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Electrochemical evidence for the existence of three stable oxidation states for heterocycles of the type XC6H4CN2E2 (E = S, Se). X‐ray crystal structure of the dimer with X = Cl, E = S

Renè T. Boeré、Klaus H. Moock、Masood Parvez1994-09-01Zeitschrift für anorganische und allgemeine Chemie

Abstract The preparation and isolation in the solid state of five aryl 1,2,3,5‐dithia‐ and diselenadiazolyls is reported. The structure of the dimer of 4‐ClC 6 H 4 CN 2 S 2 in the solid state was obtained: monoclinic, C2/c with Z = 8, a = 20.982(10), b = 10.058(3), c = 15.867(6) Å, β = 93.34(4)°, R = 0.066, R w = 0.…

Magnetism in coordination complexesCrystallography and molecular interactionsOrganic and Molecular Conductors Research

Attenuation properties of diagnostic x‐ray shielding materials

Benjamin R. Archer、Thomas R. Fewell、Burton J. Conway 等 4 位作者1994-09-01Medical Physics

Single- and three-phase broad-beam x-ray attenuation data have been obtained using lead, steel, plate glass, gypsum wallboard, lead acrylic, and wood. Tube voltages of 50, 70, 100, 125, and 150 kVp were employed and the resulting curves were compared to transmission data found in the literature. To simplify computatio…

Non-Destructive Testing TechniquesRadiation Shielding Materials AnalysisGraphite, nuclear technology, radiation studies

Relation between molecular orientation and rheology in lyotropic hydroxypropylcellulose solutions

K. Hongladarom、V. Secakusuma、Wesley R. Burghardt1994-09-01Journal of Rheology

Views Icon Views Article contents Figures & tables Video Audio Supplementary Data Peer Review Share Icon Share Twitter Facebook Reddit LinkedIn Tools Icon Tools Reprints and Permissions Cite Icon Cite Search Site Citation K. Hongladarom, V. Secakusuma, W. R. Burghardt; Relation between molecular orientation and rheolo…

Liquid Crystal Research AdvancementsAdvanced Cellulose Research StudiesSurfactants and Colloidal Systems

Cure and Mechanical Behavior of Rubber Compounds Containing Ground Vulcanizates. Part I—Cure Behavior

D. Gibala、G. R. Hamed1994-09-01Rubber Chemistry and Technology

Abstract SBR compounds containing ground vulcanizates of known composition and cure state were prepared and the cure behavior studied. Decreases in scorch times and maximum rheometer torques were observed when ground vulcanizates were added to the SBR compounds. Two primary phenomena are proposed to explain these find…

Polymer Nanocomposites and PropertiesSynthesis and properties of polymersSilicone and Siloxane Chemistry

Theoretical studies of the interaction between aluminum and poly(p-phenylenevinylene) and derivatives

M. Lögdlund、J. L. Brédas1994-09-01The Journal of Chemical Physics

We report the results of a theoretical study of the interaction between aluminum and poly(p-phenylenevinylene) and derivatives of poly(p-phenylenevinylene). This allows us to investigate the initial stages of formation of the metal/conjugated polymer interface. Applying the semiempirical Austin model 1 method, we find…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsMolecular Junctions and Nanostructures

Modeling the dynamics of nonlinear inductor circuits

Jonathan H. B. Deane1994-09-01IEEE Transactions on Magnetics

The Jiles-Atherton (J-A) model is applied to the problem of describing the dynamics of a nonlinear circuit driven by a square wave voltage source and comprising a linear resistor and capacitor in series with a nonlinear inductor, whose core displays saturation and hysteresis. The presence of hysteresis is shown to inc…

Magnetic properties of thin filmsNonlinear Dynamics and Pattern FormationMagnetic Properties and Applications

Pitting Corrosion of Pipeline Steel in Dilute Bicarbonate Solution with Chloride Ions

Xuan Mao、X. Liu、R. Winston Revie1994-09-01CORROSION

Corrosion behavior of grade 550 (X-80) pipeline steel with coating disbondments was studied in a range of bicarbonate (HCO3−) solutions using a potentiodynamic polarization technique. Corrosion morphology of the steel was examined using optical and scanning electron microscopy. The shape of the polarization curves and…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Genetically Engineered Fluoropolymers. Synthesis of Repetitive Polypeptides Containing p-Fluorophenylalanine residues

Eiichiro Yoshikawa、Maurille J. Fournier、Thomas L. Mason 等 4 位作者1994-09-01Macromolecules

Genetic engineering offers the potential for creating new proteins with novel materials properties. The aim of this study is to develop strategies for incorporating the non-natural amino acid p-fluorophenylalanine (pfF), which is known to be utilized by the Escherichia coli protein synthesis apparatus, into repetitive…

RNA and protein synthesis mechanismsbiodegradable polymer synthesis and propertiesAnimal Genetics and Reproduction

Thermocapillary migration of an attached drop on a solid surface

Mark L. Ford、Ali Nadim1994-09-01Physics of Fluids

Migration of a small drop of liquid, initially at rest on a level, solid surface, can be induced by means of thermocapillary forces. If a temperature gradient is imposed across the solid, it has the effect of diminishing the surface tension on the warmer side of the droplet. Consequently, migration manifests itself as…

Surface Modification and SuperhydrophobicityFluid Dynamics and Heat TransferFluid Dynamics and Thin Films

29 Si and 27 Al MAS‐NMR of NaOH‐Activated Blast‐Furnace Slag

Paul J. Schilling、Leslie G. Butler、Amitava Roy 等 4 位作者1994-09-01Journal of the American Ceramic Society

b 29 Si and 27 Al MAS‐NMR were performed on NaOH‐activated blast‐furnace slag to better characterize the amorphous and poorly crystalline phases which occur in this system. The unreacted glass has a mainly dimeric silicate structure represented by a broad 29 Si peak (FWHM = 15 ppm) centered at –74.5 ppm [ Q 1 ], with…

Glass properties and applicationsClay minerals and soil interactionsNuclear materials and radiation effects

Crosslinking Reactions for the Conversion of Polyphosphazenes into Useful Materials

Harry R. Allcock1994-09-01Chemistry of Materials

The conversion of phosphazene high polymers to useful materials depends on the development of methods to cross-link the macromolecular chains. A number of cross-linking routes have been used, including chemical, photochemical, and high energy radiation techniques. The relationship of the cross-linking processes to ele…

Flame retardant materials and properties

A New Synthetic Method of Preparing Iodohydrin and Bromohydrin Derivatives through in situ Generation of Hypohalous Acids from H5IO6 and NaBrO3 in the Presence of NaHSO3

Haruyoshi Masuda、Kiyoshi Takase、Masahiro Nishio 等 6 位作者1994-09-01The Journal of Organic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA New Synthetic Method of Preparing Iodohydrin and Bromohydrin Derivatives through in situ Generation of Hypohalous Acids from H5IO6 and NaBrO3 in the Presence of NaHSO3Haruyoshi Masuda, Kiyoshi Takase, Masahiro Nishio, Akira Hasegawa, Yutaka Nishiyama, and Yasutaka IshiiCit…

Radioactive element chemistry and processingCovalent Organic Framework ApplicationsChemical Synthesis and Characterization

Degradation of unstabilized medium‐density polyethylene pipes in hot‐water applications

J. Viebke、E. Elble、M. Ifwarson 等 4 位作者1994-09-01Polymer Engineering and Science

Abstract Pipes of an unstabilized medium‐density polyethylene have been pressure tested with internal stagnant water and moderately circulating air as the external medium at temperatures ranging from 70 to 105°C and changes in molecular structure and crystallinity have been studied. The stage III (fracture induced by…

Polymer crystallization and propertiesMicroplastics and Plastic PollutionPolymer Science and PVC

Prototypes for the Polaronic Ferromagnet. Synthesis and Characterization of High-Spin Organic Polymers

Michael M. Murray、Piotr Kaszyński、David A. Kaisaki 等 5 位作者1994-09-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPrototypes for the Polaronic Ferromagnet. Synthesis and Characterization of High-Spin Organic PolymersMichael M. Murray, Piotr Kaszynski, David A. Kaisaki, Wonghil Chang, and Dennis A. DoughertyCite this: J. Am. Chem. Soc. 1994, 116, 18, 8152–8161Publication Date (Print):Sep…

Magnetism in coordination complexesPolyoxometalates: Synthesis and ApplicationsOrganic and Molecular Conductors Research

In situ growth of layered, spinel, and rock-salt LiCoO2 by laser ablation deposition

M. Antaya、K. J. Cearns、J. S. Prestón 等 5 位作者1994-09-01Journal of Applied Physics

A study is reported of the in situ growth of three distinct phases of LiCoO2 by laser ablation deposition on heated substrates in an oxygen background. Films were characterized by x-ray diffraction from which crystal structure, crystal orientation, lattice constants, and phase information were obtained. Electron micro…

ZnO doping and propertiesSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Simple method for measuring phase modulation in liquid crystal televisions

Zheng Zhang1994-09-01Optical Engineering

The relative phase shift of light transmitted through a liquid crystal television (LCTV) panel as a function of the applied voltage on the LCTV can be obtained by writing a Ronchi grating pattern to the LCTV and measuring the intensities in the diffraction pattern at the Fourier plane combined with the amplitude modul…

Liquid Crystal Research AdvancementsAdvanced Optical Imaging TechnologiesOptical Polarization and Ellipsometry

Optical absorption spectra of Au7, Au9, Au11, and Au13, and their cations: Gold clusters with 6, 7, 8, 9, 10, 11, 12, and 13 s-electrons

B. A. Collings、K. Athanassenas、D. Lacombe 等 5 位作者1994-09-01The Journal of Chemical Physics

The optical absorption spectra of a series of small gold clusters and their cations have been measured, between 1.9 and 5.6 eV, using a method based upon the photodepletion of a molecular beam of their van der Waals complexes containing one and two xenon atoms. This method provides size-specific information even thoug…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications

Coated Semiconductor Nanoparticles: The CdS/PbS System's Photoluminescence Properties

Hongyao Zhou、H. Sasahara、Itaru Honma 等 5 位作者1994-09-01Chemistry of Materials

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCoated Semiconductor Nanoparticles: The CdS/PbS System's Photoluminescence PropertiesH. S. Zhou, H. Sasahara, I. Honma, H. Komiyama, and Joseph W. HausCite this: Chem. Mater. 1994, 6, 9, 1534–1541Publication Date (Print):September 1, 1994Publication History Published online1…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Shock-wave strength properties of boron carbide and silicon carbide.

D. E. Grady1994-09-01Journal de Physique IV (Proceedings)

Time-resolved velocity interferometry measurements have been made on boron carbide and silicon carbide ceramics to assess dynamic equation-of-state and strength properties of these materials. Hugoniot pecursor characteristics, and post-yield shock and release wave properties, indicated markedly different dynamic stren…

Advanced ceramic materials synthesisDiamond and Carbon-based Materials ResearchMechanical and Optical Resonators

Crystal structure and elastic-constant anomalies in the magnetic 3dtransition metals

Per Söderlind、Rajeev Ahuja、Olle Eriksson 等 5 位作者1994-09-01Physical review. B, Condensed matter

Assuming a saturated ferromagnet, the anomalous crystal structures of the magnetic 3d transition elements Fe, Co, and Ni are explained from simple band-filling arguments. The full-potential linear muffin-tin orbital (FP-LMTO) method is used to calculate the elastic constants (${\mathit{C}}_{11}$, ${\mathit{C}}_{12}$,…

High-pressure geophysics and materialsRare-earth and actinide compoundsMagnetic Properties of Alloys