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Oxidant or Catalyst for Oxidation? A Study of How Structure and Disorder Change the Selectivity for Direct versus Catalytic Oxidation Mediated by Manganese(III,IV) Oxides

Mayada Sabri、Hannah J. King、Rosalind J. Gummow 等 8 位作者2018-10-24Chemistry of Materials

Structure type and disorder have become important questions in catalyst design, with the most active catalysts often noted to be “disordered” or “amorphous” in nature. To quantify the effects of disorder and structure type systematically, a test set of manganese(III,IV) oxides was developed and their reactivity as oxi…

Catalytic Processes in Materials ScienceElectrochemical Analysis and ApplicationsCatalysis and Oxidation Reactions

Amino Acid Coordination Driven Self‐Assembly for Enhancing both the Biological Stability and Tumor Accumulation of Curcumin

Yongxin Li、Qianli Zou、Chengqian Yuan 等 6 位作者2018-10-24Angewandte Chemie

Abstract Clinical translation of curcumin has been highly obstructed by the rapid degradation and poor tissue absorption of this agent. Herein, we report on the generation of supramolecular curcumin nanoagents through amino acid coordination driven self‐assembly to simultaneously increase the biological stability and…

RNA Interference and Gene DeliveryCurcumin's Biomedical ApplicationsSupramolecular Self-Assembly in Materials

Coherent perfect absorption and asymmetric interferometric light-light control in graphene with resonant dielectric nanostructures

Feng Xiong、Jinglan Zou、Wei Xu 等 7 位作者2018-10-24Optics Express

Engineering light absorption in graphene has been the focus of intensive research in the past few years. In this paper, we show numerically that coherent perfect absorption can be realized in monolayer graphene in the near infrared range by harnessing resonances of dielectric nanostructures. The asymmetry of the struc…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchOrbital Angular Momentum in Optics

Surface Morphology and Electrical Properties of Cu3BTC2 Thin Films Before and After Reaction with TCNQ

Konrad Thürmer、Christian Schneider、Vitalie Stavila 等 8 位作者2018-10-24ACS Applied Materials & Interfaces

HKUST-1 or Cu 3 BTC 2 (BTC = 1,3,5-benzenetricarboxylate) is a prototypical metal–organic framework (MOF) that holds a privileged position among MOFs for device applications, as it can be deposited as thin films on various substrates and surfaces. Recently, new potential applications in electronics have emerged for th…

Metal-Organic Frameworks: Synthesis and ApplicationsGas Sensing Nanomaterials and SensorsMXene and MAX Phase Materials

Effect of the LLTO nanoparticles on the conducting properties of PEO-based solid electrolyte

Carlos Ricardo Milian Pila、Eduardo Pérez Cappe、Nelcy Della Santina Mohallem 等 9 位作者2018-10-24Solid State Sciences

The influence of LLTO (Li0.33La0.56TiO3) nanoparticles on the conducting properties of PEO (polyethylene oxide)8-LiClO4 polymer-salt complex electrolyte still remains not fully understood. This paper aims to establish the role of LLTO filler concentration, its morphology, agglomeration and charge nanoparticles surface…

Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesConducting polymers and applications

Zak phase and topological plasmonic Tamm states in one-dimensional plasmonic crystals

Lei Wang、Wei Cai、Mengli Bie 等 5 位作者2018-10-24Optics Express

The Zak phase and topological plasmonic Tamm states in plasmonic crystals based on periodic metal-insulator-metal waveguides are systematically investigated. We reveal that robust topological interfacial states against structural defects exist when the Zak phase between two adjoining plasmonic lattices are different i…

Metamaterials and Metasurfaces ApplicationsTopological Materials and PhenomenaPhotonic Crystals and Applications

Molecular dynamics simulations with machine learning potential for Nb-doped lithium garnet-type oxide Li7−xLa3(Zr2−xNbx)O12

Kazutoshi Miwa、Ryoji Asahi2018-10-24Physical Review Materials

Lithium garnet-type oxide ${\mathrm{Li}}_{7}{\mathrm{La}}_{3}{\mathrm{Zr}}_{2}{\mathrm{O}}_{12}$ (LLZO) is one of the most promising solid electrolyte materials. In this study, the Li conduction properties of Nb-doped LLZO, ${\mathrm{Li}}_{6.75}{\mathrm{La}}_{3}({\mathrm{Zr}}_{1.75}{\mathrm{Nb}}_{0.25}){\mathrm{O}}_{1…

Advancements in Battery MaterialsAdvanced Battery Materials and TechnologiesSolid-state spectroscopy and crystallography

Thickness-Dependent Perpendicular Magnetic Anisotropy and Gilbert Damping in Hf / Co 20 Fe 60 B 20 / Mg O Heterostructures

James Lourembam、Abhijit Ghosh、Minggang Zeng 等 6 位作者2018-10-24Physical Review Applied

Command over fundamental magnetic properties, such as magnetic anisotropy and Gilbert damping, could lead to a universal magnetic memory with long data retention and ultralow power consumption. The authors study these properties in film heterostructures fabricated on industry-friendly platforms, with subnanometer depo…

Magnetic properties of thin filmsZnO doping and propertiesAdvanced Memory and Neural Computing

Graphene based tunable grating structure

Shobhit K. Patel、Mayurkumar Ladumor、Vishal Sorathiya 等 4 位作者2018-10-24Materials Research Express

We propose graphene-silicon hybrid tunable grating structure. The graphene sections are interleaved in silicon waveguide. Periodic and chirped grating structures are the two different designs are presented in the paper. The reflectance, transmittance, electric field intensity and fermi energy results are presented for…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchThermal Radiation and Cooling Technologies

Uptake and function of membrane‐destabilizing cationic nanogels for intracellular drug delivery

William B. Liechty、Rebekah L. Scheuerle、Julia E. Vela Ramirez 等 4 位作者2018-10-24Bioengineering & Translational Medicine

Abstract The design of intracellular drug delivery vehicles demands an in‐depth understanding of their internalization and function upon entering the cell to tailor the physicochemical characteristics of these platforms and achieve efficacious treatments. Polymeric cationic systems have been broadly accepted to be mem…

Nanoparticle-Based Drug DeliveryLipid Membrane Structure and BehaviorRNA Interference and Gene Delivery

Band-Gap Tuning of Organic–Inorganic Hybrid Palladium Perovskite Materials for a Near-Infrared Optoelectronics Response

Huawei Zhou、Xiao-Lei Cui、Cang Yuan 等 19 位作者2018-10-24ACS Omega

High Resolution Image Download MS PowerPoint Slide Organic–inorganic hybrid material is a recent hot topic in the scientific community. The best band gap for the entire solar absorption spectrum is about 1.1 eV. However, the lead perovskite band gap is about 1.5 eV. Therefore, developing organic–inorganic hybrid mater…

Perovskite Materials and ApplicationsConducting polymers and applicationsSolid-state spectroscopy and crystallography

High-Performance White Organic Light-Emitting Diodes with Simplified Structure Incorporating Novel Exciplex-Forming Host

Qi‐Sheng Tian、Lei Zhang、Yun Hu 等 6 位作者2018-10-24ACS Applied Materials & Interfaces

It is a challenge to engineer white organic light-emitting diodes (WOLEDs) with high efficiency, low operating voltage, good color quality, and low efficiency roll-off, simultaneously. Herein, we employ a novel exciplex to solve this problem, which mixes a bipolar host material 2,6-bis(3-(carbazol-9-yl)phenyl)pyridine…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Crystalline Conjugated Polymers for Organic Solar Cells: From Donor, Acceptor to Single‐Component

Dongdong Xia、Cheng Li、Weiwei Li2018-10-24The Chemical Record

Organic solar cells have made rapid progress in the last two decades due to the innovation of conjugated materials and photovoltaic devices. Microphase separation that connects with materials and devices plays a crucial role in the charge generation process. In this account, we summary our recent works of developing n…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsConducting polymers and applications

The Analysis of a Structural State of Surface Layer after Electroerosive Alloying. II. Features of Formation of Electroerosive Coatings on Special Steels and Alloys by Hard Wear-Resistant and Soft Antifriction Materials

Viacheslav Tarelnyk、O. P. Gaponova、Ye. V. Konoplyanchenko 等 5 位作者2018-10-24METALLOFIZIKA I NOVEISHIE TEKHNOLOGII

В работе представлены результаты металлографических исследований электроэрозионных покрытий на специальных сталях и сплавах (стали Р6М5, 12Х18Н10Т, 07Х16Н6, сплав ХН58МБЮД и бронза БрБ2) твёрды ми износостойкими (сплавы ВК8, Т15К6, СТИМ-3В и W, Mo, Cr), мягкими антифрикционными (Cu, Ni, бронза БрБ2, Sn) материалами, а…

Engineering Technology and MethodologiesMaterial Properties and ApplicationsSurface Treatment and Coatings

Exfoliating Polyoxometalate‐Encapsulating Metal‐Organic Framework into Two‐Dimensional Nanosheets for Superior Oxidative Desulfurization

Lili Xu、Yang Wang、Tingting Xu 等 8 位作者2018-10-24ChemCatChem

Abstract We report the exfoliation of two‐dimensional polyoxometalate‐encapsulating MOF (POM−Co‐MOF) into atomically thick nanosheets for highly efficient desulfurization application. Two‐dimensional layer‐structured MOF [Co2(H2O)4(BTX)3][PMo12O40] (BTX=1,4‐Bis(1,2,4‐triazol‐1‐ylmethyl)benzene) is featured with Keggin…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsCatalysis and Hydrodesulfurization Studies

Fabrication of 3D Hierarchical Byttneria Aspera‐Like Ni@Graphitic Carbon Yolk–Shell Microspheres as Bifunctional Catalysts for Ultraefficient Oxidation/Reduction of Organic Contaminants

Xueyan Liu、Dan Xu、Qiong Wang 等 4 位作者2018-10-24Small

Abstract The search for earth‐abundant, low‐cost, recyclable, multifunctional as well as highly active catalysts remains the most pressing demand for heterogeneous catalytic elimination of pollutants in water environment remediation. Herein, a porous graphitic carbon‐encapsulated Ni nanoparticles (NPs) hybrid (Ni@GC)…

Advanced Photocatalysis TechniquesCatalytic Processes in Materials ScienceNanomaterials for catalytic reactions

Sorption-Related Characteristics of Surface Charred Spruce Wood

Maija Kymäläinen、Hannu Turunen、Petr Čermák 等 5 位作者2018-10-24Materials

L.) wood samples were charred with a hot plate and several time-temperature combinations while using simultaneous surface compression. Temperature profile, water sorption, cupping after water exposure and density profile were measured. Furthermore, changes in the microstructure and surface functional groups were inves…

Wood Treatment and PropertiesNatural Fiber Reinforced CompositesLignin and Wood Chemistry

Selective Photokilling of Human Pancreatic Cancer Cells Using Cetuximab-Targeted Mesoporous Silica Nanoparticles for Delivery of Zinc Phthalocyanine

Özge Er、Süleyman Gökhan Çolak、Kasım Ocakoğlu 等 9 位作者2018-10-24Molecules

Background: Photodynamic therapy (PDT) is a non-invasive and innovative cancer therapy based on the photodynamic effect. In this study, we sought to determine the singlet oxygen production, intracellular uptake, and in vitro photodynamic therapy potential of Cetixumab-targeted, zinc(II) 2,3,9,10,16,17,23,24-octa(tert-…

Nanoplatforms for cancer theranosticsPorphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research Studies

Curing Reaction of Benzoxazine Under High Pressure and the Effect on Thermal Resistance of Polybenzoxazine

Ka Zeng、Jiayue Huang、Junwen Ren 等 4 位作者2018-10-24Macromolecular Chemistry and Physics

Abstract Two benzoxazine monomers, bisphenol A/aniline type benzoxazine (BA‐a) and bisphenol A/tert‐butylamine type benzoxazine (BA‐tb), are prepared with high purity. Their curing behaviors and cure kinetics are studied by high pressure differential scanning calorimetry (HP DSC) at normal pressure and high pressure,…

Epoxy Resin Curing ProcessesInjection Molding Process and PropertiesSynthesis and properties of polymers

Re‐ and Preconfigurable Multistable Visible Light Responsive Surface Topographies

Matthew Hendrikx、Jeroen ter Schiphorst、Ellen P. A. van Heeswijk 等 10 位作者2018-10-24Small

Light responsive materials that are able to change their shape are becoming increasingly important. However, preconfigurable bistable or even multi-stable visible light responsive coatings have not been reported yet. Such materials will require less energy to actuate and will have a longer lifetime. Here, it is shown…

Supramolecular Self-Assembly in MaterialsPhotochromic and Fluorescence ChemistryAdvanced Materials and Mechanics