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Macroscopic and microscopic thermodynamic observations in swollen poly(vinyl acetate) networks

Ferenc Horkay、A. M. Hecht、Simon Mallam 等 5 位作者1991-05-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMacroscopic and microscopic thermodynamic observations in swollen poly(vinyl acetate) networksFerenc Horkay, Anne Marie Hecht, Simon Mallam, Erik Geissler, and Adrian R. RennieCite this: Macromolecules 1991, 24, 10, 2896–2902Publication Date (Print):May 1, 1991Publication Hi…

Polymer Nanocomposites and PropertiesConducting polymers and applicationsPolymer Science and PVC

X-ray photoelectron spectroscopic studies of polypyrrole synthesized with oxidative iron(III) salts

E. T. Kang、K. G. Neoh、Yee Kang Ong 等 5 位作者1991-05-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTX-ray photoelectron spectroscopic studies of polypyrrole synthesized with oxidative iron(III) saltsE. T. Kang, K. G. Neoh, Y. K. Ong, K. L. Tan, and B. T. G. TanCite this: Macromolecules 1991, 24, 10, 2822–2828Publication Date (Print):May 1, 1991Publication History Published…

Corrosion Behavior and InhibitionConducting polymers and applicationsAnalytical Chemistry and Sensors

New high-refractive-index organic/inorganic hybrid materials from sol-gel processing

Beijing Wang、G. L. Wilkes、J. C. Hedrick 等 5 位作者1991-05-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNew high-refractive-index organic/inorganic hybrid materials from sol-gel processingB. Wang, G. L. Wilkes, J. C. Hedrick, S. C. Liptak, and J. E. McGrathCite this: Macromolecules 1991, 24, 11, 3449–3450Publication Date (Print):May 1, 1991Publication History Published online1…

Mesoporous Materials and CatalysisSilicone and Siloxane Chemistry

Serine modulates substrate channeling in tryptophan synthase. A novel intersubunit triggering mechanism

Karen S. Anderson、Edith Wilson Miles、Kenneth A. Johnson1991-05-01Journal of Biological Chemistry

Tryptophan synthase, an alpha 2 beta 2 complex, is a classic example of an enzyme that is thought to "channel" a metabolic intermediate (indole) from the active site of the alpha subunit to the active site of the beta subunit. We now examine the kinetics of substrate channeling by tryptophan synthase directly by chemi…

Enzyme Structure and FunctionBiochemical and Molecular ResearchBiochemical Acid Research Studies

Crystallization kinetics during polymer processing—Analysis of available approaches for process modeling

Rajen M. Patel、Joseph E. Spruiell1991-05-01Polymer Engineering and Science

Abstract An analysis of available methods of dealing with polymer crystallization for process modeling is presented. Problems encountered in using isothermal data to predict nonisothermal results are discussed and illustrated using experimental data for nylon 6. A half‐time analysis is used to evaluate and extrapolate…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesThermal and Kinetic Analysis

Bis[3-tert-butyl-5-(N-oxy-tert-butylamino)phenyl] nitroxide in a quartet ground state: a prototype for persistent high-spin poly[(oxyimino)-1,3-phenylenes]

Takayuki Ishida、Hiizu Iwamura1991-05-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTBis[3-tert-butyl-5-(N-oxy-tert-butylamino)phenyl] nitroxide in a quartet ground state: a prototype for persistent high-spin poly[(oxyimino)-1,3-phenylenes]Takayuki Ishida and Hiizu IwamuraCite this: J. Am. Chem. Soc. 1991, 113, 11, 4238–4241Publication Date (Print):May 1, 19…

Magnetism in coordination complexesAdvanced NMR Techniques and ApplicationsElectron Spin Resonance Studies

Atropisomer-specific formation of premicellar porphyrin J-aggregates in aqueous surfactant solutions

David C. Barber、Ruth A. Freitag-Beeston、David G. Whitten1991-05-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAtropisomer-specific formation of premicellar porphyrin J-aggregates in aqueous surfactant solutionsDavid C. Barber, Ruth A. Freitag-Beeston, and David G. WhittenCite this: J. Phys. Chem. 1991, 95, 10, 4074–4086Publication Date (Print):May 1, 1991Publication History Publishe…

Supramolecular Chemistry and ComplexesMagnetism in coordination complexesPorphyrin and Phthalocyanine Chemistry

Hyperbranched poly(siloxysilanes)

Lon J. Mathias、Terrell W. Carothers1991-05-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHyperbranched poly(siloxysilanes)Lon J. Mathias and Terrell W. CarothersCite this: J. Am. Chem. Soc. 1991, 113, 10, 4043–4044Publication Date (Print):May 1, 1991Publication History Published online1 May 2002Published inissue 1 May 1991https://pubs.acs.org/doi/10.1021/ja00010…

Dendrimers and Hyperbranched Polymers

Thermodynamic Properties of the NaBr+H2O System

Donald G. Archer1991-05-01Journal of Physical and Chemical Reference Data

Equations that described the thermodynamic properties of the NaBr+H2O system were obtained from a fit to experimental results for this system. The experimental results included in the fit spanned the range of temperature of approximately 260 to 623 K and the range of pressure from the vapor pressure of the solution to…

Thermal and Kinetic Analysis

The ZnGa2 O 4 Phosphor for Low‐Voltage Blue Cathodoluminescence

Shigeo Itoh、Hitoshi Toki、Yoshitaka Sato 等 5 位作者1991-05-01Journal of The Electrochemical Society

The phosphor has been investigated for its application to vacuum fluorescent displays (VFDs) utilizing low‐voltage cathodoluminescence. It is expected that this oxide phosphor does not cause damage to filaments in VFD's, while it is a serious problem for conventional sulfide phosphors. This phosphor shows blue lumines…

Luminescence Properties of Advanced MaterialsGas Sensing Nanomaterials and SensorsOrganic Light-Emitting Diodes Research

Subdwarf Studies. III. The Halo Metallicity Distribution

Sean G. Ryan、John E. Norris1991-05-01The Astronomical Journal

We have constructed the metallicity distribution of a sample of 372 kinematically selected halo stars, most having spectroscopically determined abundances, drawn from our southern subdwarf study and the northern program of Laird et al. [AJ, 95, 1843 (l988a); 96, 1908 (l988b)]. We find that the metallicity distribution…

nanoparticles nucleation surface interactionsX-ray Diffraction in CrystallographyInorganic Fluorides and Related Compounds

The normal modes at the surface of simple metals

Ku‐Ding Tsuei、E. W. Plummer、A. Liebsch 等 6 位作者1991-05-01Surface Science

The dynamic response of the electrons at the surface of simple metals, like Na, K and Cs, to an external time varying field is discussed in this paper. Of special interest are the normal modes at a surface, defined theoretically by the poles in the reflection function. The surface plasmon is the best known normal mode…

Electron and X-Ray Spectroscopy TechniquesSurface and Thin Film PhenomenaIntegrated Circuits and Semiconductor Failure Analysis

Thermal degradation of poly(methyl methacrylate). 4. Random side-group scission

Lewis E. Manring1991-05-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThermal degradation of poly(methyl methacrylate). 4. Random side-group scissionLewis E. ManringCite this: Macromolecules 1991, 24, 11, 3304–3309Publication Date (Print):May 1, 1991Publication History Published online1 May 2002Published inissue 1 May 1991https://pubs.acs.org/…

Polymer crystallization and propertiesMachine Learning in Materials ScienceElectron and X-Ray Spectroscopy Techniques

Surface science studies of the electronic and chemical properties of bimetallic systems

José A. Rodríguez、D. Wayne Goodman1991-05-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSurface science studies of the electronic and chemical properties of bimetallic systemsJose A. Rodriguez and D. Wayne GoodmanCite this: J. Phys. Chem. 1991, 95, 11, 4196–4206Publication Date (Print):May 1, 1991Publication History Published online1 May 2002Published inissue 1…

Advanced Chemical Physics StudiesAdvanced Physical and Chemical Molecular InteractionsChemical and Physical Properties of Materials

Premelting crystalline relaxations and phase transitions in nylon 6 and 6,6

N. Sanjeeva Murthy、Sean A. Curran、S. M. Aharoni 等 4 位作者1991-05-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPremelting crystalline relaxations and phase transitions in nylon 6 and 6,6N. S. Murthy, S. A. Curran, S. M. Aharoni, and H. MinorCite this: Macromolecules 1991, 24, 11, 3215–3220Publication Date (Print):May 1, 1991Publication History Published online1 May 2002Published inis…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesMicroplastics and Plastic Pollution

Relationships between structural parameters and Raman frequencies for some planar and nonplanar nickel(II) porphyrins

John A. Shelnutt、Craig J. Medforth、M. Dolores Berber 等 5 位作者1991-05-01Journal of the American Chemical Society

Molecular mechanics calculations, based on a force field derived from a previously published normal coordinate analysis for NiOEP (1) and the X-ray structure of NiOEP? triclinic form, have been used to predict the structures of NiTPP (2), NiP (3), and several recently synthesized nickel porphyrins which bear alkyl or…

Metal complexes synthesis and propertiesMagnetism in coordination complexesPorphyrin and Phthalocyanine Chemistry

Ferroelectric thin films for electronic applications

Gene H. Haertling1991-05-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

This is a review paper on the history of ferroelectric thin films, current practices in their fabrication, characteristics of interest which relate to their use, and the application of these films to memory and electrooptic devices.

Liquid Crystal Research Advancements

A molecular interpretation of the toughness of glassy polymers

Hugh R. Brown1991-05-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA molecular interpretation of the toughness of glassy polymersH. R. BrownCite this: Macromolecules 1991, 24, 10, 2752–2756Publication Date (Print):May 1, 1991Publication History Published online1 May 2002Published inissue 1 May 1991https://pubs.acs.org/doi/10.1021/ma00010a01…

Organometallic Complex Synthesis and CatalysisGlass properties and applicationsCatalysis and Oxidation Reactions

Dynamic light-scattering study of the glass transition in a colloidal suspension

W. van Megen、P. N. Pusey1991-05-01Physical Review A

This paper describes a light-scattering study of the glass transition in nonaqueous suspensions of sterically stabilized colloidal spheres. The observed phase behavior, fluid, crystal, and glass, is consistent with an essentially hard-sphere interaction between the particles. Metastable fluid states were obtained upon…

Liquid Crystal Research AdvancementsMaterial Dynamics and Properties