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Theoretical Investigations of the Effects of J-Aggregation on the Linear and Nonlinear Optical Properties ofE-4-(4-Dimethylaminostyryl)-1-methylpyridinium [DAMS+]

Francesca Nunzi、Simona Fantacci、Filippo De Angelis 等 7 位作者2008-01-01The Journal of Physical Chemistry C

J-type aggregation of organic chromophores into inorganic host matrixes provides a useful route toward materials showing strong second-order nonlinear optical (NLO) response. The increased NLO response of J-aggregates is related to the peculiar arrangement of the NLO-phores into the host matrix, which produces the app…

Nonlinear Optical Materials ResearchPhotochemistry and Electron Transfer StudiesSpectroscopy and Quantum Chemical Studies

Guest driven rearrangements of protonation and hydrogen bonding in decavanadate anions as their tetraalkylammonium salts

Setsuko Nakamura、Tomoji Ozeki2008-01-01Dalton Transactions

Single crystal X-ray structure determinations of [(n-C5H11)4N]3[H3V10O28].2(CH3)2CO (TAA-acetone), [(n-C5H11)4N]8[H3V10O28]2[H4V10O28].7C4H8O2 (TAA-dioxane), [(n-C5H11)4N]3[H3V10O28] (TAAh) and [(n-C6H13)4N]2[H4V10O28].4C4H8O2 (THA-dioxane) revealed that protonation and hydrogen bond formation of decavanadate anions i…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsVanadium and Halogenation Chemistry

Ordered Integrated Arrays of Pd and Pt Nanotubules on Al with Controllable Dimensions and Tailored Morphologies

S. Z. Chu、Hirotaka Kawamura、Michitsugu Mori2008-01-01Journal of The Electrochemical Society

We reported an approach to fabricate integrated arrays of palladium (Pd) and platinum (Pt) nanotubules with high aspect ratios on aluminum sheets by a critical-potential anodization and an electroless deposition. The critical-potential anodization provided ordered porous anodic alumina (PAA) films as supporting materi…

Electrocatalysts for Energy ConversionAnodic Oxide Films and NanostructuresNanoporous metals and alloys

Self-Catalyzed Hydrogenolysis of Nickelocene: Functional Metal Coating of Three-Dimensional Nanosystems at Low Temperature

Qing Peng、Joseph C. Spagnola、Gregory N. Parsons2008-01-01Journal of The Electrochemical Society

In this paper we demonstrate the hydrogenolysis of nickelocene can take place through a self-catalyzed process at low temperature ( < 70 ° C ) in supercritical carbon dioxide to generate relatively uniform dispersed Ni (nickel) metal particles onto carbon nanotubes forests and Ni films on flat surfaces. The ability to…

Electrocatalysts for Energy ConversionCarbon Nanotubes in CompositesGraphene research and applications

Poly(ether imide) membranes: studies on the effect of surface modification and protein pre-adsorption on endothelial cell adhesion, growth and function

Rumiana Tzoneva、B. Seifert、Wolfgang Albrecht 等 6 位作者2008-01-01Journal of Biomaterials Science Polymer Edition

Poly(ether imide) (PEI) membranes of which the surface was modified with carboxylic groups were tested in comparison to pure PEI and poly(ethylene terephtalate) (PET) for their ability to support attachment, growth and function of human umbilical vein endothelial cells (HUVEC) with respect to endothelization of the ab…

Surface Modification and SuperhydrophobicityElectrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction Studies

Langmuir–Schaefer films of a set of achiral amphiphilic porphyrins: aggregation and supramolecular chirality

Tianyu Wang、Minghua Liu2008-01-01Soft Matter

A series of new achiral porphyrins with hydrophobic dodecyl chains and hydrophilic substituents were designed in order to clarify the relationship between molecular geometry and aggregation as well as the supramolecular chirality in Langmuir-Schaefer films. These achiral porphyrins have zero (TPPA0), one (TPPA1), two…

Porphyrin and Phthalocyanine ChemistrySynthesis and Properties of Aromatic CompoundsSupramolecular Self-Assembly in Materials

Effect of secondary substituent on the physical properties, crystal structures, and nanoparticle morphologies of (porphyrin)Sn(OH)2: diversity enabled via synthetic manipulations

Suk Joong Lee、Rebecca A. Jensen、Christos D. Malliakas 等 6 位作者2008-01-01Journal of Materials Chemistry

A highly efficient porphyrin synthesis facilitates a systematic investigation of the effects that secondary substituents have on the physical properties, crystal structures, and nanoparticle morphologies of amphiphilic (porphyrin)Sn(OH)2.

Metal-Organic Frameworks: Synthesis and ApplicationsMetal complexes synthesis and propertiesPorphyrin and Phthalocyanine Chemistry

Hydrogen Transport in a Coupled Elastoplastic-Diffusion Analysis near a Blunting Crack Tip

Hiroshi Kanayama、Masao Ogino、Reza Miresmaeili 等 5 位作者2008-01-01Journal of Computational Science and Technology

The role of hydrogen in hydrogen embrittlement, stress corrosion cracking and hydrogen induced cracking has been largely determined. The hydrogen cracking problem in metallurgical fields has been studied for many years. In spite of that, it is still not possible to explain exactly how the presence of hydrogen within t…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsNuclear Materials and Properties

Generalized Ellingham diagrams for utilization in solid oxide fuel cells

Haruo Kishimoto、Katsuhiko Yamaji、Manuel E. Brito 等 5 位作者2008-01-01Journal of Mining and Metallurgy Section B Metallurgy

Generalized Ellingham diagram for the P-O-H and the Ni-P-OH systems have been constructed to investigate thermodynamically the chemical stability of nickel anode against the gaseous impurities containing phosphorous compounds. In the same way as the original Ellingham diagram, the oxygen potential is used as the verti…

Advancements in Solid Oxide Fuel CellsCatalysis and Oxidation ReactionsElectronic and Structural Properties of Oxides

Organic Solar Cells with Hydrogenated In-Doped ZnO Replacing Sn-Doped In2O3 as Transparent Electrode

Young Ran Park、Donggeun Jung、Young Sung Kim2008-01-01Japanese Journal of Applied Physics

Hydrogenated In-doped ZnO (IZO:H) anodic films grown at different ratios ( R ) of hydrogen to argon were deposited at a low processing temperature of 100 °C on a glass substrate by pulsed DC magnetron sputtering for photovoltaic cells. Even at a low substrate temperature, the transparent electrode showed an average op…

ZnO doping and propertiesPerovskite Materials and ApplicationsThin-Film Transistor Technologies

Behaviour of human mesenchymal stem cells on a polyelectrolyte-modified HEMA hydrogel for silk-based ligament tissue engineering

Michela Bosetti、Francesca Boccafoschi、Anna Calarco 等 8 位作者2008-01-01Journal of Biomaterials Science Polymer Edition

The aim of this study was to design a functional bio-engineered material to be used as scaffold for autologous mesenchymal stem cells in ligament tissue engineering. Polyelectrolyte modified HEMA hydrogel (HEMA-co-METAC), applied as coating on silk fibroin fibres, has been formulated in order to take advantage of the…

Knee injuries and reconstruction techniquesPeriodontal Regeneration and TreatmentsSilk-based biomaterials and applications

Low-temperature c-axis oriented growth of nanocrystalline ZnO thin films on Si substrates by plasma assisted pulsed laser deposition

Jie Shao、Y. Q. Shen、Jian Sun 等 7 位作者2008-01-01Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures Processing Measurement and Phenomena

Nanocrystalline zinc oxide (nc-ZnO) thin films with c-axis orientation were deposited on Si (100) substrates at a temperature lower than 100 °C by plasma assisted pulsed laser deposition from metallic zinc. Oxygen plasma generated by electron cyclotron resonance (ECR) microwave discharge was used as a reactive and ene…

ZnO doping and propertiesCopper-based nanomaterials and applicationsGa2O3 and related materials

Imaging by a sub-wavelength metallic lens with large field of view

Shaoyun Yin、Chongxi Zhou、Xiangang Luo 等 4 位作者2008-01-01Optics Express

The characteristics of the phase retardations and the invariability against the incident angles are investigated when light enters the rectangular holes with different sizes perforated on metallic film. A kind of metallic structure with a great potential in imaging is brought forward. The finite difference time domain…

Plasmonic and Surface Plasmon ResearchOptical Coatings and GratingsNear-Field Optical Microscopy

Absorption Mechanisms of Silicon Nanocrystals in Cosputtered Silicon-Rich–Silicon Oxide Films

A. Podhorodecki、J. Misiewicz、F. Gourbilleau 等 4 位作者2008-01-01Electrochemical and Solid-State Letters

Optical properties of silicon-rich–silicon oxide (SRSO) films have been investigated by emission and absorption spectroscopies in the broad spectral range. The impact of the different hydrogen partial pressure of the sputtering method on the absorption properties of SRSO films has been described and commented on. For…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

CFD Simulation of a Coolant Flow and a Heat Transfer in a Pebble Bed Reactor

Wang-Kee In、Won-Jae Lee、Yassin A. Hassan2008-01-01OpenAlex

This CFD study is to simulate a coolant (gas) flow and heat transfer in a PBR core during a normal operation. This study used a pebble array with direct area contacts among the pebbles which is one of the pebbles arrangements for a detailed simulation of PBR core CFD studies. A CFD model is developed to more adequatel…

Nuclear reactor physics and engineeringNuclear Materials and PropertiesIron and Steelmaking Processes

Wood-based lignosulfonate versus synthetic polycarboxylate in concrete admixture systems: The perspective of a traditional pulping by-product competing with an oil-based substitute in a business-to-business market in central Europe.

Tobias Stern、Peter Schwarzbauer2008-01-01Forest Products Journal

A primary data survey was conducted to evaluate the market potential of lignosulfonate as a raw material for plasticizers in the concrete industries of Austria and southern Germany (Bavaria). The results showed significant differences between the countries. Since 2002 lignosulfonate-based products have been massively…

biodegradable polymer synthesis and propertiesLignin and Wood Chemistry

Nanoporous gold electrocatalysis for ethylene monitoring and control

Reza Shekarriz、W. Allen2008-01-01European Journal of Horticultural Science

Summary Maintaining the quality and freshness of fruit and vegetables during transportation and storage is an important role for most postharvest industries. One way to control freshness is by carefully monitoring and regulating exposure to ethylene. By limiting exposure to ethylene the natural aging process of fresh…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceNanoporous metals and alloys

Measuring and control the hysteresis loop by using analog and digital integrators

Zoltán Pólik、Miklós Kuczmann2008-01-01Journal of Optoelectronics and Advanced Materials

We have managed to build up a computer controlled measurement system applying National Instruments Data Acquisiton card and National Insturments LabVIEW software package. First, in a previous study, the specimen under test has been simulated by the Jiles-Atherton model of hysteresis, but simulated measurements have be…

Magnetic Properties and ApplicationsNon-Destructive Testing TechniquesAdvanced Electrical Measurement Techniques

Poly(allylamine hydrochloride)–dextran microgels functionalized with magnetic and luminescent nanoparticles

Lin Wang、Junqi Sun2008-01-01Journal of Materials Chemistry

Microgels of chemically cross-linked poly(allylamine hydrochloride) (PAH) and dextran (named PAH-D) encapsulated with magnetic Fe3O4 and luminescent CdTe nanoparticles were successfully fabricated. The superparamagnetic Fe3O4nanoparticles were firstly incorporated into PAH-D microgels by in situ synthesis of Fe3O4nano…

Quantum Dots Synthesis And PropertiesHydrogels: synthesis, properties, applicationsCarbon and Quantum Dots Applications

A flexible tripodal ligand linking octametallic terbium rings into luminescent polymeric chains

Xiao-Yan Chen、C. Marchal、Yaroslav Filinchuk 等 5 位作者2008-01-01Chemical Communications

Six bidentate building blocks have been used to form a tripodal ligand with a flexible C3 symmetric spacer to direct the assembly of large octametallic clusters covalently linked to form a 1-D highly luminescent terbium tube-like polymer.

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesInorganic Chemistry and Materials