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Nanoscale Investigation of Defects and Oxidation of HfSe2

Qirong Yao、Lijie Zhang、Pantelis Bampoulis 等 4 位作者2018-10-18The Journal of Physical Chemistry C

Abstract HfSe2 is a very good candidate for a transition metal dichalcogenide-based field-effect transistor owing to its moderate band gap of about 1 eV and its high-? dielectric native oxide. Unfortunately, the experimentally determined charge carrier mobility is about 3 orders of magnitude lower than the theoretical…

2D Materials and ApplicationsQuantum Dots Synthesis And PropertiesMXene and MAX Phase Materials

Combination of Density Functional Theory and Microkinetic Study to the Mn-Doped CeO2 Catalysts for CO Oxidation: A Case Study to Understand the Doping Metal Content

Weiyu Song、Lulu Chen、Jianlin Deng 等 7 位作者2018-10-18The Journal of Physical Chemistry C

CeO 2 doped with metal is employed in many catalytic reactions. Optimizing the content of metal is a routine step to improve the activity. In low doping metal content, the catalytic performance improves with the increase of the doping metal content. However, the catalytic performance decreases beyond the optimal dopin…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Microstructure and Properties of C/SiC‐Diamond Composites Prepared by the Combination of CVI and RMI

Jingxin Li、Yongsheng Liu、Beiya Nan 等 7 位作者2018-10-18Advanced Engineering Materials

Diamond modified continuous carbon fiber reinforced silicon carbide (C/SiC‐Diamond) composites are prepared using a combination of chemical vapor infiltration (CVI) and reactive melt infiltration (RMI). The effect of the diamond particle size on the microstructure, mechanical properties, and thermophysical properties…

Advanced ceramic materials synthesisThermal properties of materialsAdvanced materials and composites

Block Copolymers as Dispersants for Single-Walled Carbon Nanotubes: Modes of Surface Attachment and Role of Block Polydispersity

Ricardo M.F. Fernandes、Jing Dai、Oren Regev 等 5 位作者2018-10-18Langmuir

Abstract When using amphiphilic polymers to exfoliate and disperse carbon nanotubes in water, the balance between the hydrophobic and hydrophilic moieties is critical and nontrivial. Here, we investigate the mode of surface attachment of a triblock copolymer, Pluronics F127, composed of a central hydrophobic polypropy…

Carbon Nanotubes in CompositesNanopore and Nanochannel Transport StudiesNMR spectroscopy and applications

Characterization of shape memory polymer parts fabricated using material extrusion 3D printing technique

Carlos A. Garcia Rosales、Hoejin Kim、Mario F. Garcia Duarte 等 7 位作者2018-10-18Rapid Prototyping Journal

Purpose Shape memory polymer (SMP) is capable of recovering its original shape from a high degree of deformation by applying an external stimulus such as thermal energy. This research presents an integration of two commercial SMP materials (DiAPLEX and Tecoflex) and a material extrusion (ME) printer to fabricate SMP p…

Additive Manufacturing and 3D Printing TechnologiesPolymer composites and self-healingInnovations in Concrete and Construction Materials

Flexible Films of Covalent Organic Frameworks with Ultralow Dielectric Constants under High Humidity

Pengpeng Shao、Jie Li、Fan Chen 等 10 位作者2018-10-18Angewandte Chemie

Abstract Covalent organic framework (COF) films combine the processability of polymers with the porosity and atomic precision of crystalline porous materials, properties that are long‐sought‐after in electronics yet hard to realize. Herein, we prepared four flexible COF films with different alkoxy side chains via inte…

Advanced Sensor and Energy Harvesting MaterialsDielectric materials and actuatorsCovalent Organic Framework Applications

Solubility Determination of Nicotinamide and Its Application for the Cocrystallization with Benzoic Acid

Jinbo Ouyang、Yu Zhang、Bing Na 等 6 位作者2018-10-18Journal of Chemical & Engineering Data

Solubility of nicotinamide in a series of pure solvents, including ethanol, 1-propanol, isopropanol, ethyl acetate, methanol, 1-butanol, methyl acetate, isobutanol, acetone, and butyl acetate, was measured between 283.15 and 323.15 K. The solubility data increase with rising of temperature and mainly follow the order…

Crystallography and molecular interactionsCrystallization and Solubility StudiesChemical Thermodynamics and Molecular Structure

Mesopore Connectivity Improving Aerosol-Assisted Synthesis of Mesoporous Alumina Powders with High Surface Area

Hirokazu Maruoka、Atsuko Tomita、Zheng Liu 等 4 位作者2018-10-18Langmuir

Considering the closed packing of supramolecular mediated cage-type (spherical) mesopores inside spherical particles that are typically obtained by the aerosol-assisted process, uniform mesopores cannot be packed so periodically and then the mesopores are less connected and/or occasionally isolated, leading to the for…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisAerogels and thermal insulation

Fabrication of nanocellulose/PEGDA hydrogel by 3D printing

Aimin Tang、Qin-Wen Wang、Shan Zhao 等 4 位作者2018-10-18Rapid Prototyping Journal

Purpose Nanocellulose is characterised by favourable biocompatibility, degradability, nanostructure effect, high modulus and high tensile strength and has been widely applied in various fields. The current research in the field of new nanocellulose materials mainly focuses on the hydrogel, aerogel and the tissue engin…

Advanced Cellulose Research StudiesElectrospun Nanofibers in Biomedical ApplicationsAdditive Manufacturing and 3D Printing Technologies

Ratiometric NOE(−1.6) contrast in brain tumors

Zhongliang Zu2018-10-18NMR in Biomedicine

Recently, a new nuclear Overhauser enhancement (NOE)-mediated saturation transfer effect at around -1.6 ppm from water, termed NOE(-1.6), was reported to show hypointense signals in brain tumors. Similar to chemical exchange saturation transfer or magnetization transfer (MT) effects, which depend on the solute pool co…

Advanced MRI Techniques and ApplicationsLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Counterion influence on dynamic spin properties in a V( iv ) complex

Chun‐Yi Lin、Thacien Ngendahimana、Gareth R. Eaton 等 5 位作者2018-10-18Chemical Science

Studies of R 3 NH + salts of [V(C 6 H 4 O 2 ) 3 ] 2− experimentally define the distance dependence of the impact of the CH 3 -group on spin properties.

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Catalyzed Oxygenation Mechanisms

Experimental investigation on the mechanical properties and water absorption behavior of randomly oriented short pineapple/coir fiber-reinforced hybrid epoxy composites

Mohit Mittal、Rajiv Chaudhary2018-10-18Materials Research Express

Experimental investigation on the mechanical properties and water absorption behavior of randomly oriented short pineapple/coir fiber-reinforced hybrid epoxy composites, Mittal, Mohit, Chaudhary, Rajiv

Natural Fiber Reinforced CompositesTextile materials and evaluationsMaterial Properties and Processing

Studies on Catalytic Activity of Hydrogen Peroxide Generation according to Au Shell Thickness of Pd/Au Nanocubes

In Ho Kim、Myung-gi Seo、Changhyeok Choi 等 12 位作者2018-10-18ACS Applied Materials & Interfaces

The catalytic properties of materials are determined by their electronic structures, which are based on the arrangement of atoms. Using precise calculations, synthesis, analysis, and catalytic activity studies, we demonstrate that changing the lattice constant of a material can modify its electronic structure and ther…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Metalloporphyrin Two-Dimensional Polymers via Metal-Catalyst-Free C–C Bond Formation for Efficient Catalytic Hydrogen Evolution

Kayaramkodath Chandran Ranjeesh、Rajith Illathvalappil、Vivek Chandrakant Wakchaure 等 6 位作者2018-10-18ACS Applied Energy Materials

A sensible design plays a pivotal role in developing new two-dimensional polymers. Recent years have witnessed many such potential ways utilizing boraxine, imine, phenazine, and C–C linkages, etc., in this direction. However, a metal catalyst-free direct C–C bond remains unexplored in two-dimensional polymer synthesis…

Advanced Photocatalysis TechniquesMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework Applications

Microbial production of d ‐lactic acid from dried distiller's grains with solubles

Nurul Aqilah Mohd Zaini、Afroditi Chatzifragkou、Dimitris Charalampopoulos2018-10-18Engineering in Life Sciences

Abstract d ‐Lactic acid production is gaining increasing attention due to the thermostable properties of its polymer, poly‐ d ‐lactic acid . In this study, Lactobacillus coryniformis subsp. torquens , was evaluated for its ability to produce d ‐lactic acid using Dried Distiller's Grains with Solubles (DDGS) hydrolysat…

Biofuel production and bioconversionEnzyme Catalysis and Immobilizationbiodegradable polymer synthesis and properties

Vibrational properties and Raman spectra of pristine and fluorinated blue phosphorene

Zexiang Deng、Zhibing Li、Weiliang Wang 等 4 位作者2018-10-18Physical Chemistry Chemical Physics

Using density functional theory, we investigated the vibrational properties and Raman spectra of pristine blue phosphorene and fluorinated blue phosphorene. The fluorinated blue phosphorene possesses a Dirac cone at the K point (about 310 cm-1). The shape of the Dirac cone remains unchanged under different tensile str…

Perovskite Materials and Applications2D Materials and ApplicationsMXene and MAX Phase Materials

Development of Silane-Based Coatings with Zirconia Nanoparticles Combining Wetting, Tribological, and Aesthetical Properties

Sara López de Armentia、M. Pantoja、J. Abenójar 等 4 位作者2018-10-18Coatings

Silane-based coatings with nanoparticles have been widely used in applications related to surface protection. Between them, the improvement of corrosion resistance by increasing the hydrophobicity is one of the main research goals. However, most coatings present problems of low wear resistance and poor aesthetic appea…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchTribology and Wear Analysis

A Flexible Supercapacitor with High True Performance

Zhonghua Ren、Yuanji Li、Jie Yu2018-10-18iScience

The demand for better "true performance" of supercapacitors, which is defined as the energy density based on the packaged cell with high active mass loading, is spurred by the ever-increasing energy storage market. The true performance of present supercapacitors is unsatisfactory, greatly limited by the currently used…

Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationAdvanced battery technologies research

Application of Anionic Phosphorus Derivatives of Alkyl Polyglucosides for the Production of Sustainable and Mild Body Wash Cosmetics

Artur Seweryn、Tomasz Bujak2018-10-18ACS Sustainable Chemistry & Engineering

This paper explores the possibility of using phosphorus derivatives of alkyl polyglucosides with varying alkyl chain lengths (C4, C8, C10, C12), obtained from natural raw materials, in the production of mild and eco-friendly body wash cosmetics, as examples of sustainable products. The central assumption was that part…

biodegradable polymer synthesis and propertiesTextile materials and evaluationsSensory Analysis and Statistical Methods

High Thermoelectric Performance in Sintered Octahedron-Shaped Sn(CdIn)xTe1+2x Microcrystals

Raza Moshwan、Xiao‐Lei Shi、Wei‐Di Liu 等 9 位作者2018-10-18ACS Applied Materials & Interfaces

In this study, we fabricate In/Cd codoped octahedron-shape Sn(CdIn) x Te 1+2 x microcrystals with a promising thermoelectric performance by using a facile solvothermal method. The high hole–carrier concentration of pristine SnTe is significantly reduced through effective In/Cd codoping, which increases the Seebeck coe…

Advanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin FilmsAdvanced Semiconductor Detectors and Materials