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Photochemically-induced perturbation of the 1 A ⇌ 5 T equilibrium in Fe 11 complexes by pulsed laser irradiation in the metal-to-ligand charge-transfer absorption band

John J. McGravey、Ian Lawthers1982-01-01Journal of the Chemical Society Chemical Communications

Rapid perturbation of the 1A ⇌5T equilibrium in several Fe11 complexes occurs upon irradiation in the metal-to-ligand charge-transfer absorption region of the low-spin state, providing primary evidence for the formation of a 5T ligand field state from the initially populated charge-transfer state and permitting study…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Étude expérimentale de la distribution de l'aluminium entre bain silicaté basique et spinelle chromifère. Implications pétrogénétiques : teneur en chrome des spinelles

Colette Maurel、Pierre Maurel1982-01-01Bulletin de Minéralogie

The partitioning of aluminium between silicate melt (olivine tholeiite) and chromian spinel was studied experimentally. Runs were carried out at temperatures of 1 180˗1 300 °C and oxygen fugacities of 10⁻⁷˗10⁻⁹ atmosphere, at one atmosphere total pressure. The Al₂O₃ content of spinel is related to the Al₂O₃ content of…

Concrete and Cement Materials ResearchAdvanced ceramic materials synthesisClay minerals and soil interactions

Ferroelectromagnets

G.A. Smolenskii、I. E. Chupis1982-01-01Uspekhi Fizicheskih Nauk

1982 . 137, . 3 537.226.33 + 538.11 . . , . . 1. 415 2. () 420 ) , (421). ) (422). 3. 423 ) (424). ) (425). ) (426). ) (428). 4. 429 ) (429). ) (432). ) (433). 434 5. 434 ) (434). ) (439). 6. 440 7. 443 444 1. *) , , .

Magnetic Properties of AlloysMagnetic Properties and Applications

Role of the crystal-field theory in determining the structures of spinels

Jeremy K. Burdett、G. D. Price、Sarah L. Price1982-01-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRole of the crystal-field theory in determining the structures of spinelsJeremy K. Burdett, Geoffrey D. Price, and Sarah L. PriceCite this: J. Am. Chem. Soc. 1982, 104, 1, 92–95Publication Date (Print):January 1, 1982Publication History Published online1 May 2002Published in…

X-ray Diffraction in CrystallographyPigment Synthesis and PropertiesThermal and Kinetic Analysis

Electrical Transport Properties in 2H-NbS2, -NbSe2, -TaS2 and -TaSe2

M. Naito、Shōji Tanaka1982-01-01Journal of the Physical Society of Japan

Detailed measurements of the resistivity and the Hall coefficient have been made on high-quality single crystals of 2 H metallic transition-metal dichalcogenides between 4.2 K and 300 K, in order to investigate the carrier scattering mechanisms in a CDW system. The resistivity of 2 H -NbS 2 , which has no CDW transiti…

2D Materials and ApplicationsSolid-state spectroscopy and crystallographyOrganic and Molecular Conductors Research

Hydrogen-bonding properties of hard-segment model compounds in polyurethane block copolymers

C. M. Brunette、Shaw Ling Hsu、W. J. MacKnight1982-01-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHydrogen-bonding properties of hard-segment model compounds in polyurethane block copolymersC. M. Brunette, S. L. Hsu, and W. J. MacKnightCite this: Macromolecules 1982, 15, 1, 71–77Publication Date (Print):January 1, 1982Publication History Published online1 May 2002Publish…

Polymer crystallization and propertiesPolymer composites and self-healingPolymer Nanocomposites and Properties

Prussian-blue-modified electrodes: An application for a stable electrochromic display device

Kingo Itaya、Kimio Shibayama、Haruo Akahoshi 等 4 位作者1982-01-01OpenAlex

An electrochromic display based on a Prussian-blue-modified electrode is described. Prussian blues are deposited electrochemically in a solution of ferric-ferricyanide. Current flow at +0.2 and +1.0 V is due to the reduction of Fe3+ and the oxidation of Fe2+ in the Prussian-blue coating, respectively. The result is a…

Transition Metal Oxide NanomaterialsElectrowetting and Microfluidic Technologies

Small-angle x-ray scattering study of perfluorinated ionomer membranes. 2. Models for ionic scattering maximum

Mineo Fujimura、Takeji Hashimoto、Hiromichi Kawai1982-01-01OpenAlex

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSmall-angle x-ray scattering study of perfluorinated ionomer membranes. 2. Models for ionic scattering maximumMineo Fujimura, Takeji Hashimoto, and Hiromichi KawaiCite this: Macromolecules 1982, 15, 1, 136–144Publication Date (Print):January 1, 1982Publication History Publis…

Fiber-reinforced polymer compositesSynthesis and properties of polymersSilicone and Siloxane Chemistry

Lightning rod effect in surface enhanced Raman scattering

P. F. Liao、Alexander Wokaun1982-01-01OpenAlex

The electromagnetic model of Gersten and Nitzan1 of the surface enhanced Raman scattering is discussed. The ’’lightning rod’’ effect is taken up in some detail. (AIP)

Plasmonic and Surface Plasmon ResearchNanocluster Synthesis and ApplicationsGold and Silver Nanoparticles Synthesis and Applications

Heat Treatment: Structure and Properties of Nonferrous Alloys

C. R. Brooks1982-01-01OpenAlex

Heat treatment, structure, and properties of nonferrous alloys , Heat treatment, structure, and properties of nonferrous alloys , مرکز فناوری اطلاعات و اطلاع رسانی کشاورزی

Metallurgy and Material Science

Improvement of photoelectrochemical hydrogen generation by surface modification of p-type silicon semiconductor photocathodes

Raymond N. Dominey、Nathan S. Lewis、James A. Bruce 等 5 位作者1982-01-01OpenAlex

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTImprovement of photoelectrochemical hydrogen generation by surface modification of p-type silicon semiconductor photocathodesRaymond N. Dominey, Nathan S. Lewis, James A. Bruce, Dana C. Bookbinder, and Mark S. WrightonCite this: J. Am. Chem. Soc. 1982, 104, 2, 467–482Publica…

Electron and X-Ray Spectroscopy TechniquesPhotocathodes and Microchannel Platessolar cell performance optimization

Zirconium in the Nuclear Industry

D.G. Franklin1982-01-01OpenAlex

Description This publication provides information on the performance of zirconium and zirconium alloy components in nuclear application. Nuclear physicists have discovered that some materials -- zirconium, for example, provide much better neutron economy than conventional materials such as stainless steels.

Nuclear and radioactivity studiesNuclear Materials and Properties

Data analysis techniques in x-ray photoelectron spectroscopy

Andrew Proctor、Peter M. A. Sherwood1982-01-01OpenAlex

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTData analysis techniques in x-ray photoelectron spectroscopyAndrew. Proctor and Peter M. A. SherwoodCite this: Anal. Chem. 1982, 54, 1, 13–19Publication Date (Print):January 1, 1982Publication History Published online1 May 2002Published inissue 1 January 1982https://pubs.acs…

Electron and X-Ray Spectroscopy TechniquesX-ray Spectroscopy and Fluorescence AnalysisSurface and Thin Film Phenomena

Local inertial effects in dynamic fragmentation

D. E. Grady1982-01-01OpenAlex

A general definition of dynamic fragmentation can encompass any impulsive process which partitions a body of material into discrete domains. Two examples are fragmentation due to brittle fracture under impact loading and fragmentation due to shear banding in shock-compression plastic deformation. In application, predi…

Energetic Materials and CombustionLaser-Plasma Interactions and DiagnosticsHigh-Velocity Impact and Material Behavior

The use of electronically counted microspheres in absolute diatom analysis

R. W. Battarbee、M. J. Kneen1982-01-01OpenAlex

A method of estimating diatom concentrations in sediment samples by the addition of known quantities of microspheres is described. Polystyrene or glass microspheres can be used and their concentration in suspensions can be rapidly calculated with an electronic particle counter. Test results are compared with results f…

Water Quality Monitoring and AnalysisDiatoms and Algae ResearchAnalytical Chemistry and Sensors

Temperature Programmed Reduction

Nicholas W. Hurst、Stephen J. Gentry、Alan R. Jones 等 4 位作者1982-01-01OpenAlex

The success or otherwise of catalyst preparation or modification depends on the availability of suitable characterization techniques to determine the condition of the catalyst. There are many techniques available for this purpose including x-ray powder diffraction, electron microscopy, photoelectron spectroscopy, and…

Thermal and Kinetic AnalysisX-ray Diffraction in CrystallographyCatalysis and Oxidation Reactions

Constitutive Equations for the Rate-Dependent Deformation of Metals at Elevated Temperatures

Lallit Anand1982-01-01OpenAlex

Approximate constitutive equations are proposed for use in the analysis of the rate-dependent deformation of metals at temperatures in excess of a homologous temperature of 0.5. The constitutive equations are formulated within the scope of some recent theories of elastoviscoplasticity with internal variables, but empl…

Microstructure and mechanical propertiesMetallurgy and Material FormingHigh-Velocity Impact and Material Behavior

The determination of hydroxyl by infrared absorption in quartz, silicate glasses and similar materials

M. S. Paterson1982-01-01OpenAlex

L'analyse des calibrations existantes pour différentes substances montre que l'intensité de l'absorption des I.R. de 3 µm par les hydroxyles dépend de la fréquence. Quand on prend en compte le facteur d'anisotropie γ, une raie unique de calibration pour le coefficient d'absorption molaire intégral I peut, en première…

Glass properties and applicationsSpectroscopy and Chemometric AnalysesWater Quality Monitoring and Analysis

Amphiboles and Other Hydrous Pyriboles

Ribbe, Paul H.、Veblen, David R.1981-12-31OpenAlex

Most of Volume 9A of Reviews in Mineralogy treats amphiboles and other hydrous pyriboles as isolated systems. It reviews the structural complexity and resulting chemical variability and diversity of petrologic behavior of amphiboles, whereby Volume 9A contains a hefty dose of petrology and in contrast, Volume 9B is de…

Chemical Reactions and MechanismsThermal and Kinetic AnalysisRadioactive element chemistry and processing