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The role of a plasmonic substrate on the enhancement and spatial resolution of tip-enhanced Raman scattering

Mahfujur Rahaman、A. G. Milekhin、Ashutosh Mukherjee 等 7 位作者2018-11-07Faraday Discussions

/plasmonic heterostructure. Our calculations show a higher electric field concentration at the edges that exponentially decays to the center. Therefore, it reproduces the ring-like shape of the experimental image. Moreover, the calculations suggest a TERS enhancement of 135 at the edges compared to the center, which i…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesPlasmonic and Surface Plasmon Research

Thermally Persistent High-Spin Ground States in Octahedral Iron Clusters

Raúl Hernández Sánchez、Theodore A. Betley2018-11-07Journal of the American Chemical Society

Chemical oxidation and reduction of the all-ferrous ( H L) 2 Fe 6 in THF affords isostructural, coordinatively unsaturated clusters of the type [( H L) 2 Fe 6 ] n: [( H L) 2 Fe 6 ][BArF 24 ] ( 1, n = +1; where [BArF 24 ] − = tetrakis[(3,5-trifluoromethyl)phenyl]borate), [Bu 4 N][( H L) 2 Fe 6 ] ( 2a, n = −1), [P][( H…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesInorganic Chemistry and Materials

Extraction and Characterization of Lignocellulosic Fibers from Girardinia Bullosa (Steudel) Wedd. (Ethiopian Kusha Plant)

Ravindra D. Kale、Tambizot Getachew Alemayehu、Vikrant G. Gorade2018-11-07Journal of Natural Fibers

Currently, eco-friendly products have been given great attention as the world is being polluted severely by non-biodegradable products and by-products. Different textile products have their own share in affecting the environment. This research is focused on exploring alternative bast fiber products to support the supp…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research StudiesTextile materials and evaluations

Co-Delivery of Gemcitabine and Paclitaxel in cRGD-Modified Long Circulating Nanoparticles with Asymmetric Lipid Layers for Breast Cancer Treatment

Jing Zhang、Peng Zhang、Qian Zou 等 8 位作者2018-11-07Molecules

Combination chemotherapy is a common clinical practice in cancer treatment. Here, cyclic RGD (arginylglycylaspartic acid) peptide was introduced to the surface of lipid/calcium/phosphate (LCP) asymmetric lipid layer nanoparticles for the co-delivery of paclitaxel (PTX) and gemcitabine monophosphate (GMP) (P/G-NPs). Th…

Nanoparticle-Based Drug DeliveryRNA Interference and Gene DeliveryNanoplatforms for cancer theranostics

Review of ZnO Transparent Conducting Oxides for solar applications

Yuqi Chen2018-11-07IOP Conference Series Materials Science and Engineering

Solar energy is a renewable clean energy and photovoltaic is one of the most effective ways to use sunlight currently. Transparent conductive films such as ITO, AZO and so on as the window layer are widely used in HIT and other high efficientcy silicon-based heterojunction solar cells. The Zinc oxide conductive thin f…

ZnO doping and propertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Dielectric, Ferroelectric, and Magnetic Properties of Sm-Doped BiFeO3 Ceramics Prepared by a Modified Solid-State-Reaction Method

Fuzeng Zhang、Xiangjun Zeng、Daoguang Bi 等 6 位作者2018-11-07Materials

Sm-doped BiFeO3 (BFO) material was prepared using a modified solid-state-reaction method, which used fast heating and cooling during the sintering process. The Sm doping level varied between 1 mol % to 8 mol %. Processing parameters, such as sintering temperature and annealing temperature, were optimized to obtain hig…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsDielectric properties of ceramics

On-Line Cable Condition Monitoring Using Natural Power Disturbances

Lulu Li、Jing Yong、Wilsun Xu2018-11-07IEEE Transactions on Power Delivery

On-line cable insulation condition monitoring can significantly reduce the outages caused by insulation failure. This paper proposes a new method to achieve this by utilizing the natural power disturbances originating from outside of the cable, such as capacitor switching and fault transients. In this method, the rela…

High voltage insulation and dielectric phenomenaLightning and Electromagnetic PhenomenaElectrical Fault Detection and Protection

TC4/Ag Metal Matrix Nanocomposites Modified by Friction Stir Processing: Surface Characterization, Antibacterial Property, and Cytotoxicity in Vitro

Zhi Yang、Hao Gu、Gang Sha 等 9 位作者2018-11-07ACS Applied Materials & Interfaces

Numerous antibacterial biomaterials have been developed, but a majority of them suffer from poor biocompatibility. With the purpose of reducing biomaterial-related infection and cytotoxicity, friction stir processing (FSP) was employed to embed silver nanoparticles (Ag NPs) in a Ti-6Al-4V (TC4) substrate. Characteriza…

Bone Tissue Engineering MaterialsPolymer Surface Interaction StudiesMXene and MAX Phase Materials

Fire-Resistant Inorganic Analogous Xuan Paper with Thousands of Years’ Super-Durability

Li‐Ying Dong、Ying‐Jie Zhu2018-11-07ACS Sustainable Chemistry & Engineering

Xuan paper is a unique kind of high-quality paper originating in ancient China; it enjoys a great reputation as “the king of paper that lasts for 1000 years” and was inscribed on the Representative List of the Intangible Cultural Heritage of Humanity by the Educational, Scientific and Cultural Organization of the Unit…

biodegradable polymer synthesis and propertiesPolymer composites and self-healingFlame retardant materials and properties

Photothermal-Assisted Optical Stretching of Gold Nanoparticles

Shuangshuang Wang、Tao Ding2018-11-07ACS Nano

The synergy of photothermal energy and optical forces generated by tightly focused laser beams can be used to transform the shape of gold nanoparticles. Here, the combination of these two effects is demonstrated to be an effective way of elongating gold nanoparticles (Au NPs), massively tuning their plasmonic properti…

Gold and Silver Nanoparticles Synthesis and Applicationsnanoparticles nucleation surface interactionsLaser-Ablation Synthesis of Nanoparticles

Active learning in Gaussian process interpolation of potential energy surfaces

Elena Uteva、Richard J. Wheatley、Richard D. Wilkinson 等 4 位作者2018-11-07The Journal of Chemical Physics

Three active learning schemes are used to generate training data for Gaussian process interpolation of intermolecular potential energy surfaces. These schemes aim to achieve the lowest predictive error using the fewest points and therefore act as an alternative to the status quo methods involving grid-based sampling o…

Process Optimization and IntegrationReservoir Engineering and Simulation MethodsMachine Learning in Materials Science

Tough and Processable Hydrogels Based on Lignin and Hydrophilic Polyurethane

Farshad Oveissi、Sina Naficy、Thi Yen Loan Le 等 5 位作者2018-11-07ACS Applied Bio Materials

Lignin is a low-cost, natural polymer with abundant polar sites on its backbone that can be utilized for physical cross-linking of polymers. Here, we use lignin for additional cross-linking of hydrophilic polyether-based polyurethane (HPU) hydrogels, aiming to improve their mechanical properties and processability. Wi…

Hydrogels: synthesis, properties, applicationsElectrospun Nanofibers in Biomedical ApplicationsPolymer composites and self-healing

Anisotropic Third-Order Nonlinearity in Pristine and Lithium Hydride Intercalated Black Phosphorus

Tieshan Yang、Ibrahim Abdelwahab、Han Lin 等 8 位作者2018-11-07ACS Photonics

Two-dimensional (2D) black phosphorus (BP) displays unique anisotropic properties in its linear optical responses, but its third-order nonlinearity (Kerr effect) has remained relatively unexplored. Here we measured the third-order nonlinear optical responses in exfoliated BP and in lithium hydride intercalated BP (LiH…

2D Materials and ApplicationsPlasmonic and Surface Plasmon ResearchAdvanced Fiber Laser Technologies

Efficient room-temperature production of high-quality graphene by introducing removable oxygen functional groups to the precursor

Hongwu Chen、Wencheng Du、Jing Liu 等 5 位作者2018-11-07Chemical Science

fabrication yield trade-off. Here, we report a wet chemical method for the high-efficiency production of a high-quality graphene oxide precursor, with all steps conducted at room-temperature. The functionalization of graphite was performed under temperature and water content control in a concentrated sulfuric acid-pot…

Advancements in Battery MaterialsGraphene research and applicationsGraphene and Nanomaterials Applications

Faster Ion Switching NiCo 2 O 4 Nanoparticle Electrode-Based Supercapacitor Device with High Performances and Long Cycling Stability

Lakshya Kumar、Himani Chauhan、Neetu Yadav 等 6 位作者2018-11-07ACS Applied Energy Materials

Although nanostructured NiCo 2 O 4 is the most appealing and studied electrode material by far as it is cheap, nontoxic, and efficient for supercapacitor application, it still lacks suitable device application comprising a wide voltage window and high operating current density, high specific energy and power, and abso…

Advancements in Battery MaterialsSupercapacitor Materials and FabricationAdvanced battery technologies research

Multiring pure-phase binary optical elements to extend depth of focus

Ning Xu、Zhe Kong、Qiaofeng Tan 等 4 位作者2018-11-07Applied Optics

Multiring pure-phase binary optical elements (BOEs) are widely used to extend the depth of focus (DOF) in many optical applications. Although researchers have designed various BOEs to extend the DOF, few theories and experiments have been reported to validate the performances of different N-ring pure-phase BOEs to rea…

Advanced optical system designOptical Coherence Tomography ApplicationsOptical Coatings and Gratings

Ultra-rapid transient liquid phase bonding of Mg alloys within 1 s in air by ultrasonic assistance

Zhiwu Xu、Zhengwei Li、Liming Peng 等 4 位作者2018-11-07Materials & Design

An ultra-rapid transient liquid phase bonding method was successfully used to join AZ31B Mg alloys by using pure Zn interlayers in air. The bonding time was shortened to 1 s with ultrasonic assistance. Eutectic structures, MgZn, and MgZn 2 formed at relatively low temperatures of 360 °C and 370 °C. Only eutectic struc…

Magnesium Alloys: Properties and ApplicationsAluminum Alloys Composites PropertiesAdvanced Welding Techniques Analysis

Thalia dealbata Inspired Anisotropic Cellular Biomass Derived Carbonaceous Aerogel

Tao Chen、Jian Zhang、Peiheng Shi 等 9 位作者2018-11-07ACS Sustainable Chemistry & Engineering

Carbon aerogels with biomimetic structures have shown excellent physicochemical properties and brought great potential applications to a wide range of fields. The utilization of renewable resources as the carbon precursors offers a low-cost and scalable way to fabricate biomimetic carbon aerogels with intriguing prope…

Supercapacitor Materials and FabricationAdvanced Materials and MechanicsAerogels and thermal insulation

Single-Crystal MoO3 Micrometer and Millimeter Belts Prepared from Discarded Molybdenum Disilicide Heating Elements

Xiaolong Hou、Juntong Huang、Mingqiang Liu 等 8 位作者2018-11-07Scientific Reports

Abstract Single-crystal MoO3 micrometer to millimeter even centimeter belts were prepared via a novel route of oxidizing a discarded molybdenum disilicide heating element at 1000 °C for 3 h. The morphology and structure features, and growth mechanism of the products were evidently investigated by X-ray diffraction, Fo…

Gas Sensing Nanomaterials and SensorsOrganic Light-Emitting Diodes ResearchTransition Metal Oxide Nanomaterials

Macromolecule Orientation in Nanofibers

Dan Tian、Chun‐Hui He、Ji‐Huan He2018-11-07Nanomaterials

Electrospinning is now commercially used for the fabrication of nano/micro fibers. Compared with spider dragline silk, artificial fibers have poor mechanical properties. Unlike natural silk, which has a hierarchical structure with an approximate 3-fold symmetry, the molecular structure of spun fiber has neither foldin…

Surface Modification and SuperhydrophobicityElectrospun Nanofibers in Biomedical ApplicationsSilk-based biomaterials and applications