsSynthesis and properties of polymers

Optical Emissions of Zn and ZnO in Zn-ZnO Structure Synthesized by Electrodeposition with Aqueous Solution of Zinc Nitrate-6-hydrate

Ming‐Kwei Lee、Hwai-Fu Tu2008-04-23Crystal Growth & Design

High Resolution Image Download MS PowerPoint Slide Both hexagonal zinc and wurtzite zinc oxide were deposited on p-type silicon substrate by the electrodeposition with an aqueous solution of zinc nitrate-6-hydrate near room temperature. Zinc dominates the growth at higher current density, and zinc oxide dominates the…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

Why Does Cyanide Pretend to be a Weak Field Ligand in [Cr(CN)5]3−?

Richard L. Lord、Mu‐Hyun Baik2008-04-23Inorganic Chemistry

Chemical reasoning based on ligand-field theory suggests that homoleptic cyano complexes should exhibit low-spin configurations, particularly when the coordination sphere is nearly saturated. Recently, the well-known chromium hexacyano complex anion [Cr(CN)6](4-) was shown to lose cyanide to afford [Cr(CN)5](3-) in th…

Metal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

New Coordination Polymers of Lanthanide(iii) with Tetrazole-1-acetic Acid: Synthesis, Crystal Structures, and Magnetic Properties

Xiu‐Qing Zhang、Qing Yu、He‐Dong Bian 等 7 位作者2008-04-23Australian Journal of Chemistry

New coordination polymers {[Ln(tza)3(H2O)2]·mH2O}n (Ln = LaIII1 and PrIII2, m = 2; Ln = NdIII3, m = 1.5) and {[Sm2(tza)6(H2O)5]·H2O}n4 (Htza = tetrazole-1-acetic acid) have been synthesized and characterized by IR spectroscopy, elemental analysis, X-ray crystallography, and magnetic measurements. The Htza ligand coord…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

A New Family ofD-2-Hydroxyacid Dehydrogenases That ComprisesD-Mandelate Dehydrogenases and 2-Ketopantoate Reductases

Yusuke Wada、Saho Iwai、Yusuke Tamura 等 7 位作者2008-04-23Bioscience Biotechnology and Biochemistry

The gene for the D-mandelate dehydrogenase (D-ManDH) of Enterococcus faecalis IAM10071 was isolated by means of an activity staining procedure and PCR and expressed in Escherichia coli cells. The recombinant enzyme exhibited high catalytic activity toward various 2-ketoacid substrates with bulky hydrophobic side chain…

Enzyme Structure and FunctionAmino Acid Enzymes and MetabolismDiet, Metabolism, and Disease

Electric Field Quenching of Carbon Nanotube Photoluminescence

Anton V. Naumov、Sergei M. Bachilo、Dmitri Tsyboulski 等 4 位作者2008-04-23Nano Letters

The effect of external electric fields on the photoluminescence intensity of single-walled carbon nanotubes was investigated for individual nanotubes and bulk samples in polymeric films. Fields of up to 10(7) V/m caused dramatic, reversible decreases in emission intensity. Quenching efficiency varied as the cosine of…

Carbon Nanotubes in CompositesMechanical and Optical ResonatorsNanotechnology research and applications

Hybrid composite based on poly(vinyl alcohol) and fillers from renewable resources

Patrizia Cinelli、Emo Chiellini、Syed H. Imam2008-04-23Journal of Applied Polymer Science

Abstract Hybrid composite laminates consisting of polyvinyl alcohol (PVA) as continuous phase (33% by weight) and lignocellulosic fillers, derived from sugarcane bagasse, apple and orange waste (22% by weight) were molded in a carver press in the presence of water and glycerol such as platicizers agents. Corn starch w…

Nanocomposite Films for Food PackagingNatural Fiber Reinforced Compositesbiodegradable polymer synthesis and properties

Synthesis and Spectroscopic Properties of Low-Symmetry Tribenzoporphyrazines with Annulated 6H-1,4-Diazepine Ring

Maria Pia Donzello、Claudio Ercolani、Luisa Mannina 等 7 位作者2008-04-23Australian Journal of Chemistry

Template co-condensation of 2,3-dicyano-5,7-diphenyl-6H-1,4-diazepine 1 with 10-fold molar excess of phthalodinitrile 2 in the presence of MgII propoxide or butoxide in the corresponding alcohol leads to a mixture of MgII-diazepinoporphyrazines 3–6 from which the low symmetry 3:1 species 3, which contains three annula…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Hexagonally Patterned Lamellar Morphology in ABC Triblock Copolymer/Aluminosilicate Nanocomposites

Gilman E. S. Toombes、Surbhi Mahajan、Malcolm G. Thomas 等 7 位作者2008-04-23Chemistry of Materials

X-ray scattering and electron microscopy were used to characterize the structure of poly(ethylene- alt -propylene- block -ethylene oxide- block-n -hexyl methacrylate) (PEP- b -PEO- b -PHMA) triblock copolymer/aluminosilicate hybrid materials in which the volume fraction of the PEP end-block (0.09 ≤ f PEP ≤ 0.12) was m…

Advanced Polymer Synthesis and CharacterizationMesoporous Materials and CatalysisBlock Copolymer Self-Assembly

Improvement of Full-Thickness Skin Graft Survival by Application of Vascular Endothelial Growth Factor in Rats

Feng Zhang、Tanya Oswald、Lin Lin 等 6 位作者2008-04-23Annals of Plastic Surgery

The effect of vascular endothelial growth factor (VEGF) on skin graft survival was studied in rats. Models of skin grafting on muscle and periosteum were designed. For the study of skin grafting on muscle model, 32 rats were divided into 4 groups. VEGF was administrated systemically after skin graft placement intrafas…

Electrospun Nanofibers in Biomedical ApplicationsWound Healing and TreatmentsPeriodontal Regeneration and Treatments

Automatic Measurement and Recognition of Yarn Snarls by Digital Image and Signal Processing Methods

Bingang Xu、Charlotte Marion Murrells、Xiao Ming Tao2008-04-23Textile Research Journal

In this paper, a computerized method has been proposed for automatic measurement and recognition of yarn wet snarls from an image of snarled yarn samples captured in a water bath. After image acquisition, image conversion and individual snarled sample extraction, the yarn profile function was extracted from the separa…

Optical measurement and interference techniquesTextile materials and evaluationsIndustrial Vision Systems and Defect Detection

Structural, Magnetic and Magnetotransport Properties of La0.7Pb0.3(Mn1–xNix)O3 (0.1 ≤ x ≤ 0.3) CMR Manganites

Alazne Peña、J. Gutiérrez、Javier Campo 等 7 位作者2008-04-23European Journal of Inorganic Chemistry

Abstract Structural and magnetic properties of La 0.7 Pb 0.3 (Mn 1– x Ni x )O 3 (0.1 ≤ x ≤ 0.3) manganites are reported. Samples were fabricated by the sol–gel low‐temperature method. At room temperature, the first structural characterization of all phases indicated the rhombohedral space group ( R $\bar {3}$ c ). All…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics